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Carbon disulfide

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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas27.949kcal/molReviewChase, 1998Data last reviewed in December, 1976
Deltafgas27.98 ± 0.19kcal/molCcrGood, Lacina, et al., 1961ALS
Quantity Value Units Method Reference Comment
Deltacgas-265.8kcal/molCcbGuerin, Marthe, et al., 1949ALS
Quantity Value Units Method Reference Comment
gas,1 bar56.879cal/mol*KReviewChase, 1998Data last reviewed in December, 1976

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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View table.

Temperature (K) 298. - 1000.1000. - 6000.
A 8.56929114.63980
B 12.545700.329547
C -9.760381-0.033585
D 2.8684400.002219
E -0.053736-0.775345
F 24.7378121.52750
G 63.6137071.56049
H 27.9501027.95010
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in December, 1976 Data last reviewed in December, 1976

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid21.37 ± 0.17kcal/molCcrGood, Lacina, et al., 1961ALS
Quantity Value Units Method Reference Comment
Deltacliquid-403.24 ± 0.12kcal/molCcrGood, Lacina, et al., 1961Reanalyzed by Cox and Pilcher, 1970, Original value = -402.09 ± 0.12 kcal/mol; ALS
Quantity Value Units Method Reference Comment
liquid36.09cal/mol*KN/ABrown and Manov, 1937DH

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
18.88298.Staveley, Tupman, et al., 1955T = 286 to 317 K.; DH
17.90294.81Zhdanov, 1945T = 7 to 31°C. Value is unsmoothed experimental datum.; DH
18.6293.Mazur, 1939T = -100 to 20°C.; DH
18.2301.2Phillip, 1939DH
18.17297.43Brown and Manov, 1937T = 15 to 297 K. Value is unsmoothed experimental datum.; DH

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil319.2 ± 0.6KAVGN/AAverage of 13 out of 14 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus161. ± 3.KAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Ttriple161.11KN/ABrown and Manov, 1937, 2Uncertainty assigned by TRC = 0.02 K; TRC
Ttriple161.59KN/AStull, 1937Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Tc552.KN/AMajer and Svoboda, 1985 
Quantity Value Units Method Reference Comment
Deltavap6.6 ± 0.1kcal/molAVGN/AAverage of 6 values; Individual data points

Enthalpy of vaporization

DeltavapH (kcal/mol) Temperature (K) Method Reference Comment
6.391319.4N/AMajer and Svoboda, 1985 
6.86270.N/ADykyj, Svoboda, et al., 1999Based on data from 255. - 354. K.; AC
6.48369.N/ADykyj, Svoboda, et al., 1999Based on data from 354. - 552. K.; AC
6.81275.AStephenson and Malanowski, 1987Based on data from 260. - 353. K.; AC
6.55353.AStephenson and Malanowski, 1987Based on data from 338. - 408. K.; AC
6.45403.AStephenson and Malanowski, 1987Based on data from 388. - 497. K.; AC
6.86505.AStephenson and Malanowski, 1987Based on data from 490. - 533. K.; AC
6.86270.EBBoublík and Aim, 1972Based on data from 255. - 318. K. See also Stephenson and Malanowski, 1987.; AC
6.72292.EBWaddington, Smith, et al., 1962Based on data from 277. - 353. K.; AC
6.72 ± 0.02282.CWaddington, Smith, et al., 1962AC
6.38 ± 0.02319.CWaddington, Smith, et al., 1962AC
6.60318.N/AThomson, 1946Based on data from 303. - 358. K.; AC

Enthalpy of vaporization

ΔvapH = A exp(-βTr) (1 − Tr)β
    ΔvapH = Enthalpy of vaporization (at saturation pressure) (kcal/mol)
    Tr = reduced temperature (T / Tc)

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Temperature (K) A (kcal/mol) beta Tc (K) Reference Comment
282. - 319.8.8600.2264552.Majer and Svoboda, 1985 

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
276.74 - 353.084.061121168.62-31.616Waddington, Smith, et al., 1962Coefficents calculated by NIST from author's data.

