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Methylene chloride

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DRB - D.R. Burgess
ALS - H.Y. Afeefy, J.F. Liebman, and S.E. Stein

QuantityValueUnitsMethodReferenceComment
Deltafgas-95.52kJ/molReviewChase, 1998Data last reviewed in December, 1968
Deltafgas-95.1 ± 2.5kJ/molReviewManion, 2002derived from recommended «DELTA»fHliquid° and «DELTA»vapH°; DRB
Deltafgas-95.7 ± 1.3kJ/molChydLacher, Amador, et al., 1967Reanalyzed by Cox and Pilcher, 1970, Original value = -96.0 ± 1.3 kJ/mol; At 250 C; ALS
QuantityValueUnitsMethodReferenceComment
gas,1 bar270.28J/mol*KReviewChase, 1998Data last reviewed in December, 1968

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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View table.

Temperature (K)298. - 1200.1200. - 6000.
A19.1735195.12993
B136.84446.721722
C-95.12993-1.288196
D26.031050.085646
E-0.119405-14.93885
F-106.9338-157.3506
G256.0144340.5412
H-95.52114-95.52114
ReferenceChase, 1998Chase, 1998
CommentData last reviewed in December, 1968Data last reviewed in December, 1968

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DRB - D.R. Burgess
ALS - H.Y. Afeefy, J.F. Liebman, and S.E. Stein
DH - E.S. Domalski and E.D. Hearing

QuantityValueUnitsMethodReferenceComment
Deltafliquid-124.1 ± 2.5kJ/molReviewManion, 2002adopted combustion calorimetry data of Hu and Sinke, 1969 with increased uncertainty to reflect other data; DRB
Deltafliquid-124.3kJ/molCcrHu and Sinke, 1969, 2ALS
QuantityValueUnitsMethodReferenceComment
Deltacliquid-602.50kJ/molCcrHu and Sinke, 1969, 2ALS
Deltacliquid-605.8 ± 8.4kJ/molCcbSmith, Bjellerup, et al., 1953Reanalyzed by Cox and Pilcher, 1970, Original value = -605. ± 4. kJ/mol; ALS
QuantityValueUnitsMethodReferenceComment
liquid174.5J/mol*KN/AMoseeva, Rabinovich, et al., 1978DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K)Temperature (K)ReferenceComment
102.3298.15Moseeva, Rabinovich, et al., 1978T = 5 to 300 K.; DH
105.5303.2Harrison and Moelwyn-Hughes, 1957T = 244 to 303 K. Unsmoothed experimental datum.; DH
129.3298.Kurbatov, 1948T = -76 to 41°C. Mean Cp, four temperatures.; DH
100.0298.Riedel, 1941T = -47 to 41°C.; DH
100.0298.1Riedel, 1940T = -47 to 41°C.; DH
100.5292.5Perlick, 1937T = -58 to 19°C. Value is unsmoothed experimental datum.; DH
100.8292.5Perlick, 1937, 2T = -58 to 19°C. Value is unsmoothed experimental datum.; DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, M. Frenkel director
DRB - D.R. Burgess
AC - W.E. Acree, Jr., J.S. Chickos
ALS - H.Y. Afeefy, J.F. Liebman, and S.E. Stein
DH - E.S. Domalski and E.D. Hearing

QuantityValueUnitsMethodReferenceComment
Tboil313. ± 1.KAVGN/AAverage of 12 values; Individual data points
QuantityValueUnitsMethodReferenceComment
Tfus198.06KN/ATimmermans, 1952Uncertainty assigned by TRC = 0.4 K; TRC
Tfus176.KN/AVan de Vloed, 1939Uncertainty assigned by TRC = 1.5 K; TRC
Tfus177.KN/ATimmermans, 1935Uncertainty assigned by TRC = 2. K; TRC
Tfus176.65KN/ATimmermans, 1934Uncertainty assigned by TRC = 0.4 K; TRC
QuantityValueUnitsMethodReferenceComment
Tc508.KN/AGarcia-Sanchez, Romero-Martinez, et al., 1989Uncertainty assigned by TRC = 0.2 K; mean of 5 determinations, direct observation of meniscus; TRC
Tc510.KN/AMajer and Svoboda, 1985 
QuantityValueUnitsMethodReferenceComment
Pc63.55barN/AGarcia-Sanchez, Romero-Martinez, et al., 1989Uncertainty assigned by TRC = 0.15 bar; mean of 5 determinations, measurement of P at Tc; TRC
QuantityValueUnitsMethodReferenceComment
Deltavap29.kJ/molN/AMajer and Svoboda, 1985 
Deltavap29.03 ± 0.08kJ/molReviewManion, 2002adopted Majer, Svab, et al., 1980 value plus a correction for non-ideality; DRB
Deltavap30.6 ± 0.1kJ/molCAn and Hu, 1989AC
Deltavap28.8kJ/molCMajer, Sváb, et al., 1980AC
Deltavap28.5 ± 0.42kJ/molVMathews, 1926Reanalyzed by Pedley, Naylor, et al., 1986, Original value = 27.7 ± 0.96 kJ/mol; ALS

Enthalpy of vaporization

DeltavapH (kJ/mol)Temperature (K)MethodReferenceComment
28.06313.N/AMajer and Svoboda, 1985 
30.2248.N/AGaneff and Jungers, 2010Based on data from 233. - 313. K.; AC
29.0326.AStephenson and Malanowski, 1987Based on data from 311. - 383. K.; AC
30.3279.EBBoublík and Aim, 1972Based on data from 264. - 311. K.; AC
29.2308.N/AMueller and Ignatowski, 1960Based on data from 303. - 313. K.; AC
29.4186. - 312.N/APerry, 1926AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K)ABCReferenceComment
303.14 - 313.143.973231016.865-56.623Mueller and Ignatowski, 1960, 2Coefficents calculated by NIST from author's data.
233. - 313.4.536911327.016-20.474Ganeff and Jungers, 1948Coefficents calculated by NIST from author's data.

