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Acetonitrile

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 51 to 100

MeCO2 anion + Acetonitrile = (MeCO2 anion bullet Acetonitrile)

By formula: C2H3O2- + C2H3N = (C2H3O2- bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar61.9 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar75.3J/mol*KPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar39. ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B

(C2H4N+ bullet Acetonitrile) + Water = (C2H4N+ bullet Water bullet Acetonitrile)

By formula: (C2H4N+ bullet C2H3N) + H2O = (C2H4N+ bullet H2O bullet C2H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar66.5kJ/molPHPMSDeakyne, Meot-Ner (Mautner), et al., 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar103.J/mol*KPHPMSDeakyne, Meot-Ner (Mautner), et al., 1986gas phase; n; M

(Rubidium ion (1+) bullet 4Acetonitrile) + Acetonitrile = (Rubidium ion (1+) bullet 5Acetonitrile)

By formula: (Rb+ bullet 4C2H3N) + C2H3N = (Rb+ bullet 5C2H3N)

Quantity Value Units Method Reference Comment
Deltar46.4kJ/molHPMSDavidson and Kebarle, 1976gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar136.J/mol*KHPMSDavidson and Kebarle, 1976gas phase; Entropy change is questionable; M

C3H5O+ + Acetonitrile = (C3H5O+ bullet Acetonitrile)

By formula: C3H5O+ + C2H3N = (C3H5O+ bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar64.0kJ/molPHPMSMeot-ner, 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar79.1J/mol*KPHPMSMeot-ner, 1988, 2gas phase; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
39.295.FAMackay, Rakshit, et al., 1982gas phase; M

(Sodium ion (1+) bullet 2Acetonitrile) + Acetonitrile = (Sodium ion (1+) bullet 3Acetonitrile)

By formula: (Na+ bullet 2C2H3N) + C2H3N = (Na+ bullet 3C2H3N)

Quantity Value Units Method Reference Comment
Deltar89. ± 3.kJ/molCIDTValina, 2001RCD
Deltar86.2kJ/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
Deltar115.J/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

(Sodium ion (1+) bullet 3Acetonitrile) + Acetonitrile = (Sodium ion (1+) bullet 4Acetonitrile)

By formula: (Na+ bullet 3C2H3N) + C2H3N = (Na+ bullet 4C2H3N)

Quantity Value Units Method Reference Comment
Deltar64. ± 3.kJ/molCIDTValina, 2001RCD
Deltar62.3kJ/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
Deltar117.J/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

(Sodium ion (1+) bullet Acetonitrile) + Acetonitrile = (Sodium ion (1+) bullet 2Acetonitrile)

By formula: (Na+ bullet C2H3N) + C2H3N = (Na+ bullet 2C2H3N)

Quantity Value Units Method Reference Comment
Deltar109. ± 7.9kJ/molCIDTValina, 2001RCD
Deltar102.kJ/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
Deltar95.0J/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

C10H4Cl2O2- + Acetonitrile = (C10H4Cl2O2- bullet Acetonitrile)

By formula: C10H4Cl2O2- + C2H3N = (C10H4Cl2O2- bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar<6.3 ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
6.3343.PHPMSChowdhury, 1987gas phase; DG<; M

C6H5NO2- + Acetonitrile = (C6H5NO2- bullet Acetonitrile)

By formula: C6H5NO2- + C2H3N = (C6H5NO2- bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar28. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
28.343.PHPMSChowdhury, 1987gas phase; M

1,4-Naphthalenedione anion + Acetonitrile = (1,4-Naphthalenedione anion bullet Acetonitrile)

By formula: C10H6O2- + C2H3N = (C10H6O2- bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar18. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
18.343.PHPMSChowdhury, 1987gas phase; M

C6H4FNO2- + Acetonitrile = (C6H4FNO2- bullet Acetonitrile)

By formula: C6H4FNO2- + C2H3N = (C6H4FNO2- bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar26. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
26.343.PHPMSChowdhury, 1987gas phase; M

C6H4FNO2- + Acetonitrile = (C6H4FNO2- bullet Acetonitrile)

By formula: C6H4FNO2- + C2H3N = (C6H4FNO2- bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar26. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
26.343.PHPMSChowdhury, 1987gas phase; M