Enthalpy of fusion

DeltafusH (kcal/mol) Temperature (K) Reference Comment
1.049161.11Brown and Manov, 1937DH

Entropy of fusion

DeltafusS (cal/mol*K) Temperature (K) Reference Comment
6.511161.11Brown and Manov, 1937DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Chlorine anion + Carbon disulfide = (Chlorine anion bullet Carbon disulfide)

By formula: Cl- + CS2 = (Cl- bullet CS2)

Quantity Value Units Method Reference Comment
Deltar8.80 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Deltar11.7 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar13.9cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Deltar20.cal/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar4.6 ± 2.2kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B
Deltar5.7 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M

CS2- + Carbon disulfide = (CS2- bullet Carbon disulfide)

By formula: CS2- + CS2 = (CS2- bullet CS2)

Quantity Value Units Method Reference Comment
Deltar21.9 ± 1.5kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B,M
Deltar4.4 ± 1.1kcal/molN/ATsukuda, Hirose, et al., 1997gas phase; EA given is Vertical Detachment Energy. Affinity is difference from next lower Vertical De; B
Deltar4.10 ± 0.60kcal/molLPESBowen and Eaton, 1988gas phase; B
Quantity Value Units Method Reference Comment
Deltar30.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar13.0 ± 2.5kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B

(CS2- bullet Carbon disulfide) + Carbon disulfide = (CS2- bullet 2Carbon disulfide)

By formula: (CS2- bullet CS2) + CS2 = (CS2- bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar4.60 ± 0.70kcal/molN/ATsukuda, Hirose, et al., 1997gas phase; EA given is Vertical Detachment Energy. Affinity is difference from next lower Vertical De; B
Deltar6.4 ± 1.4kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar21.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar0.1 ± 3.3kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B

S2+ + Carbon disulfide = (S2+ bullet Carbon disulfide)

By formula: S2+ + CS2 = (S2+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar30.9kcal/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Deltar28.8kcal/molPIOno, Linn, et al., 1981gas phase; M
Deltar21.9kcal/molPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; equilibrium uncertain; M
Quantity Value Units Method Reference Comment
Deltar25.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Deltar17.1cal/mol*KPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; equilibrium uncertain; M

(Fluorine anion bullet 2Carbon disulfide) + Carbon disulfide = (Fluorine anion bullet 3Carbon disulfide)

By formula: (F- bullet 2CS2) + CS2 = (F- bullet 3CS2)

Quantity Value Units Method Reference Comment
Deltar5.4 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; Estimated entropy; single temperature measurement; B,M
Quantity Value Units Method Reference Comment
Deltar17.cal/mol*KN/AHiraoka, Fujimaki, et al., 1993gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar0.3 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; Estimated entropy; single temperature measurement; B

Fluorine anion + Carbon disulfide = (Fluorine anion bullet Carbon disulfide)

By formula: F- + CS2 = (F- bullet CS2)

Quantity Value Units Method Reference Comment
Deltar35.0 ± 1.5kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Deltar31.3 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B
Quantity Value Units Method Reference Comment
Deltar28.2cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar26.5 ± 1.5kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B
Deltar24.1 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B

CS2+ + Carbon disulfide = (CS2+ bullet Carbon disulfide)

By formula: CS2+ + CS2 = (CS2+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar24.9kcal/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Deltar21.9kcal/molPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; M
Deltar17.5kcal/molPIOno, Linn, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Deltar21.9cal/mol*KPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; M

(CS2+ bullet 2Carbon disulfide) + Carbon disulfide = (CS2+ bullet 3Carbon disulfide)

By formula: (CS2+ bullet 2CS2) + CS2 = (CS2+ bullet 3CS2)

Quantity Value Units Method Reference Comment
Deltar4.9kcal/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; Entropy change calculated or estimated; M
Deltar3.9kcal/molPIOno, Linn, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Deltar17.cal/mol*KN/AHiraoka, Fujimaki, et al., 1994, 2gas phase; Entropy change calculated or estimated; M

(Chlorine anion bullet 3Carbon disulfide) + Carbon disulfide = (Chlorine anion bullet 4Carbon disulfide)

By formula: (Cl- bullet 3CS2) + CS2 = (Cl- bullet 4CS2)

Quantity Value Units Method Reference Comment
Deltar6.8 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; Estimated entropy; single temperature measurement; B
Quantity Value Units Method Reference Comment
Deltar-0.1 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; Estimated entropy; single temperature measurement; B

CHS2+ + Carbon disulfide = (CHS2+ bullet Carbon disulfide)

By formula: CHS2+ + CS2 = (CHS2+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar9.0kcal/molPHPMSHiraoka, Fujimaki, et al., 1993, 2gas phase; M
Deltar11.1kcal/molPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; M
Quantity Value Units Method Reference Comment
Deltar14.5cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1993, 2gas phase; M
Deltar26.4cal/mol*KPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; M

(Chlorine anion bullet 2Carbon disulfide) + Carbon disulfide = (Chlorine anion bullet 3Carbon disulfide)

By formula: (Cl- bullet 2CS2) + CS2 = (Cl- bullet 3CS2)

