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Bromotrifluoromethane

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil215.3KN/APCR Inc., 1990BS
Quantity Value Units Method Reference Comment
Tfus98.47KN/AMcDonald, Shrader, et al., 1959Metastable crystal phase; Uncertainty assigned by TRC = 0.05 K; TRC
Tfus98.72KN/AMcDonald, Shrader, et al., 1959Crystal phase 1 phase; Uncertainty assigned by TRC = 0.05 K; TRC
Quantity Value Units Method Reference Comment
Tc340.08KN/AHigashi, Uematsu, et al., 1985Uncertainty assigned by TRC = 0.02 K; by disappearance of the meniscus; TRC
Quantity Value Units Method Reference Comment
Pc39.56barN/AHigashi, Uematsu, et al., 1985Uncertainty assigned by TRC = 0.03 bar; TRC
Quantity Value Units Method Reference Comment
rhoc5.13mol/lN/AHigashi, Uematsu, et al., 1985Uncertainty assigned by TRC = 0.03 mol/l; TRC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
17.8291.AStephenson and Malanowski, 1987Based on data from 276. - 340. K.; AC
17.7252.AStephenson and Malanowski, 1987Based on data from 160. - 267. K.; AC
19.1180.N/AKudchadker, Kudchadker, et al., 1979Based on data from 165. - 216. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference
129.5 - 215.44.585521018.317.086McDonald, Shrader, et al., 1959, 2

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

McDonald, Shrader, et al., 1959
McDonald, R.A.; Shrader, S.A.; Stull, D.R., Vapor Pressures and Freezing Points of 30 Organics, J. Chem. Eng. Data, 1959, 4, 311. [all data]

Higashi, Uematsu, et al., 1985
Higashi, Y.; Uematsu, M.; Watanabe, K., Measurements of the Vapor-liquid Coexistence Curve and Determination of the Critical Parameters for Refrigerant 13B1, Bull. JSME, 1985, 28, 2660-6. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Kudchadker, Kudchadker, et al., 1979
Kudchadker, A.P.; Kudchadker, S.A.; Shukla, R.P.; Patnaik, P.R., Vapor pressures and boiling points of selected halomethanes, J. Phys. Chem. Ref. Data, 1979, 8, 2, 499, https://doi.org/10.1063/1.555600 . [all data]

McDonald, Shrader, et al., 1959, 2
McDonald, R.A.; Shrader, S.A.; Stull, D.R., Vapor Pressures and Freezing Points of Thirty Pure Organic Compounds., J. Chem. Eng. Data, 1959, 4, 4, 311-313, https://doi.org/10.1021/je60004a009 . [all data]


Notes

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