C6H4ClNO2- + Acetonitrile = (C6H4ClNO2- bullet Acetonitrile)

By formula: C6H4ClNO2- + C2H3N = (C6H4ClNO2- bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar24. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
24.343.PHPMSChowdhury, 1987gas phase; M

C6H4FNO2- + Acetonitrile = (C6H4FNO2- bullet Acetonitrile)

By formula: C6H4FNO2- + C2H3N = (C6H4FNO2- bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar25. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
25.343.PHPMSChowdhury, 1987gas phase; M

C6H4ClNO2- + Acetonitrile = (C6H4ClNO2- bullet Acetonitrile)

By formula: C6H4ClNO2- + C2H3N = (C6H4ClNO2- bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar26. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
26.343.PHPMSChowdhury, 1987gas phase; M

C6H4ClNO2- + Acetonitrile = (C6H4ClNO2- bullet Acetonitrile)

By formula: C6H4ClNO2- + C2H3N = (C6H4ClNO2- bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar25. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
25.343.PHPMSChowdhury, 1987gas phase; M

C6H4N2O4- + Acetonitrile = (C6H4N2O4- bullet Acetonitrile)

By formula: C6H4N2O4- + C2H3N = (C6H4N2O4- bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar13. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
13.343.PHPMSChowdhury, 1987gas phase; M

C6H4N2O4- + Acetonitrile = (C6H4N2O4- bullet Acetonitrile)

By formula: C6H4N2O4- + C2H3N = (C6H4N2O4- bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar20. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
20.343.PHPMSChowdhury, 1987gas phase; M

C6H4N2O4- + Acetonitrile = (C6H4N2O4- bullet Acetonitrile)

By formula: C6H4N2O4- + C2H3N = (C6H4N2O4- bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar18. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
18.343.PHPMSChowdhury, 1987gas phase; M

C7H7NO2- + Acetonitrile = (C7H7NO2- bullet Acetonitrile)

By formula: C7H7NO2- + C2H3N = (C7H7NO2- bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar28. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
28.343.PHPMSChowdhury, 1987gas phase; M

C6F4O2- + Acetonitrile = (C6F4O2- bullet Acetonitrile)

By formula: C6F4O2- + C2H3N = (C6F4O2- bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar14. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
14.343.PHPMSChowdhury, 1987gas phase; M

p-Benzoquinone anion + Acetonitrile = (p-Benzoquinone anion bullet Acetonitrile)

By formula: C6H4O2- + C2H3N = (C6H4O2- bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar20. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
20.343.PHPMSChowdhury, 1987gas phase; M

C7H4N2O2- + Acetonitrile = (C7H4N2O2- bullet Acetonitrile)

By formula: C7H4N2O2- + C2H3N = (C7H4N2O2- bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar22. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
22.343.PHPMSChowdhury, 1987gas phase; M

C7H4N2O2- + Acetonitrile = (C7H4N2O2- bullet Acetonitrile)

By formula: C7H4N2O2- + C2H3N = (C7H4N2O2- bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar21. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
21.343.PHPMSChowdhury, 1987gas phase; M

(C2H4N+ bullet Acetonitrile bullet Water) + Acetonitrile = (C2H4N+ bullet 2Acetonitrile bullet Water)

By formula: (C2H4N+ bullet C2H3N bullet H2O) + C2H3N = (C2H4N+ bullet 2C2H3N bullet H2O)

Quantity Value Units Method Reference Comment
Deltar86.2kJ/molPHPMSDeakyne, Meot-Ner (Mautner), et al., 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar114.J/mol*KPHPMSDeakyne, Meot-Ner (Mautner), et al., 1986gas phase; n; M

C4H9O+ + Acetonitrile = (C4H9O+ bullet Acetonitrile)

By formula: C4H9O+ + C2H3N = (C4H9O+ bullet C2H3N)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
86.6320.ICRBromilow, Abboud, et al., 1980gas phase; switching reaction,n((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973; M

(C2H4N+ bullet Water) + Acetonitrile = (C2H4N+ bullet Acetonitrile bullet Water)

By formula: (C2H4N+ bullet H2O) + C2H3N = (C2H4N+ bullet C2H3N bullet H2O)