Quantity Value Units Method Reference Comment
Deltar7.20 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar21.3cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar0.8 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

(Chlorine anion bullet Carbon disulfide) + Carbon disulfide = (Chlorine anion bullet 2Carbon disulfide)

By formula: (Cl- bullet CS2) + CS2 = (Cl- bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar7.70 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar15.8cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar3.0 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

(Fluorine anion bullet Carbon disulfide) + Carbon disulfide = (Fluorine anion bullet 2Carbon disulfide)

By formula: (F- bullet CS2) + CS2 = (F- bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar6.70 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar15.3cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar2.1 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

(Iodide bullet Carbon disulfide) + Carbon disulfide = (Iodide bullet 2Carbon disulfide)

By formula: (I- bullet CS2) + CS2 = (I- bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar6.80 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar21.7cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar0.2 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

(Bromine anion bullet Carbon disulfide) + Carbon disulfide = (Bromine anion bullet 2Carbon disulfide)

By formula: (Br- bullet CS2) + CS2 = (Br- bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar7.30 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar20.4cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.2 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

Iodide + Carbon disulfide = (Iodide bullet Carbon disulfide)

By formula: I- + CS2 = (I- bullet CS2)

Quantity Value Units Method Reference Comment
Deltar7.40 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar16.7cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar2.4 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

Bromine anion + Carbon disulfide = (Bromine anion bullet Carbon disulfide)

By formula: Br- + CS2 = (Br- bullet CS2)

Quantity Value Units Method Reference Comment
Deltar8.30 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar13.0cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar4.4 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

(S2+ bullet 2Carbon disulfide) + Carbon disulfide = (S2+ bullet 3Carbon disulfide)

By formula: (S2+ bullet 2CS2) + CS2 = (S2+ bullet 3CS2)

Quantity Value Units Method Reference Comment
Deltar5.5kcal/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar17.cal/mol*KN/AHiraoka, Fujimaki, et al., 1994, 2gas phase; Entropy change calculated or estimated; M

(S2- bullet Carbon disulfide) + Carbon disulfide = (S2- bullet 2Carbon disulfide)

By formula: (S2- bullet CS2) + CS2 = (S2- bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar6.1kcal/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/AHiraoka, Fujimaki, et al., 1994, 2gas phase; Entropy change calculated or estimated; M

(CS2+ bullet Carbon disulfide) + Carbon disulfide = (CS2+ bullet 2Carbon disulfide)

By formula: (CS2+ bullet CS2) + CS2 = (CS2+ bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar6.5kcal/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Deltar4.4kcal/molPIOno, Linn, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Deltar21.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M

Methyl cation + Carbon disulfide = (Methyl cation bullet Carbon disulfide)

By formula: CH3+ + CS2 = (CH3+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar60.2kcal/molPHPMSMcMahon, Heinis, et al., 1988gas phase; switching reaction(CH3+)N2, Entropy change calculated or estimated, uses MCA(N2) = 48.3 kcal/mol; Foster, Williamson, et al., 1974; M

(CS2- bullet 3Carbon disulfide) + Carbon disulfide = (CS2- bullet 4Carbon disulfide)

By formula: (CS2- bullet 3CS2) + CS2 = (CS2- bullet 4CS2)

Quantity Value Units Method Reference Comment
Deltar2.3 ± 6.7kcal/molN/ATsukuda, Hirose, et al., 1997gas phase; EA given is Vertical Detachment Energy. Affinity is difference from next lower Vertical De; B

(CS2- bullet 4Carbon disulfide) + Carbon disulfide = (CS2- bullet 5Carbon disulfide)

By formula: (CS2- bullet 4CS2) + CS2 = (CS2- bullet 5CS2)

Quantity Value Units Method Reference Comment
Deltar1.8 ± 6.6kcal/molN/ATsukuda, Hirose, et al., 1997gas phase; EA given is Vertical Detachment Energy. Affinity is difference from next lower Vertical De; B

(CS2- bullet 2Carbon disulfide) + Carbon disulfide = (CS2- bullet 3Carbon disulfide)

By formula: (CS2- bullet 2CS2) + CS2 = (CS2- bullet 3CS2)

Quantity Value Units Method Reference Comment
Deltar-23.40kcal/molN/ATsukuda, Hirose, et al., 1997gas phase; EA given is Vertical Detachment Energy. Affinity is difference from next lower Vertical De; B

(S2+ bullet Carbon disulfide) + Carbon disulfide = (S2+ bullet 2Carbon disulfide)

By formula: (S2+ bullet CS2) + CS2 = (S2+ bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar8.3kcal/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M