Enthalpy of fusion

DeltafusH (kJ/mol)Temperature (K)ReferenceComment
6.160178.22Moseeva, Rabinovich, et al., 1978DH
6.16178.2Domalski and Hearing, 1996AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - J.E. Bartmess
M - M. M. Meot-Ner (Mautner) and S. G. Lias
ALS - H.Y. Afeefy, J.F. Liebman, and S.E. Stein
MS - J.A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

CHCl2- + Hydrogen cation = Methylene chloride

By formula: CHCl2- + H+ = CH2Cl2

QuantityValueUnitsMethodReferenceComment
Deltar1572. ± 9.2kJ/molG+TSBorn, Ingemann, et al., 2000gas phase; D-EA from this reference yields BDE = 96.0±3.2 kcal/mol; B
Deltar1567. ± 13.kJ/molG+TSBohme, Lee-Ruff, et al., 1972gas phase; Comparable to DMSO; value altered from reference due to change in acidity scale; B
QuantityValueUnitsMethodReferenceComment
Deltar1540. ± 8.4kJ/molIMREBorn, Ingemann, et al., 2000gas phase; D-EA from this reference yields BDE = 96.0±3.2 kcal/mol; B
Deltar1543.9 ± 2.9kJ/molIMREPoutsma, Paulino, et al., 1997gas phase; relative to tBuOH at «DELTA»Gacid = 369.3; B
Deltar1535. ± 13.kJ/molIMRBBohme, Lee-Ruff, et al., 1972gas phase; Comparable to DMSO; value altered from reference due to change in acidity scale; B

Chlorine anion + Methylene chloride = (Chlorine anion bullet Methylene chloride)

By formula: Cl- + CH2Cl2 = (Cl- bullet CH2Cl2)

QuantityValueUnitsMethodReferenceComment
Deltar66.1 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Deltar61.9 ± 8.4kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Deltar64.9 ± 1.3kJ/molTDEqDougherty, Dalton, et al., 1974gas phase; B,M
QuantityValueUnitsMethodReferenceComment
Deltar92.5J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Kebarle, 1977; M
Deltar92.0J/mol*KHPMSDougherty, Dalton, et al., 1974gas phase; M
QuantityValueUnitsMethodReferenceComment
Deltar38. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Deltar37.0kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Deltar37.2 ± 2.5kJ/molTDEqDougherty, Dalton, et al., 1974gas phase; B

CN- + Methylene chloride = (CN- bullet Methylene chloride)

By formula: CN- + CH2Cl2 = (CN- bullet CH2Cl2)

QuantityValueUnitsMethodReferenceComment
Deltar68. ± 15.kJ/molIMRELarson and McMahon, 1987gas phase; B,M
QuantityValueUnitsMethodReferenceComment
Deltar101.J/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
QuantityValueUnitsMethodReferenceComment
Deltar38. ± 9.6kJ/molIMRELarson and McMahon, 1987gas phase; B,M

C2H5+ + Methylene chloride = (C2H5+ bullet Methylene chloride)

By formula: C2H5+ + CH2Cl2 = (C2H5+ bullet CH2Cl2)

QuantityValueUnitsMethodReferenceComment
Deltar151.kJ/molPHPMSSharma, Meza de Hojer, et al., 1985gas phase; Entropy change is questionable; M
QuantityValueUnitsMethodReferenceComment
Deltar189.J/mol*KPHPMSSharma, Meza de Hojer, et al., 1985gas phase; Entropy change is questionable; M

2Hydrogen + Methylene chloride = Methane + 2Hydrogen chloride

By formula: 2H2 + CH2Cl2 = CH4 + 2HCl

QuantityValueUnitsMethodReferenceComment
Deltar-163.4 ± 1.3kJ/molChydLacher, Amador, et al., 1967gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -167.7 ± 1.3 kJ/mol; At 250 C; ALS

CH2Cl3- + 2Methylene chloride = C2H4Cl5-

By formula: CH2Cl3- + 2CH2Cl2 = C2H4Cl5-

QuantityValueUnitsMethodReferenceComment
Deltar54.81kJ/molN/AHiraoka, Mizuno, et al., 2001gas phase; B
QuantityValueUnitsMethodReferenceComment
Deltar27.4kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B

C2H4Cl5- + 3Methylene chloride = C3H6Cl7-

By formula: C2H4Cl5- + 3CH2Cl2 = C3H6Cl7-

QuantityValueUnitsMethodReferenceComment
Deltar40.6kJ/molN/AHiraoka, Mizuno, et al., 2001gas phase; B
QuantityValueUnitsMethodReferenceComment
Deltar19.4kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B

C3H6Cl7- + 4Methylene chloride = C4H8Cl9-

By formula: C3H6Cl7- + 4CH2Cl2 = C4H8Cl9-

QuantityValueUnitsMethodReferenceComment
Deltar37.7kJ/molN/AHiraoka, Mizuno, et al., 2001gas phase; B
QuantityValueUnitsMethodReferenceComment
Deltar15.2kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B

C4H8Cl9- + 5Methylene chloride = C5H10Cl11-

By formula: C4H8Cl9- + 5CH2Cl2 = C5H10Cl11-

QuantityValueUnitsMethodReferenceComment
Deltar32.2kJ/molN/AHiraoka, Mizuno, et al., 2001gas phase; B
QuantityValueUnitsMethodReferenceComment
Deltar11.0kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B

C3H7+ + Methylene chloride = (C3H7+ bullet Methylene chloride)

By formula: C3H7+ + CH2Cl2 = (C3H7+ bullet CH2Cl2)

