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Ethene, 1,1-dichloro-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil304.2KN/AAldrich Chemical Company Inc., 1990BS
Tboil304.55KN/AKovac, Svoboda, et al., 1985Uncertainty assigned by TRC = 0.2 K; TRC
Tboil304.7KN/AMajer and Svoboda, 1985 
Quantity Value Units Method Reference Comment
Ttriple150.59KN/AHildenbrand, McDonald, et al., 1959Uncertainty assigned by TRC = 0.02 K; TRC
Quantity Value Units Method Reference Comment
Deltavap26.74kJ/molN/AMajer and Svoboda, 1985 
Deltavap26.74 ± 0.09kJ/molReviewManion, 2002derived from vapor pressure data of Hildebranld, Kramer, et al., 1959 plus a correction for non-ideality; DRB
Deltavap26.48 ± 0.08kJ/molCMansson, Ringner, et al., 1971ALS
Deltavap26.48 ± 0.084kJ/molVHildenbrand, McDonald, et al., 1959, 2ALS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
26.14304.7N/AMajer and Svoboda, 1985 
26.476298.15N/AHildenbrand, McDonald, et al., 1959, 2P = 80.03 kPa; DH
28.4260.AStephenson and Malanowski, 1987Based on data from 245. - 305. K. See also Hildenbrand and McDonald, 1959 and Dykyj, 1970.; AC

Entropy of vaporization

DeltavapS (J/mol*K) Temperature (K) Reference Comment
88.80298.15Hildenbrand, McDonald, et al., 1959, 2P; DH

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
244.79 - 305.74.10781104.726-35.403Hildenbrand, McDonald, et al., 1959, 2Coefficents calculated by NIST from author's data.

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
6.514150.59Hildenbrand, McDonald, et al., 1959, 2DH
6.51150.9Domalski and Hearing, 1996AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
43.26150.59Hildenbrand, McDonald, et al., 1959, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Kovac, Svoboda, et al., 1985
Kovac, A.; Svoboda, J.; Ondrus, I., Vapor-liquid equilibrium of some binary systems containing 1,1-dichloroethylene, Chem. Zvesti, 1985, 39, 6, 729. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Hildenbrand, McDonald, et al., 1959
Hildenbrand, D.L.; McDonald, R.A.; Kramer, W.R.; Stull, D.R., Thermodyn. and spectroscopic study of vinylidene chloride. I. Thermodyn. properties of the solid, liquid, and ideal gas, J. Chem. Phys., 1959, 30, 930-4. [all data]

Manion, 2002
Manion, J.A., Evaluated Enthalpies of Formation of the Stable Closed Shell C1 and C2 Chlorinated Hydrocarbons, J. Phys. Chem. Ref. Data, 2002, 31, 1, 123-172, https://doi.org/10.1063/1.1420703 . [all data]

Hildebranld, Kramer, et al., 1959
Hildebranld, D.L.; Kramer, W.K.; McDonald, R.A.; Stull, D.R., Thermodynamic and Spectroscopic Study of Vinylidene Chloride. I. Thermodynamic Properties of the Solid, Liquid, and Ideal Gas, J. Chem. Phys., 1959, 30, 4, 930, https://doi.org/10.1063/1.1730128 . [all data]

Mansson, Ringner, et al., 1971
Mansson, M.; Ringner, B.; Sunner, S., The enthalpies of combustion and formation of some simple chloroalkanes and chloralkenes 1,1,1-trichloroethane and 1,1-dichloroethene, J. Chem. Thermodyn., 1971, 3, 547-551. [all data]

Hildenbrand, McDonald, et al., 1959, 2
Hildenbrand, d.L.; McDonald, R.A.; Kramer, W.R.; Stull, D.R., Thermodynamic and spectroscopic study of vinylidene chloride. I. Thermodynamic properties of the solid, liquid, and ideal gas, J. Chem. Phys., 1959, 30, 930-934. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Hildenbrand and McDonald, 1959
Hildenbrand, D.L.; McDonald, R.A., The Heat of Vaporization and Vapor Pressure of Carbon Tetrachloride; The Entropy from Calorimetric Data., J. Phys. Chem., 1959, 63, 9, 1521-1522, https://doi.org/10.1021/j150579a053 . [all data]

Dykyj, 1970
Dykyj, J., Petrochemica, 1970, 10, 2, 51. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]


Notes

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