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2-Propanamine

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess

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Individual Reactions

(C3H210N+ bullet 22-Propanamine) + 2-Propanamine = (C3H210N+ bullet 32-Propanamine)

By formula: (C3H210N+ bullet 2C3H9N) + C3H9N = (C3H210N+ bullet 3C3H9N)

Quantity Value Units Method Reference Comment
Deltar67.8kJ/molHPMSZielinska and Wincel, 1974gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar164.J/mol*KHPMSZielinska and Wincel, 1974gas phase; Entropy change is questionable; M

(C3H210N+ bullet 2-Propanamine) + 2-Propanamine = (C3H210N+ bullet 22-Propanamine)

By formula: (C3H210N+ bullet C3H9N) + C3H9N = (C3H210N+ bullet 2C3H9N)

Quantity Value Units Method Reference Comment
Deltar82.8kJ/molHPMSZielinska and Wincel, 1974gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar178.J/mol*KHPMSZielinska and Wincel, 1974gas phase; Entropy change is questionable; M

C3H8N- + Hydrogen cation = 2-Propanamine

By formula: C3H8N- + H+ = C3H9N

Quantity Value Units Method Reference Comment
Deltar1662. ± 13.kJ/molG+TSBrauman and Blair, 1971gas phase; B
Quantity Value Units Method Reference Comment
Deltar1631. ± 13.kJ/molIMRBBrauman and Blair, 1971gas phase; B

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Zielinska and Wincel, 1974
Zielinska, T.J.; Wincel, H., Gas - Phase Solvation of Protonated Aliphatic Amines: Methyl, Ethyl, n - Propyl, and Iso - Propylamine, Chem. Phys. Lett., 1974, 25, 354. [all data]

Brauman and Blair, 1971
Brauman, J.I.; Blair, L.K., Gas phase acidities of amines, J. Am. Chem. Soc., 1971, 93, 3911. [all data]


Notes

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