QuantityValueUnitsMethodReferenceComment
Deltar65.3kJ/molPHPMSSharma, Meza de Hojer, et al., 1985gas phase; M
QuantityValueUnitsMethodReferenceComment
Deltar130.J/mol*KPHPMSSharma, Meza de Hojer, et al., 1985gas phase; M

C6H11+ + Methylene chloride = (C6H11+ bullet Methylene chloride)

By formula: C6H11+ + CH2Cl2 = (C6H11+ bullet CH2Cl2)

QuantityValueUnitsMethodReferenceComment
Deltar44.4kJ/molPHPMSSharma, Meza de Hojer, et al., 1985gas phase; M
QuantityValueUnitsMethodReferenceComment
Deltar130.J/mol*KPHPMSSharma, Meza de Hojer, et al., 1985gas phase; M

Lithium ion (1+) + Methylene chloride = (Lithium ion (1+) bullet Methylene chloride)

By formula: Li+ + CH2Cl2 = (Li+ bullet CH2Cl2)

QuantityValueUnitsMethodReferenceComment
Deltar120.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

C4H9+ + Methylene chloride = (C4H9+ bullet Methylene chloride)

By formula: C4H9+ + CH2Cl2 = (C4H9+ bullet CH2Cl2)

QuantityValueUnitsMethodReferenceComment
Deltar40.kJ/molPHPMSSharma, Meza de Hojer, et al., 1985gas phase; M
QuantityValueUnitsMethodReferenceComment
Deltar93.3J/mol*KPHPMSSharma, Meza de Hojer, et al., 1985gas phase; M

C5H11+ + Methylene chloride = (C5H11+ bullet Methylene chloride)

By formula: C5H11+ + CH2Cl2 = (C5H11+ bullet CH2Cl2)

QuantityValueUnitsMethodReferenceComment
Deltar40.kJ/molPHPMSSharma, Meza de Hojer, et al., 1985gas phase; M
QuantityValueUnitsMethodReferenceComment
Deltar97.5J/mol*KPHPMSSharma, Meza de Hojer, et al., 1985gas phase; M

C5H9+ + Methylene chloride = (C5H9+ bullet Methylene chloride)

By formula: C5H9+ + CH2Cl2 = (C5H9+ bullet CH2Cl2)

QuantityValueUnitsMethodReferenceComment
Deltar41.kJ/molPHPMSSharma, Meza de Hojer, et al., 1985gas phase; M
QuantityValueUnitsMethodReferenceComment
Deltar84.5J/mol*KPHPMSSharma, Meza de Hojer, et al., 1985gas phase; M

C14H21MnO2 (solution) + Methylene chloride (solution) = C8H7Cl2MnO2 (solution) + Heptane (solution)

By formula: C14H21MnO2 (solution) + CH2Cl2 (solution) = C8H7Cl2MnO2 (solution) + C7H16 (solution)

QuantityValueUnitsMethodReferenceComment
Deltar-37.7 ± 4.2kJ/molPACYang and Yang, 1992solvent: Heptane; MS

Henry's Law data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: R. Sander

Henry's Law constant (water solution)

kH(T) = H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
H = Henry's law constant for solubility in water at 298.15 K (mol/kg*bar)
d(ln(kH))/d(1/T) = Temperature dependence constant (K)

H (mol/kg*bar)d(ln(kH))/d(1/T) (K)MethodReferenceComment
0.364100.LN/A 
0.41 MN/A 
0.383500.XN/A 
0.403800.MN/A 
0.403900.XN/A 
0.40 QN/A missing citation give several references for the Henry's law constants but don't assign them to specific species.
0.344300.XN/A 
0.473800.MGossett, 1987 
0.354200.XN/A 
0.394500.XN/A 
0.354200.MN/A 
0.313600.XN/A 
0.313700.XLeighton and Calo, 1981 
0.39 LN/A 
0.854200.XN/A 
0.40 VN/A 
1.2 VN/AValue at T = 275. K.
0.37 CN/A 
0.44 VN/A 
0.33 MPearson and McConnell, 1975The same data was also published in missing citation. Value at T = 293. K.
0.444100.MN/A 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - S.G. Lias

Data compiled as indicated in comments:
B - J.E. Bartmess
MM - M. Mautner
LBLHLM - S.G. Lias, J.E. Bartmess, J.F. Liebman, J.L. Holmes, R.D. Levin, and W.G. Mallard
LLK - S.G. Lias, R.D. Levin, and S.A. Kafafi
RDSH - H.M. Rosenstock, K. Draxl, B.W. Steiner, and J.T. Herron
LL - S.G. Lias and J.F. Liebman

QuantityValueUnitsMethodReferenceComment
IE (evaluated)11.33 ± 0.04eVN/AN/AL

Proton affinity at 298K

Proton affinity (kJ/mol)ReferenceComment
628. ± 8.Cacace, de Petris, et al., 1999COS; C2H2. Paper reports PA although proton transfer reactivity brackets GB. Following authors, the GBs of CH2Cl2 and COS are equated given reversible proton transfer.; MM

Gas basicity at 298K

Gas basicity (review) (kJ/mol)ReferenceComment
602. ± 8.Cacace, de Petris, et al., 1999COS; C2H2. Paper reports PA although proton transfer reactivity brackets GB. Following authors, the GBs of CH2Cl2 and COS are equated given reversible proton transfer.; MM

Ionization energy determinations

IE (eV)MethodReferenceComment
11.32PEVon Niessen, Asbrink, et al., 1982LBLHLM
11.40PEKimura, Katsumata, et al., 1981LLK
11.32 ± 0.01PIWerner, Tsai, et al., 1974LLK
11.28EILossing, 1972LLK
11.33PEDewar and Worley, 1969RDSH
11.36CICermak, 1968RDSH
11.35 ± 0.02PIWatanabe, 1957RDSH
11.40PEDixon, Murrell, et al., 1971Vertical value; LLK

