Fluorodichloromethane

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil282.0KN/APCR Inc., 1990BS
Quantity Value Units Method Reference Comment
Tc451.65KN/ABenning and McHarness, 1940Uncertainty assigned by TRC = 0.4 K; visual observation of the meniscus; TRC
Quantity Value Units Method Reference Comment
ρc5.07mol/lN/ABenning and McHarness, 1940Uncertainty assigned by TRC = 0.02 mol/l; by extrapolation of rectilinear diameter to critical temp.; TRC

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
6.24267.AStephenson and Malanowski, 1987Based on data from 225. - 282. K.; AC
6.05294.AStephenson and Malanowski, 1987Based on data from 279. - 344. K.; AC
5.78356.AStephenson and Malanowski, 1987Based on data from 341. - 399. K.; AC
5.76412.AStephenson and Malanowski, 1987Based on data from 397. - 450. K.; AC
6.26267.N/AStull, 1947Based on data from 181. - 282. K.; AC
8.77259.N/ABenning and McHarness, 1940, 2Based on data from 244. - 317. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
181.8 - 282.14.09494996.267-38.978Stull, 1947Coefficents calculated by NIST from author's data.
282.1 - 450.74.291501105.42-24.479Stull, 1947Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Benning and McHarness, 1940
Benning, A.F.; McHarness, R.C., Thermodynamic Properties of Fluorochloromethanes and -Ethanes densities and critical constants of three fluorochloromethanes and trifluorotrichloroethane, Ind. Eng. Chem., 1940, 32, 814. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Benning and McHarness, 1940, 2
Benning, A.F.; McHarness, R.C., Thermodynamic Properties of Fluorochloromethanes and -Ethanes Vapor Pressure of Three Fluorochloromethanes and Trifluorotichloroethane, Ind. Eng. Chem., 1940, 32, 4, 497-499, https://doi.org/10.1021/ie50364a011 . [all data]


Notes

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