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Ethyne, dichloro-

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Quantity Value Units Method Reference Comment
IE (evaluated)9.9eVN/AN/AL

Ionization energy determinations

IE (eV) Method Reference Comment
9.9PEMaier and Thommen, 1984LBLHLM
10.03 ± 0.01PEKlapstein, Maier, et al., 1983LBLHLM
10.0PEBock, Ried, et al., 1981LLK
10.3 ± 0.1EIKloster-Jensen, Pascual, et al., 1970RDSH
10.09PEHeilbronner, Hornung, et al., 1970Vertical value; RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CCl+15.4 ± 0.1CClEIKloster-Jensen, Pascual, et al., 1970RDSH


Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Maier and Thommen, 1984
Maier, J.P.; Thommen, F., Relaxation dynamics of open-shell cations studied by photoelectron-photon coincidence spectroscopy, Gas Phase Ion Chem., 1984, 3, 357. [all data]

Klapstein, Maier, et al., 1983
Klapstein, D.; Maier, J.P.; Zambach, W., Emission spectra of rotationally cooled dihaloacetylene cations in the gas phase: A2«PI»(«OMEGA»,g) --> x2«PI»(«OMEGA»,u) band systems, Chem. Phys., 1983, 77, 463. [all data]

Bock, Ried, et al., 1981
Bock, H.; Ried, W.; Stein, U., Analyse und optimierung von gasphasen-reaktionen, 19. Pyrolyse von cyclobuten-1,2-dionen zu acetylenen, Chem. Ber., 1981, 114, 673. [all data]

Kloster-Jensen, Pascual, et al., 1970
Kloster-Jensen, E.; Pascual, C.; Vogt, J., Mass spectrometric studies of mono- and di-haloacetylenes,, Helv. Chim. Acta, 1970, 53, 2109. [all data]

Heilbronner, Hornung, et al., 1970
Heilbronner, E.; Hornung, V.; Kloster-Jensen, E., Die Photoelektron-Spektren der Dihalogen-acetylene, Helv. Chim. Acta, 1970, 53, 331. [all data]


Go To: Top, Gas phase ion energetics data, References