(CHS2+ bullet Carbon disulfide) + Carbon disulfide = (CHS2+ bullet 2Carbon disulfide)

By formula: (CHS2+ bullet CS2) + CS2 = (CHS2+ bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar4.7kcal/molPHPMSHiraoka, Fujimaki, et al., 1993, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar14.3cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1993, 2gas phase; M

S2- + Carbon disulfide = (S2- bullet Carbon disulfide)

By formula: S2- + CS2 = (S2- bullet CS2)

Quantity Value Units Method Reference Comment
Deltar19.1kcal/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar29.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M

C6H6+ + Carbon disulfide = (C6H6+ bullet Carbon disulfide)

By formula: C6H6+ + CS2 = (C6H6+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar12.2kcal/molPHPMSMeot-Ner (Mautner), Hamlet, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
Deltar24.cal/mol*KPHPMSMeot-Ner (Mautner), Hamlet, et al., 1978gas phase; M

(CS2+ bullet 3Carbon disulfide) + Carbon disulfide = (CS2+ bullet 4Carbon disulfide)

By formula: (CS2+ bullet 3CS2) + CS2 = (CS2+ bullet 4CS2)

Quantity Value Units Method Reference Comment
Deltar2.6kcal/molPIOno, Linn, et al., 1980gas phase; M

(Iron ion (1+) bullet Carbon disulfide) + Carbon disulfide = (Iron ion (1+) bullet 2Carbon disulfide)

By formula: (Fe+ bullet CS2) + CS2 = (Fe+ bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar44.9 ± 1.4kcal/molCIDTRodgers and Armentrout, 2000RCD

CS+ + Carbon disulfide = (CS+ bullet Carbon disulfide)

By formula: CS+ + CS2 = (CS+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar36.0kcal/molPIOno, Linn, et al., 1981gas phase; M

Sulfur cation + Carbon disulfide = (Sulfur cation bullet Carbon disulfide)

By formula: S+ + CS2 = (S+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar39.7kcal/molPIGress, Linn, et al., 1980gas phase; M

trithiocarbonic acid = Carbon disulfide + Hydrogen sulfide

By formula: CH2S3 = CS2 + H2S

Quantity Value Units Method Reference Comment
Deltar10.6 ± 0.3kcal/molCmGattow and Krebes, 1963liquid phase; ALS

Iron ion (1+) + Carbon disulfide = (Iron ion (1+) bullet Carbon disulfide)

By formula: Fe+ + CS2 = (Fe+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar39.7 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD

Vanadium ion (1+) + Carbon disulfide = (Vanadium ion (1+) bullet Carbon disulfide)

By formula: V+ + CS2 = (V+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar27.2 ± 3.0kcal/molCIDTSchroeder, Kretzschmar, et al., 2003RCD

Molybdenum ion (1+) + Carbon disulfide = (Molybdenum ion (1+) bullet Carbon disulfide)

By formula: Mo+ + CS2 = (Mo+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar16.1 ± 3.0kcal/molCIDTSchroeder, Kretzschmar, et al., 2003RCD

Henry's Law data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Rolf Sander

Henry's Law constant (water solution)

kH(T) = H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
H = Henry's law constant for solubility in water at 298.15 K (mol/kg*bar)
d(ln(kH))/d(1/T) = Temperature dependence constant (K)

H (mol/kg*bar) d(ln(kH))/d(1/T) (K) Method Reference Comment
0.0552800.MN/A 
0.051 QN/A missing citation give several references for the Henry's law constants but don't assign them to specific species.
0.0751200.XN/A 
0.0444100.XN/AAs quoted by missing citation.
0.0564000.XRex, 1906As quoted by missing citation.

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to CS2+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)10.073 ± 0.005eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)163.0kcal/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity157.2kcal/molN/AHunter and Lias, 1998HL

Electron affinity determinations

EA (eV) Method Reference Comment
0.5525 ± 0.0013N/ACavanagh, Gibson, et al., 2012poor Franck-Condon overlap makes previous LPES studies too bound; B
0.580 ± 0.050LPESMisaizu, Tsunoyama, et al., 2004Vertical Detachment Energy: 1.27±0.10 eV; B
0.51 ± 0.10IMREChowdhury, Heinis, et al., 1986«DELTA»Gea(423 K) = -12.7 kcal/mol; «DELTA»Sea (estimated) = +2.0 eu.; B
<0.799982LPESScheidt and Weinkauf, 1997B
0.000694N/ACompton, Dunning, et al., 1996Quadrupole-bound state; B
0.60 ± 0.10ECDChen and Wentworth, 1983B
0.50 ± 0.20EndoHughes, Lifschitz, et al., 1973B
1.460 ± 0.020LPESTsukuda, Hirose, et al., 1997EA given is Vertical Detachment Energy. Poor Franck-Condon overlap; B
0.89 ± 0.20LPESOakes and Ellison, 1986The discrepancy with equilibrium has not been resolved. Poor Franck-Condon overlap.; B
1.00 ± 0.20NBIECompton, Reinhardt, et al., 1975B
0.94 ± 0.32IMRBKraus, Muller-Duysing, et al., 1961Between NH2-, C-; B

