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Dimethyl sulfide

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Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C2H6S+ + Dimethyl sulfide = (C2H6S+ bullet Dimethyl sulfide)

By formula: C2H6S+ + C2H6S = (C2H6S+ bullet C2H6S)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Deltar112.kJ/molDTDeng, Illies, et al., 1995gas phase; «DELTA»rH(0K) = 115. kJ/mol; M
Quantity Value Units Method Reference Comment
Deltar111.J/mol*KDTDeng, Illies, et al., 1995gas phase; «DELTA»rH(0K) = 115. kJ/mol; M

C2H7S+ + Dimethyl sulfide = (C2H7S+ bullet Dimethyl sulfide)

By formula: C2H7S+ + C2H6S = (C2H7S+ bullet C2H6S)

Quantity Value Units Method Reference Comment
Deltar110.kJ/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; «DELTA»rH?, inconsistent with other protonated sulfur dimers; M
Quantity Value Units Method Reference Comment
Deltar119.J/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; «DELTA»rH?, inconsistent with other protonated sulfur dimers; M

C4H9+ + Dimethyl sulfide = (C4H9+ bullet Dimethyl sulfide)

By formula: C4H9+ + C2H6S = (C4H9+ bullet C2H6S)

Quantity Value Units Method Reference Comment
Deltar185.kJ/molPHPMSMeot-Ner (Mautner) and Sieck, 1991gas phase; condensation; M
Quantity Value Units Method Reference Comment
Deltar178.J/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1991gas phase; condensation; M

Lithium ion (1+) + Dimethyl sulfide = (Lithium ion (1+) bullet Dimethyl sulfide)

By formula: Li+ + C2H6S = (Li+ bullet C2H6S)

Quantity Value Units Method Reference Comment
Deltar137.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Sodium ion (1+) + Dimethyl sulfide = (Sodium ion (1+) bullet Dimethyl sulfide)

By formula: Na+ + C2H6S = (Na+ bullet C2H6S)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
59.4298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Deng, Illies, et al., 1995
Deng, Y.; Illies, A.J.; James, M.A.; McKee, M.L.; Peschke, M., A Definitive Investigation of the Gas-Phase Two-Center Three-electron Bond in [H2S:SH2+], [Me2S:SMe2]+, and [Et2S:SEt2]+: Therory and Experiment, J. Am. Chem. Soc., 1995, 117, 1, 420, https://doi.org/10.1021/ja00106a048 . [all data]

Meot-Ner (Mautner) and Sieck, 1985
Meot-Ner (Mautner), M.; Sieck, L.W., The Ionic Hydrogen Bond and Ion Solvation. 4. SH+ O and NH+ S Bonds. Correlations with Proton Affinity. Mutual Effects of Weak and Strong Ligands in Mixed Clusters, J. Phys. Chem., 1985, 89, 24, 5222, https://doi.org/10.1021/j100270a021 . [all data]

Meot-Ner (Mautner) and Sieck, 1991
Meot-Ner (Mautner), M.; Sieck, L.W., Proton affinity ladders from variable-temperature equilibrium measurements. 1. A reevaluation of the upper proton affinity range, J. Am. Chem. Soc., 1991, 113, 12, 4448, https://doi.org/10.1021/ja00012a012 . [all data]

Staley and Beauchamp, 1975
Staley, R.H.; Beauchamp, J.L., Intrinsic Acid - Base Properties of Molecules. Binding Energies of Li+ to pi - and n - Donor Bases, J. Am. Chem. Soc., 1975, 97, 20, 5920, https://doi.org/10.1021/ja00853a050 . [all data]

Dzidic and Kebarle, 1970
Dzidic, I.; Kebarle, P., Hydration of the Alkali Ions in the Gas Phase. Enthalpies and Entropies of Reactions M+(H2O)n-1 + H2O = M+(H2O)n, J. Phys. Chem., 1970, 74, 7, 1466, https://doi.org/10.1021/j100702a013 . [all data]

McMahon and Ohanessian, 2000
McMahon, T.B.; Ohanessian, G., An Experimental and Ab Initio Study of the Nature of the Binding in Gas-Phase Complexes of Sodium Ions, Chem. Eur. J., 2000, 6, 16, 2931, https://doi.org/10.1002/1521-3765(20000818)6:16<2931::AID-CHEM2931>3.0.CO;2-7 . [all data]


Notes

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