Appearance energy determinations

IonAE (eV)Other ProductsMethodReferenceComment
C+25.5 ± 0.1?EIReed and Snedden, 1956RDSH
CH+21.72 ± 0.04?EIReed and Snedden, 1956RDSH
CHCl2+13.00 ± 0.10HEIReed and Snedden, 1956RDSH
CH2+17.0Cl2EIHaney and Franklin, 1968RDSH
CH2Cl+12.10ClEIHolmes, Lossing, et al., 1988LL
CH2Cl+12.14 ± 0.02ClPIWerner, Tsai, et al., 1974LLK
CH2Cl+12.15ClEILossing, 1972LLK
CH2Cl+12.1 ± 0.1ClEIHarrison and Shannon, 1962RDSH
CH2Cl+12.89 ± 0.03ClEIReed and Snedden, 1956RDSH
CHC12+12.12 ± 0.05HEIMartin, Lampe, et al., 1966RDSH
Cl+17.4 ± 0.1CH2ClEIDeCorpo, Bafus, et al., 1971LLK
Cl+17.4CH2ClEIFranklin and Haney, 1970RDSH

De-protonation reactions

CHCl2- + Hydrogen cation = Methylene chloride

By formula: CHCl2- + H+ = CH2Cl2

QuantityValueUnitsMethodReferenceComment
Deltar1572. ± 9.2kJ/molG+TSBorn, Ingemann, et al., 2000gas phase; D-EA from this reference yields BDE = 96.0±3.2 kcal/mol; B
Deltar1567. ± 13.kJ/molG+TSBohme, Lee-Ruff, et al., 1972gas phase; Comparable to DMSO; value altered from reference due to change in acidity scale; B
QuantityValueUnitsMethodReferenceComment
Deltar1540. ± 8.4kJ/molIMREBorn, Ingemann, et al., 2000gas phase; D-EA from this reference yields BDE = 96.0±3.2 kcal/mol; B
Deltar1543.9 ± 2.9kJ/molIMREPoutsma, Paulino, et al., 1997gas phase; relative to tBuOH at «DELTA»Gacid = 369.3; B
Deltar1535. ± 13.kJ/molIMRBBohme, Lee-Ruff, et al., 1972gas phase; Comparable to DMSO; value altered from reference due to change in acidity scale; B

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - J.E. Bartmess
M - M. M. Meot-Ner (Mautner) and S. G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

CH2Cl3- + 2Methylene chloride = C2H4Cl5-

By formula: CH2Cl3- + 2CH2Cl2 = C2H4Cl5-

QuantityValueUnitsMethodReferenceComment
Deltar54.81kJ/molN/AHiraoka, Mizuno, et al., 2001gas phase; B
QuantityValueUnitsMethodReferenceComment
Deltar27.4kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B

CN- + Methylene chloride = (CN- bullet Methylene chloride)

By formula: CN- + CH2Cl2 = (CN- bullet CH2Cl2)

QuantityValueUnitsMethodReferenceComment
Deltar68. ± 15.kJ/molIMRELarson and McMahon, 1987gas phase; B,M
QuantityValueUnitsMethodReferenceComment
Deltar101.J/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
QuantityValueUnitsMethodReferenceComment
Deltar38. ± 9.6kJ/molIMRELarson and McMahon, 1987gas phase; B,M

C2H4Cl5- + 3Methylene chloride = C3H6Cl7-

By formula: C2H4Cl5- + 3CH2Cl2 = C3H6Cl7-

QuantityValueUnitsMethodReferenceComment
Deltar40.6kJ/molN/AHiraoka, Mizuno, et al., 2001gas phase; B
QuantityValueUnitsMethodReferenceComment
Deltar19.4kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B

C2H5+ + Methylene chloride = (C2H5+ bullet Methylene chloride)

By formula: C2H5+ + CH2Cl2 = (C2H5+ bullet CH2Cl2)

QuantityValueUnitsMethodReferenceComment
Deltar151.kJ/molPHPMSSharma, Meza de Hojer, et al., 1985gas phase; Entropy change is questionable; M
QuantityValueUnitsMethodReferenceComment
Deltar189.J/mol*KPHPMSSharma, Meza de Hojer, et al., 1985gas phase; Entropy change is questionable; M

C3H6Cl7- + 4Methylene chloride = C4H8Cl9-

By formula: C3H6Cl7- + 4CH2Cl2 = C4H8Cl9-

QuantityValueUnitsMethodReferenceComment
Deltar37.7kJ/molN/AHiraoka, Mizuno, et al., 2001gas phase; B
QuantityValueUnitsMethodReferenceComment
Deltar15.2kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B

C3H7+ + Methylene chloride = (C3H7+ bullet Methylene chloride)

By formula: C3H7+ + CH2Cl2 = (C3H7+ bullet CH2Cl2)

QuantityValueUnitsMethodReferenceComment
Deltar65.3kJ/molPHPMSSharma, Meza de Hojer, et al., 1985gas phase; M
QuantityValueUnitsMethodReferenceComment
Deltar130.J/mol*KPHPMSSharma, Meza de Hojer, et al., 1985gas phase; M

C4H8Cl9- + 5Methylene chloride = C5H10Cl11-

By formula: C4H8Cl9- + 5CH2Cl2 = C5H10Cl11-

QuantityValueUnitsMethodReferenceComment
Deltar32.2kJ/molN/AHiraoka, Mizuno, et al., 2001gas phase; B
QuantityValueUnitsMethodReferenceComment
Deltar11.0kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B

C4H9+ + Methylene chloride = (C4H9+ bullet Methylene chloride)

By formula: C4H9+ + CH2Cl2 = (C4H9+ bullet CH2Cl2)

