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Dimethyl methylphosphonate

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
10.00PEZverev and Villem, 1980LLK
10.00PEZverev, Villem, et al., 1979LLK
10.71PEChattorpadhyay, Findley, et al., 1981Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CHO+18.9 ± 0.8?EIBafus, Gallegos, et al., 1966RDSH
CH3+16.8 ± 0.1?EIBafus, Gallegos, et al., 1966RDSH
CH3O+13.8 ± 0.2?EIBafus, Gallegos, et al., 1966RDSH
CH4OP+16.9 ± 0.2?EIBafus, Gallegos, et al., 1966RDSH
CH4O2P+13.4 ± 0.3?EIBafus, Gallegos, et al., 1966RDSH
CH5O2P+11.9?EIBafus, Gallegos, et al., 1966RDSH
C2H5O+16.3 ± 0.1?EIBafus, Gallegos, et al., 1966RDSH
C2H6O2P+12.5 ± 0.1?EIBafus, Gallegos, et al., 1966RDSH
C2H6O3P+13.3 ± 0.3CH3EIBafus, Gallegos, et al., 1966RDSH
C2H7O2P+11.5 ± 0.2CH2OEIBafus, Gallegos, et al., 1966RDSH
PO+19.4 ± 0.3?EIBafus, Gallegos, et al., 1966RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Zverev and Villem, 1980
Zverev, V.V.; Villem, Y.Y., Ionizationp potentials of phosphoryl compounds, J. Struct. Chem., 1980, 21, 22, In original 30. [all data]

Zverev, Villem, et al., 1979
Zverev, V.V.; Villem, Ya.Ya.; Bel'skii, V.E.; Kitaev, Yu.P., The photoelectronic spectra of phosphoryl compounds, Izv. Akad. Nauk SSSR, Ser. Khim., 1979, 1, 84. [all data]

Chattorpadhyay, Findley, et al., 1981
Chattorpadhyay, S.; Findley, G.L.; McGlynn, S.P., Photoelectron spectroscopy of phosphites and phosphates, J. Electron Spectrosc. Relat. Phenom., 1981, 24, 27. [all data]

Bafus, Gallegos, et al., 1966
Bafus, D.A.; Gallegos, E.J.; Kiser, R.W., An electron impact investigation of some alkyl phosphate esters, J. Phys. Chem., 1966, 70, 2614. [all data]


Notes

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