Dimethyl methylphosphonate

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δvap12.6kcal/molGSButrow, Buchanan, et al., 2009Based on data from 258. - 454. K.; AC

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
13.1273.GSButrow, Buchanan, et al., 2009Based on data from 258. - 454. K.; AC
12.4313.GSButrow, Buchanan, et al., 2009Based on data from 258. - 454. K.; AC
12.1333.GSButrow, Buchanan, et al., 2009Based on data from 258. - 454. K.; AC
11.8353.GSButrow, Buchanan, et al., 2009Based on data from 258. - 454. K.; AC
15.351.AStephenson and Malanowski, 1987Based on data from 336. - 408. K. See also Frazer, Gerrard, et al., 1955.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
336. - 408.1.81668444.796-224.556Kosolapoff, 1955Coefficents calculated by NIST from author's data.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Butrow, Buchanan, et al., 2009
Butrow, Ann B.; Buchanan, James H.; Tevault, David E., Vapor Pressure of Organophosphorus Nerve Agent Simulant Compounds, J. Chem. Eng. Data, 2009, 54, 6, 1876-1883, https://doi.org/10.1021/je8010024 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Frazer, Gerrard, et al., 1955
Frazer, M.J.; Gerrard, W.; Coulson, C.A.; Orgel, L.E.; Taylor, W.; Weiss, J.; Taylor, W.I.; Uyeo, S.; Yajima, H.; Kosolapoff, Gennady M.; McQuillin, F.J.; Stewart, J.; Henbest, H.B.; Owen, T.C.; Nayler, P.; Whiting, M.C.; Cadogan, J.I.G., Notes, J. Chem. Soc., 1955, 2959, https://doi.org/10.1039/jr9550002959 . [all data]

Kosolapoff, 1955
Kosolapoff, G.M., Vapour Pressures and Densities of Some Lower Alkylphosphonates, J. Chem. Soc., 1955, 2964-2965. [all data]


Notes

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