QuantityValueUnitsMethodReferenceComment
Deltar40.kJ/molPHPMSSharma, Meza de Hojer, et al., 1985gas phase; M
QuantityValueUnitsMethodReferenceComment
Deltar93.3J/mol*KPHPMSSharma, Meza de Hojer, et al., 1985gas phase; M

C5H9+ + Methylene chloride = (C5H9+ bullet Methylene chloride)

By formula: C5H9+ + CH2Cl2 = (C5H9+ bullet CH2Cl2)

QuantityValueUnitsMethodReferenceComment
Deltar41.kJ/molPHPMSSharma, Meza de Hojer, et al., 1985gas phase; M
QuantityValueUnitsMethodReferenceComment
Deltar84.5J/mol*KPHPMSSharma, Meza de Hojer, et al., 1985gas phase; M

C5H11+ + Methylene chloride = (C5H11+ bullet Methylene chloride)

By formula: C5H11+ + CH2Cl2 = (C5H11+ bullet CH2Cl2)

QuantityValueUnitsMethodReferenceComment
Deltar40.kJ/molPHPMSSharma, Meza de Hojer, et al., 1985gas phase; M
QuantityValueUnitsMethodReferenceComment
Deltar97.5J/mol*KPHPMSSharma, Meza de Hojer, et al., 1985gas phase; M

C6H11+ + Methylene chloride = (C6H11+ bullet Methylene chloride)

By formula: C6H11+ + CH2Cl2 = (C6H11+ bullet CH2Cl2)

QuantityValueUnitsMethodReferenceComment
Deltar44.4kJ/molPHPMSSharma, Meza de Hojer, et al., 1985gas phase; M
QuantityValueUnitsMethodReferenceComment
Deltar130.J/mol*KPHPMSSharma, Meza de Hojer, et al., 1985gas phase; M

Chlorine anion + Methylene chloride = (Chlorine anion bullet Methylene chloride)

By formula: Cl- + CH2Cl2 = (Cl- bullet CH2Cl2)

QuantityValueUnitsMethodReferenceComment
Deltar66.1 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Deltar61.9 ± 8.4kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Deltar64.9 ± 1.3kJ/molTDEqDougherty, Dalton, et al., 1974gas phase; B,M
QuantityValueUnitsMethodReferenceComment
Deltar92.5J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Kebarle, 1977; M
Deltar92.0J/mol*KHPMSDougherty, Dalton, et al., 1974gas phase; M
QuantityValueUnitsMethodReferenceComment
Deltar38. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Deltar37.0kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Deltar37.2 ± 2.5kJ/molTDEqDougherty, Dalton, et al., 1974gas phase; B

Lithium ion (1+) + Methylene chloride = (Lithium ion (1+) bullet Methylene chloride)

By formula: Li+ + CH2Cl2 = (Li+ bullet CH2Cl2)

QuantityValueUnitsMethodReferenceComment
Deltar120.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

IR Spectrum

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, NIST Free Links, References, Notes

Data compiled by: Coblentz Society, Inc.

Data compiled by: NIST Mass Spec Data Center, S.E. Stein, director

Data compiled by: P.M. Chu, F.R. Guenther, G.C. Rhoderick, and W.J. Lafferty


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spec Data Center, S.E. Stein, director

Spectrum

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Additional Data

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OwnerNIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
OriginJapan AIST/NIMC Database- Spectrum MS-NW-5526
NIST MS number228003

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


Vibrational and/or electronic energy levels

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: T. Shimanouchi

Symmetry:   C2nu     Symmetry Number sigma = 2


 Sym.   No   Approximate   Selected Freq.  Infrared   Raman   Comments 
 Species   type of mode   Value   Rating   Value  Phase  Value  Phase

a1 1 CH2 s-str 2999  B 2999 M gas 2996 S p gas
a1 2 CH2 scis 1467  C 1467 W gas 1430.1 W p gas
a1 3 CCl2 s-str 717  B 717 M gas 713 S p gas
a1 4 CCl2 scis 282  B 284 liq. 281.5 M p gas
a2 5 CH2 twist 1153  B  ia 1153 VW gas Spectrum of liquid 2Cl2, weak band is found at «nu»1156 cm(«nu»1, )may be assigned to «nu»5
b1 6 CH2 a-str 3040  B 3045 liq. 3040 S dp gas
b1 7 CH2 rock 898  B 897.7 M gas 893 VW gas
b2 8 CH2 wag 1268  B 1268 S gas 1265 liq.
b2 9 CCl2 a-str 758  B 758 VS liq.

Source: Shimanouchi, 1972

Notes

VSVery strong
SStrong
MMedium
WWeak
VWVery weak
iaInactive
pPolarized
dpDepolarized
B1~3 cm-1 uncertainty
C3~6 cm-1 uncertainty

Gas Chromatography

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spec Data Center, S.E. Stein, director

Kovats' RI, non-polar column, isothermal

View large format table.