Ionization energy determinations

IE (eV) Method Reference Comment
10.078TEFischer, Lochschmidt, et al., 1993LL
10.080 ± 0.002PEWang, Reutt, et al., 1988LL
10.077PEReineck, Wannberg, et al., 1984LBLHLM
10. ± 1.EICarnovale, Hitchcock, et al., 1982LBLHLM
10.06PEKimura, Katsumata, et al., 1981LLK
10.079 ± 0.003PEPotts and Fattahallah, 1980LLK
10.0685 ± 0.0020SOno, Linn, et al., 1980LLK
10.05 ± 0.08EIMiletic, Eres, et al., 1980LLK
10.06 ± 0.025EIHubin-Franskin, Marmet, et al., 1980LLK
10.074PEHubin-Franskin, Delwiche, et al., 1980LLK
10.125PITrott, Blais, et al., 1979LLK
10.076 ± 0.005PICoppens, Reynaert, et al., 1979LLK
10.077PIFrey, Gotchev, et al., 1978LLK
10.074 ± 0.005PIDrowart, Smets, et al., 1978LLK
10.1 ± 0.1EIHildenbrand, 1975LLK
10.06PENatalis, 1973LLK
10.06 ± 0.01PEFrost, Lee, et al., 1973LLK
10.06PEKroto and Suffolk, 1972LLK
10.07 ± 0.10EIHildenbrand, 1972LLK
10.068 ± 0.005PEBrundle and Turner, 1969RDSH
10.122 ± 0.005PEBrundle and Turner, 1969RDSH
10.13PIMomigny and Delwiche, 1968RDSH
10.075PIMomigny and Delwiche, 1968RDSH
10.08 ± 0.01PEEland and Danby, 1968RDSH
10.14 ± 0.01PEEland and Danby, 1968RDSH
10.059 ± 0.008PIDibeler and Walker, 1967RDSH
10.112 ± 0.008PIDibeler and Walker, 1967RDSH
10.080STanaka, Jursa, et al., 1960RDSH
10.134STanaka, Jursa, et al., 1960RDSH
10.079SPrice and Simpson, 1938RDSH
10.133SPrice and Simpson, 1938RDSH
10.09PESchweig and Thiel, 1974Vertical value; LLK
10.10PEPotts and Williams, 1974Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C+10. ± 1.?EICarnovale, Hitchcock, et al., 1982LBLHLM
C+20.0 ± 0.1S2EIFerreira and Fronteira_e_Silva, 1970RDSH
C+19.9 ± 0.6S2EICuthbert, Farren, et al., 1968RDSH
C+24.0 ± 0.52SEICuthbert, Farren, et al., 1968RDSH
CS+16. ± 1.SEICarnovale, Hitchcock, et al., 1982LBLHLM
CS+14.10 ± 0.08SEIMiletic, Eres, et al., 1980LLK
CS+15.75 ± 0.02SPICoppens, Reynaert, et al., 1979LLK
CS+15.94 ± 0.07SEIHubin-Franskin, Huard, et al., 1978LLK
CS+13.9 ± 0.1S(-)EIHubin-Franskin, Huard, et al., 1978LLK
CS+15.75 ± 0.02SPIDrowart, Smets, et al., 1978LLK
CS+13.64 ± 0.02S(-)PIDrowart, Smets, et al., 1978LLK
CS+14.5S(-)EIHubin-Franskin, Locht, et al., 1976LLK
CS+14.7SEIHubin-Franskin, Locht, et al., 1976LLK
CS+16. ± 1.SEIMomigny, Mathieu, et al., 1973LLK
CS+16.15 ± 0.10SEIMomigny and Delwiche, 1968RDSH
CS+9.6 ± 0.6SEICuthbert, Farren, et al., 1968RDSH
CS+16.16 ± 0.01SPIDibeler and Walker, 1967RDSH
S+15. ± 1.CSEICarnovale, Hitchcock, et al., 1982LBLHLM
S+13.40 ± 0.08CSEIMiletic, Eres, et al., 1980LLK
S+14.80 ± 0.02CSPICoppens, Reynaert, et al., 1979LLK
S+14.88 ± 0.05CSEIHubin-Franskin, Huard, et al., 1978LLK
S+14.80 ± 0.02CSPIDrowart, Smets, et al., 1978LLK
S+13.35CSEIHubin-Franskin, Locht, et al., 1976LLK
S+15. ± 1.CSEIMomigny, Mathieu, et al., 1973LLK
S+17. ± 1.CSEIMomigny, Mathieu, et al., 1973LLK
S+14.8CSPIDibeler and Walker, 1967RDSH
S2+17. ± 1.CEICarnovale, Hitchcock, et al., 1982LBLHLM
S2+16.82 ± 0.02CPICoppens, Reynaert, et al., 1979LLK
S2+16.88 ± 0.02CPIDrowart, Smets, et al., 1978LLK
S2+14.9 ± 0.3CEIFerreira and Fronteira_e_Silva, 1970RDSH
S2+18.2 ± 0.9CEICuthbert, Farren, et al., 1968RDSH
S2+9.6 ± 0.6CEICuthbert, Farren, et al., 1968RDSH