Column typeActive phaseTemperature (C)IReferenceComment
CapillaryHP-10.553.5Wang, Liu, et al., 200530. m/0.25 mm/0.25 «mu»m
CapillaryHP-110.555.9Wang, Liu, et al., 200530. m/0.25 mm/0.25 «mu»m
CapillaryHP-140.553.7Wang, Liu, et al., 200530. m/0.25 mm/0.25 «mu»m
CapillaryHP-150.548.4Wang, Liu, et al., 200530. m/0.25 mm/0.25 «mu»m
CapillaryHP-160.542.2Wang, Liu, et al., 200530. m/0.25 mm/0.25 «mu»m
PackedC78, Branched paraffin130.506.3Dallos, Sisak, et al., 2000He; Column length: 3.3 m
CapillaryOV-170.518.Annino and Villalobos, 199922.6 m/0.53 mm/2.78 «mu»m
PackedC78, Branched paraffin130.504.9Reddy, Dutoit, et al., 1992Chromosorb G HP; Column length: 3.3 m
PackedApolane130.508.Dutoit, 1991Column length: 3.7 m
CapillaryOV-160.516.9Guan, Kiraly, et al., 198925. m/0.31 mm/0.52 «mu»m, He
CapillaryOV-175.516.5Guan, Kiraly, et al., 198925. m/0.31 mm/0.52 «mu»m, He
CapillarySE-5460.537.8Guan, Kiraly, et al., 198925. m/0.31 mm/0.52 «mu»m, He
CapillarySE-5475.537.9Guan, Kiraly, et al., 198925. m/0.31 mm/0.52 «mu»m, He
PackedOV-1100.519.Castello and Gerbino, 1988He, Chromosorb W DMCS; Column length: 3. m
PackedOV-1125.520.Castello and Gerbino, 1988He, Chromosorb W DMCS; Column length: 3. m
PackedOV-175.518.Castello and Gerbino, 1988He, Chromosorb W DMCS; Column length: 3. m
PackedSqualane80.486.Pacáková, Vojtechová, et al., 1988N2, Chezasorb AW-HMDS; Column length: 1.2 m
PackedSE-30100.524.Winskowski, 1983Gaschrom Q; Column length: 2. m
PackedApolane70.497.9Riedo, Fritz, et al., 1976He, Chromosorb; Column length: 2.4 m
PackedSqualane50.477.Vernon, 1971N2
PackedApiezon L130.511.von Kováts, 1958Celite (40:60 Gewichtsverhaltnis)
PackedApiezon L70.513.von Kováts, 1958Celite (40:60 Gewichtsverhaltnis)

Kovats' RI, non-polar column, temperature ramp

View large format table.

Column typeActive phaseIReferenceComment
CapillarySE-54531.Rembold, Wallner, et al., 198930. m/0.25 mm/0.25 «mu»m, He, 0. C @ 12. min, 12. K/min; Tend: 250. C
CapillaryOV-101540.Ohnishi and Shibamoto, 19842. K/min; Column length: 50. m; Column diameter: 0.23 mm; Tstart: 80. C; Tend: 200. C
CapillaryOV-101540.Ohnishi and Shibamoto, 19842. K/min; Column length: 50. m; Column diameter: 0.23 mm; Tstart: 80. C; Tend: 200. C

Kovats' RI, non-polar column, custom temperature program

View large format table.

Column typeActive phaseIReferenceComment
PackedSE-30510.Minyard, Tumlinson, et al., 1967He, Chromasorb W; Column length: 6.1 m; Program: 150C (10min) => 15C/min => 200C(16min) => 10C/min => 240C

Kovats' RI, polar column, isothermal

View large format table.

Column typeActive phaseTemperature (C)IReferenceComment
CapillaryCarbowax 20M70.948.Annino and Villalobos, 199931.3 m/0.53 mm/0.54 «mu»m
CapillarySupelcowax-1060.946.Castello, Vezzani, et al., 1991N2; Column length: 60. m; Column diameter: 0.75 mm
PackedSP-1000100.935.7Castello and Gerbino, 1988He, Chromosorb W DMCS; Column length: 3. m
PackedSP-1000125.932.62Castello and Gerbino, 1988He, Chromosorb W DMCS; Column length: 3. m
PackedSP-100075.926.65Castello and Gerbino, 1988He, Chromosorb W DMCS; Column length: 3. m
PackedCarbowax 20M75.933.Goebel, 1982N2, Kieselgur (60-100 mesh); Column length: 2. m

Kovats' RI, polar column, temperature ramp

View large format table.

Column typeActive phaseIReferenceComment
CapillaryCBP-20933.Shimadzu, 200325. m/0.2 mm/0.25 «mu»m, He, 50. C @ 5. min, 4. K/min; Tend: 200. C
CapillaryDB-Wax914.Shimoda and Shibamoto, 1990He, 40. C @ 6. min, 3. K/min; Column length: 60. m; Column diameter: 0.25 mm; Tend: 190. C
CapillaryDB-Wax925.Tatsuka, Suekane, et al., 199060. m/0.25 mm/0.25 «mu»m, He, 40. C @ 5. min, 3. K/min; Tend: 200. C
CapillaryDB-Wax931.Tatsuka, Suekane, et al., 199060. m/0.25 mm/0.25 «mu»m, He, 40. C @ 5. min, 3. K/min; Tend: 200. C
CapillaryDB-Wax948.Umano and Shibamoto, 198840. C @ 10. min, 2. K/min; Column length: 60. m; Column diameter: 0.25 mm; Tend: 220. C
CapillaryDB-Wax948.Umano and Shibamoto, 198840. C @ 10. min, 2. K/min; Column length: 60. m; Column diameter: 0.25 mm; Tend: 220. C
CapillaryDB-Wax905.Umano, Shoji, et al., 1986N2, 60. C @ 10. min, 2. K/min; Column length: 30. m; Column diameter: 0.25 mm; Tend: 200. C

Van Den Dool and Kratz RI, non-polar column, temperature ramp

View large format table.

Column typeActive phaseIReferenceComment
CapillaryPetrocol DH512.7Censullo, Jones, et al., 200350. m/0.25 mm/0.5 «mu»m, He, 35. C @ 10. min, 3. K/min, 200. C @ 10. min
CapillaryDB-5531.6Xu, van Stee, et al., 200330. m/0.25 mm/1. «mu»m, He, 2.5 K/min; Tstart: 50. C; Tend: 200. C
CapillaryDB-1524.Helmig, Pollock, et al., 199630. m/0.25 mm/1. «mu»m, 6. K/min; Tstart: -50. C; Tend: 180. C

Van Den Dool and Kratz RI, polar column, temperature ramp

View large format table.