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Bromine anion + Carbon disulfide = (Bromine anion bullet Carbon disulfide)

By formula: Br- + CS2 = (Br- bullet CS2)

Quantity Value Units Method Reference Comment
Deltar8.30 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar13.0cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar4.4 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

(Bromine anion bullet Carbon disulfide) + Carbon disulfide = (Bromine anion bullet 2Carbon disulfide)

By formula: (Br- bullet CS2) + CS2 = (Br- bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar7.30 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar20.4cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.2 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

CHS2+ + Carbon disulfide = (CHS2+ bullet Carbon disulfide)

By formula: CHS2+ + CS2 = (CHS2+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar9.0kcal/molPHPMSHiraoka, Fujimaki, et al., 1993, 2gas phase; M
Deltar11.1kcal/molPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; M
Quantity Value Units Method Reference Comment
Deltar14.5cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1993, 2gas phase; M
Deltar26.4cal/mol*KPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; M

(CHS2+ bullet Carbon disulfide) + Carbon disulfide = (CHS2+ bullet 2Carbon disulfide)

By formula: (CHS2+ bullet CS2) + CS2 = (CHS2+ bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar4.7kcal/molPHPMSHiraoka, Fujimaki, et al., 1993, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar14.3cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1993, 2gas phase; M

Methyl cation + Carbon disulfide = (Methyl cation bullet Carbon disulfide)

By formula: CH3+ + CS2 = (CH3+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar60.2kcal/molPHPMSMcMahon, Heinis, et al., 1988gas phase; switching reaction(CH3+)N2, Entropy change calculated or estimated, uses MCA(N2) = 48.3 kcal/mol; Foster, Williamson, et al., 1974; M

CS+ + Carbon disulfide = (CS+ bullet Carbon disulfide)

By formula: CS+ + CS2 = (CS+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar36.0kcal/molPIOno, Linn, et al., 1981gas phase; M

CS2+ + Carbon disulfide = (CS2+ bullet Carbon disulfide)

By formula: CS2+ + CS2 = (CS2+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar24.9kcal/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Deltar21.9kcal/molPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; M
Deltar17.5kcal/molPIOno, Linn, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Deltar21.9cal/mol*KPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; M

(CS2+ bullet Carbon disulfide) + Carbon disulfide = (CS2+ bullet 2Carbon disulfide)

By formula: (CS2+ bullet CS2) + CS2 = (CS2+ bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar6.5kcal/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Deltar4.4kcal/molPIOno, Linn, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Deltar21.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M

(CS2+ bullet 2Carbon disulfide) + Carbon disulfide = (CS2+ bullet 3Carbon disulfide)

By formula: (CS2+ bullet 2CS2) + CS2 = (CS2+ bullet 3CS2)

Quantity Value Units Method Reference Comment
Deltar4.9kcal/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; Entropy change calculated or estimated; M
Deltar3.9kcal/molPIOno, Linn, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Deltar17.cal/mol*KN/AHiraoka, Fujimaki, et al., 1994, 2gas phase; Entropy change calculated or estimated; M

(CS2+ bullet 3Carbon disulfide) + Carbon disulfide = (CS2+ bullet 4Carbon disulfide)

By formula: (CS2+ bullet 3CS2) + CS2 = (CS2+ bullet 4CS2)

Quantity Value Units Method Reference Comment
Deltar2.6kcal/molPIOno, Linn, et al., 1980gas phase; M

CS2- + Carbon disulfide = (CS2- bullet Carbon disulfide)

By formula: CS2- + CS2 = (CS2- bullet CS2)

Quantity Value Units Method Reference Comment
Deltar21.9 ± 1.5kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B,M
Deltar4.4 ± 1.1kcal/molN/ATsukuda, Hirose, et al., 1997gas phase; EA given is Vertical Detachment Energy. Affinity is difference from next lower Vertical De; B
Deltar4.10 ± 0.60kcal/molLPESBowen and Eaton, 1988gas phase; B
Quantity Value Units Method Reference Comment
Deltar30.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar13.0 ± 2.5kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B

(CS2- bullet Carbon disulfide) + Carbon disulfide = (CS2- bullet 2Carbon disulfide)

By formula: (CS2- bullet CS2) + CS2 = (CS2- bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar4.60 ± 0.70kcal/molN/ATsukuda, Hirose, et al., 1997gas phase; EA given is Vertical Detachment Energy. Affinity is difference from next lower Vertical De; B
Deltar6.4 ± 1.4kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar21.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar0.1 ± 3.3kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B

(CS2- bullet 2Carbon disulfide) + Carbon disulfide = (CS2- bullet 3Carbon disulfide)

By formula: (CS2- bullet 2CS2) + CS2 = (CS2- bullet 3CS2)

Quantity Value Units Method Reference Comment
Deltar-23.40kcal/molN/ATsukuda, Hirose, et al., 1997gas phase; EA given is Vertical Detachment Energy. Affinity is difference from next lower Vertical De; B

(CS2- bullet 3Carbon disulfide) + Carbon disulfide = (CS2- bullet 4Carbon disulfide)

By formula: (CS2- bullet 3CS2) + CS2 = (CS2- bullet 4CS2)

Quantity Value Units Method Reference Comment
Deltar2.3 ± 6.7kcal/molN/ATsukuda, Hirose, et al., 1997gas phase; EA given is Vertical Detachment Energy. Affinity is difference from next lower Vertical De; B

(CS2- bullet 4Carbon disulfide) + Carbon disulfide = (CS2- bullet 5Carbon disulfide)

By formula: (CS2- bullet 4CS2) + CS2 = (CS2- bullet 5CS2)

Quantity Value Units Method Reference Comment
Deltar1.8 ± 6.6kcal/molN/ATsukuda, Hirose, et al., 1997gas phase; EA given is Vertical Detachment Energy. Affinity is difference from next lower Vertical De; B

C6H6+ + Carbon disulfide = (C6H6+ bullet Carbon disulfide)

By formula: C6H6+ + CS2 = (C6H6+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar12.2kcal/molPHPMSMeot-Ner (Mautner), Hamlet, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
Deltar24.cal/mol*KPHPMSMeot-Ner (Mautner), Hamlet, et al., 1978gas phase; M

Chlorine anion + Carbon disulfide = (Chlorine anion bullet Carbon disulfide)

By formula: Cl- + CS2 = (Cl- bullet CS2)

Quantity Value Units Method Reference Comment
Deltar8.80 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Deltar11.7 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar13.9cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Deltar20.cal/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar4.6 ± 2.2kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B
Deltar5.7 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M

(Chlorine anion bullet Carbon disulfide) + Carbon disulfide = (Chlorine anion bullet 2Carbon disulfide)

By formula: (Cl- bullet CS2) + CS2 = (Cl- bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar7.70 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar15.8cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar3.0 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

(Chlorine anion bullet 2Carbon disulfide) + Carbon disulfide = (Chlorine anion bullet 3Carbon disulfide)

By formula: (Cl- bullet 2CS2) + CS2 = (Cl- bullet 3CS2)

Quantity Value Units Method Reference Comment
Deltar7.20 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar21.3cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar0.8 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

(Chlorine anion bullet 3Carbon disulfide) + Carbon disulfide = (Chlorine anion bullet 4Carbon disulfide)

By formula: (Cl- bullet 3CS2) + CS2 = (Cl- bullet 4CS2)

Quantity Value Units Method Reference Comment
Deltar6.8 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; Estimated entropy; single temperature measurement; B
Quantity Value Units Method Reference Comment
Deltar-0.1 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; Estimated entropy; single temperature measurement; B

Fluorine anion + Carbon disulfide = (Fluorine anion bullet Carbon disulfide)

By formula: F- + CS2 = (F- bullet CS2)

Quantity Value Units Method Reference Comment
Deltar35.0 ± 1.5kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Deltar31.3 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B
Quantity Value Units Method Reference Comment
Deltar28.2cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar26.5 ± 1.5kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B
Deltar24.1 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B