Column typeActive phaseIReferenceComment
CapillaryCarbowax937.2Censullo, Jones, et al., 200360. m/0.25 mm/0.5 «mu»m, He, 50. C @ 10. min, 5. K/min, 250. C @ 10. min
CapillaryFFAP936.Ott, Fay, et al., 199730. m/0.25 mm/0.25 «mu»m, He, 20. C @ 1. min, 4. K/min, 200. C @ 1. min

Van Den Dool and Kratz RI, polar column, custom temperature program

View large format table.

Column typeActive phaseIReferenceComment
CapillarySupelcowax-10927.Bianchi, Careri, et al., 200730. m/0.25 mm/0.25 «mu»m, He; Program: 35C(8min) => 4C/min => 60C => 6C/min => 160C => 20C/min => 200C(1min)
CapillarySupelcowax-10933.Bianchi, Careri, et al., 200730. m/0.25 mm/0.25 «mu»m, He; Program: 35C(8min) => 4C/min => 60C => 6C/min => 160C => 20C/min => 200C(1min)

Normal alkane RI, non-polar column, isothermal

View large format table.

Column typeActive phaseTemperature (C)IReferenceComment
CapillaryDB-160.520.Shimadzu, 2003, 260. m/0.32 mm/1. «mu»m, He
PackedSynachrom150.480.Dufka, Malinsky, et al., 1971Helium, Synachrom (60-80 mesh); Column length: 1.5 m
PackedSqualane100.488.Vernon, 1971N2

Normal alkane RI, non-polar column, temperature ramp

View large format table.

Column typeActive phaseIReferenceComment
CapillaryHP-5 MS531.Kotowska, Zalikowski, et al., 201230. m/0.25 mm/0.25 «mu»m, Helium, 35. C @ 5. min, 3. K/min, 300. C @ 15. min
CapillarySPB-5531.Vasta, Ratel, et al., 200760. m/0.32 mm/1. «mu»m, 40. C @ 5. min, 3. K/min, 230. C @ 5. min
CapillarySPB-5528.Pérès, Begnaud, et al., 200260. m/0.32 mm/1. «mu»m, 40. C @ 5. min, 3. K/min, 200. C @ 5. min
CapillaryBP-1514.Health Safety Executive, 200050. m/0.22 mm/0.75 «mu»m, He, 5. K/min; Tstart: 50. C; Tend: 200. C
CapillaryUltra-2520.King, Matthews, et al., 199550. m/0.32 mm/0.52 «mu»m, He, 40. C @ 3. min, 4. K/min, 250. C @ 30. min
CapillaryDB-1511.Habu, Flath, et al., 19853. K/min; Column length: 50. m; Column diameter: 0.32 mm; Tstart: 0. C; Tend: 250. C
CapillarySF-96527.Donetzhuber, Johansson, et al., 1976Nitrogen, 3. K/min, 130. C @ 40. min; Column length: 111. m; Column diameter: 0.76 mm; Initial hold: 8. min

Normal alkane RI, non-polar column, custom temperature program

View large format table.

Column typeActive phaseIReferenceComment
CapillaryHP-5 MS528.Kotowska, Zalikowski, et al., 201230. m/0.25 mm/0.25 «mu»m, Helium; Program: not specified
CapillaryHP-5529.Rotsatschakul, Visesanguan, et al., 200960. m/0.25 mm/0.25 «mu»m, Helium; Program: 30 0C (2 min) 2 0Cmin -> 60 0C 10 0C/min -> 100 0C 20 0C/min -> 140 0C 10 0C/min -> 200 0C (10 min)
CapillaryPolydimethyl siloxanes515.Zenkevich, Eliseenkov, et al., 2006Program: not specified
CapillaryMethyl Silicone519.Blunden, Aneja, et al., 200560. m/0.32 mm/1.0 «mu»m, Helium; Program: -50 0C (2 min) 8 0C/min -> 200 0C (7.75 min) 25 0C -> 225 0C (8 min)
CapillaryMethyl Silicone515.Zenkevich, 1998Program: not specified
CapillarySPB-1515.Flanagan, Streete, et al., 199760. m/0.53 mm/5. «mu»m, He; Program: 40C(6min) => 5C/min => 80C => 10C/min => 200C
CapillaryDB-5531.Sorimachi, Tanabe, et al., 1995He; Column length: 30. m; Program: not specified
CapillaryMethyl Silicone515.Zenkevich, Korolenko, et al., 1995Program: not specified
CapillaryDB-1512.Ciccioli, Cecinato, et al., 199460. m/0.32 mm/0.25 «mu»m; Program: not specified
CapillarySPB-1515.Strete, Ruprah, et al., 199260. m/0.53 mm/5.0 «mu»m, Helium; Program: 40 0C (6 min) 5 0C/min -> 80 0C 10 0C/min -> 200 0C
CapillarySPB-1515.Strete, Ruprah, et al., 199260. m/0.53 mm/5.0 «mu»m, Helium; Program: not specified
CapillaryDB-1504.Kawai, Ishida, et al., 199160. m/0.25 mm/0.25 «mu»m; Program: not specified
CapillaryDB-1510.Kawai, Ishida, et al., 199160. m/0.25 mm/0.25 «mu»m; Program: not specified
CapillaryMethyl Silicone527.Zenkevich and Kuznetsova, 1990Program: not specified
CapillaryCP Sil 8 CB530.Weller and Wolf, 198940. m/0.25 mm/0.25 «mu»m, He; Program: 30 0C (1 min) 15 0C/min -> 45 0C 3 0C/min -> 120 0C
CapillaryOV-1, SE-30, Methyl silicone, SP-2100, OV-101, DB-1, etc.524.Waggott and Davies, 1984Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified
CapillaryOV-1, SE-30, Methyl silicone, SP-2100, OV-101, DB-1, etc.524.Waggott and Davies, 1984Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified
CapillaryOV-1515.Ramsey and Flanagan, 1982Program: not specified

Normal alkane RI, polar column, isothermal

View large format table.