(Fluorine anion bullet Carbon disulfide) + Carbon disulfide = (Fluorine anion bullet 2Carbon disulfide)

By formula: (F- bullet CS2) + CS2 = (F- bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar6.70 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar15.3cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar2.1 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

(Fluorine anion bullet 2Carbon disulfide) + Carbon disulfide = (Fluorine anion bullet 3Carbon disulfide)

By formula: (F- bullet 2CS2) + CS2 = (F- bullet 3CS2)

Quantity Value Units Method Reference Comment
Deltar5.4 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; Estimated entropy; single temperature measurement; B,M
Quantity Value Units Method Reference Comment
Deltar17.cal/mol*KN/AHiraoka, Fujimaki, et al., 1993gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar0.3 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; Estimated entropy; single temperature measurement; B

Iron ion (1+) + Carbon disulfide = (Iron ion (1+) bullet Carbon disulfide)

By formula: Fe+ + CS2 = (Fe+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar39.7 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD

(Iron ion (1+) bullet Carbon disulfide) + Carbon disulfide = (Iron ion (1+) bullet 2Carbon disulfide)

By formula: (Fe+ bullet CS2) + CS2 = (Fe+ bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar44.9 ± 1.4kcal/molCIDTRodgers and Armentrout, 2000RCD

Iodide + Carbon disulfide = (Iodide bullet Carbon disulfide)

By formula: I- + CS2 = (I- bullet CS2)

Quantity Value Units Method Reference Comment
Deltar7.40 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar16.7cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar2.4 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

(Iodide bullet Carbon disulfide) + Carbon disulfide = (Iodide bullet 2Carbon disulfide)

By formula: (I- bullet CS2) + CS2 = (I- bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar6.80 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar21.7cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar0.2 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

Molybdenum ion (1+) + Carbon disulfide = (Molybdenum ion (1+) bullet Carbon disulfide)

By formula: Mo+ + CS2 = (Mo+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar16.1 ± 3.0kcal/molCIDTSchroeder, Kretzschmar, et al., 2003RCD

Sulfur cation + Carbon disulfide = (Sulfur cation bullet Carbon disulfide)

By formula: S+ + CS2 = (S+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar39.7kcal/molPIGress, Linn, et al., 1980gas phase; M

S2+ + Carbon disulfide = (S2+ bullet Carbon disulfide)

By formula: S2+ + CS2 = (S2+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar30.9kcal/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Deltar28.8kcal/molPIOno, Linn, et al., 1981gas phase; M
Deltar21.9kcal/molPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; equilibrium uncertain; M
Quantity Value Units Method Reference Comment
Deltar25.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Deltar17.1cal/mol*KPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; equilibrium uncertain; M

(S2+ bullet Carbon disulfide) + Carbon disulfide = (S2+ bullet 2Carbon disulfide)

By formula: (S2+ bullet CS2) + CS2 = (S2+ bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar8.3kcal/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M

(S2+ bullet 2Carbon disulfide) + Carbon disulfide = (S2+ bullet 3Carbon disulfide)

By formula: (S2+ bullet 2CS2) + CS2 = (S2+ bullet 3CS2)

Quantity Value Units Method Reference Comment
Deltar5.5kcal/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar17.cal/mol*KN/AHiraoka, Fujimaki, et al., 1994, 2gas phase; Entropy change calculated or estimated; M

S2- + Carbon disulfide = (S2- bullet Carbon disulfide)

By formula: S2- + CS2 = (S2- bullet CS2)

Quantity Value Units Method Reference Comment
Deltar19.1kcal/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar29.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M

(S2- bullet Carbon disulfide) + Carbon disulfide = (S2- bullet 2Carbon disulfide)

By formula: (S2- bullet CS2) + CS2 = (S2- bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar6.1kcal/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/AHiraoka, Fujimaki, et al., 1994, 2gas phase; Entropy change calculated or estimated; M

Vanadium ion (1+) + Carbon disulfide = (Vanadium ion (1+) bullet Carbon disulfide)

By formula: V+ + CS2 = (V+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar27.2 ± 3.0kcal/molCIDTSchroeder, Kretzschmar, et al., 2003RCD

IR Spectrum

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, Mass spectrum (electron ionization), References, Notes

Data compiled by: Coblentz Society, Inc.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director


Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Collection (C) 2014 copyright by the U.S. Secretary of Commerce
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Origin NIST Mass Spectrometry Data Center, 1990.
NIST MS number 118705

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References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

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Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References