Column typeActive phaseTemperature (C)IReferenceComment
CapillaryDB-Wax60.953.Shimadzu, 2003, 250. m/0.32 mm/1. «mu»m, He

Normal alkane RI, polar column, temperature ramp

View large format table.

Column typeActive phaseIReferenceComment
CapillaryDB-Wax944.Shimadzu, 201230. m/0.32 mm/0.50 «mu»m, Helium, 4. K/min; Tstart: 40. C; Tend: 260. C
CapillaryDB-Wax932.Rochat, Egger, et al., 200930. m/0.25 mm/0.25 «mu»m, Helium, 60. C @ 3. min, 8. K/min, 200. C @ 9.5 min
CapillaryDB-Wax937.Rochat, Egger, et al., 200930. m/0.25 mm/0.25 «mu»m, Helium, 60. C @ 3. min, 8. K/min, 200. C @ 9.5 min
CapillaryDB-Wax944.Shimadzu Corporation, 200330. m/0.32 mm/0.5 «mu»m, He, 4. K/min; Tstart: 40. C; Tend: 260. C
CapillaryDB-Wax933.Fu, Yoon, et al., 200230. m/0.25 mm/0.25 «mu»m, He, 40. C @ 5. min, 8. K/min, 250. C @ 5. min
CapillaryDB-Wax919.Duque, Bonilla, et al., 200130. m/0.25 mm/0.25 «mu»m, Helium, 4. K/min, 220. C @ 30. min; Tstart: 25. C
CapillaryDB-Wax925.Takeoka, Flath, et al., 198860. m/0.25 mm/0.25 «mu»m, H2, 30. C @ 2. min, 2. K/min; Tend: 180. C
CapillaryDB-Wax928.Takeoka, Flath, et al., 198860. m/0.25 mm/0.25 «mu»m, H2, 30. C @ 2. min, 2. K/min; Tend: 180. C

Normal alkane RI, polar column, custom temperature program

View large format table.

Column typeActive phaseIReferenceComment
CapillarySupelcowax 10912.Soria, Martinez-Castro, et al., 200850. m/0.25 mm/0.25 «mu»m, Helium; Program: 45 0C (15 min) 3 0C/min -> 75 0C 5 0C/min -> 180 0C (10 min)
CapillarySupelcowax-10927.Berard, Bianchi, et al., 200730. m/0.25 mm/0.25 «mu»m, He; Program: 35C(8min) => 6C/min => 60C => 4C/min => 160C => 20C/min => 200C(1min)
CapillarySupelcowax-10933.Berard, Bianchi, et al., 200730. m/0.25 mm/0.25 «mu»m, He; Program: 35C(8min) => 6C/min => 60C => 4C/min => 160C => 20C/min => 200C(1min)
CapillaryPolyethylene Glycol914.Zenkevich, Korolenko, et al., 1995Program: not specified
CapillaryCarbowax 20M917.Ramsey and Flanagan, 1982Program: not specified

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Manion, 2002
Manion, J.A., Evaluated Enthalpies of Formation of the Stable Closed Shell C1 and C2 Chlorinated Hydrocarbons, J. Phys. Chem. Ref. Data, 2002, 31, 1, 123-172. [doi:10.1063/1.1420703] [all data]

Lacher, Amador, et al., 1967
Lacher, J.R.; Amador, A.; Park, J.D., Reaction heats of organic compounds. Part 5.-Heats of hydrogenation of dichloromethane, 1,1- and 1,2-dichloroethane and 1,2-dichloropropane, Trans. Faraday Soc., 1967, 63, 1608-1611. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Hu and Sinke, 1969
Hu, A.T.; Sinke, G.C., Combustion calorimetry of some chlorinated organic compounds, J. Chem. Thermodyn., 1969, 1, 6, 507. [doi:10.1016/0021-9614(69)90010-X] [all data]

Hu and Sinke, 1969, 2
Hu, A.T.; Sinke, G.C., Combustion calorimetry of some chlorinated organic compounds, J. Chem. Thermodyn., 1969, 1, 507-513. [all data]

Smith, Bjellerup, et al., 1953
Smith, L.; Bjellerup, L.; Krook, S.; Westermark, H., Heats of combustion of organic chloro compounds determined by the "quartz wool" method, Acta Chem. Scand., 1953, 7, 65. [all data]

Moseeva, Rabinovich, et al., 1978
Moseeva, E.M.; Rabinovich, I.B.; Busygina, G.I.; Safonov, V.A.; Ovchinnikov, E.Yu., Thermodynamic proerties of methylene chloride, Termodin. Org. Soedin., Gor'kii, 1978, 1, 8-11. [all data]

Harrison and Moelwyn-Hughes, 1957
Harrison, D.; Moelwyn-Hughes, E.A., The heat capacities of certain liquids, Proc. Roy. Soc. (London), 1957, A239, 230-246. [all data]

Kurbatov, 1948
Kurbatov, V.Ya., Heat capacity of liquids. 2. Heat capacity and the temperature dependence of heat capacity from halogen derivatives of acylic hydrocarbons, Zh. Obshch. Kim., 1948, 18, 372-389. [all data]

Riedel, 1941
Riedel, L., Determination of the specific heat of liquid ethyl chloride and liquid methylene chloride, Bull. Int. Inst., Refrig. Annex 22, 1941, No4, 1-3. [all data]

Riedel, 1940
Riedel, L., Bestimmung der spezifischen Wärme von Äthychlorid und Methylenchlorid im flüssigen Zustand, Z. ges. Kalte-Ind., 1940, 47, 87. [all data]

Perlick, 1937
Perlick, A., Calorimetric investigations on dichloromethane, difluoromonochloroethane and tetrafluorodichloroethane, Bull. Int. Inst. Refrig., 1937, 18, 1-9. [all data]

Perlick, 1937, 2
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Notes

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