Quantity Value Units Method Reference Comment
Deltar97.9kJ/molPHPMSDeakyne, Meot-Ner (Mautner), et al., 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar103.J/mol*KPHPMSDeakyne, Meot-Ner (Mautner), et al., 1986gas phase; n; M

(NH4+ bullet 2Ammonia bullet Acetonitrile) + Ammonia = (NH4+ bullet 3Ammonia bullet Acetonitrile)

By formula: (H4N+ bullet 2H3N bullet C2H3N) + H3N = (H4N+ bullet 3H3N bullet C2H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar56.9kJ/molMKERTzeng, Wei, et al., 1991gas phase; from graph; M

(NH4+ bullet 3Ammonia bullet Acetonitrile) + Ammonia = (NH4+ bullet 4Ammonia bullet Acetonitrile)

By formula: (H4N+ bullet 3H3N bullet C2H3N) + H3N = (H4N+ bullet 4H3N bullet C2H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar31.kJ/molMKERTzeng, Wei, et al., 1991gas phase; from graph; M

(NH4+ bullet 4Ammonia bullet Acetonitrile) + Ammonia = (NH4+ bullet 5Ammonia bullet Acetonitrile)

By formula: (H4N+ bullet 4H3N bullet C2H3N) + H3N = (H4N+ bullet 5H3N bullet C2H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar29.kJ/molMKERTzeng, Wei, et al., 1991gas phase; from graph; M

(NH4+ bullet 5Ammonia bullet Acetonitrile) + Ammonia = (NH4+ bullet 6Ammonia bullet Acetonitrile)

By formula: (H4N+ bullet 5H3N bullet C2H3N) + H3N = (H4N+ bullet 6H3N bullet C2H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar25.kJ/molMKERTzeng, Wei, et al., 1991gas phase; from graph; M

(NH4+ bullet 6Ammonia bullet Acetonitrile) + Ammonia = (NH4+ bullet 7Ammonia bullet Acetonitrile)

By formula: (H4N+ bullet 6H3N bullet C2H3N) + H3N = (H4N+ bullet 7H3N bullet C2H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar23.kJ/molMKERTzeng, Wei, et al., 1991gas phase; from graph; M

(NH4+ bullet 7Ammonia bullet Acetonitrile) + Ammonia = (NH4+ bullet 8Ammonia bullet Acetonitrile)

By formula: (H4N+ bullet 7H3N bullet C2H3N) + H3N = (H4N+ bullet 8H3N bullet C2H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar25.kJ/molMKERTzeng, Wei, et al., 1991gas phase; from graph; M

(NH4+ bullet 8Ammonia bullet Acetonitrile) + Ammonia = (NH4+ bullet 9Ammonia bullet Acetonitrile)

By formula: (H4N+ bullet 8H3N bullet C2H3N) + H3N = (H4N+ bullet 9H3N bullet C2H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar23.kJ/molMKERTzeng, Wei, et al., 1991gas phase; from graph; M

(NH4+ bullet Ammonia bullet Acetonitrile) + Ammonia = (NH4+ bullet 2Ammonia bullet Acetonitrile)

By formula: (H4N+ bullet H3N bullet C2H3N) + H3N = (H4N+ bullet 2H3N bullet C2H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar64.9kJ/molMKERTzeng, Wei, et al., 1991gas phase; from graph; M

(C2H4N+ bullet Acetonitrile bullet 2Methyl Alcohol) + Acetonitrile = (C2H4N+ bullet 2Acetonitrile bullet 2Methyl Alcohol)

By formula: (C2H4N+ bullet C2H3N bullet 2CH4O) + C2H3N = (C2H4N+ bullet 2C2H3N bullet 2CH4O)

Quantity Value Units Method Reference Comment
Deltar65.3kJ/molPHPMSEl-Shall, Olafsdottir, et al., 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar90.4J/mol*KPHPMSEl-Shall, Olafsdottir, et al., 1991gas phase; M

(C2H4N+ bullet Acetonitrile bullet Methyl Alcohol) + Acetonitrile = (C2H4N+ bullet 2Acetonitrile bullet Methyl Alcohol)

By formula: (C2H4N+ bullet C2H3N bullet CH4O) + C2H3N = (C2H4N+ bullet 2C2H3N bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar29.kJ/molPHPMSEl-Shall, Olafsdottir, et al., 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar51.9J/mol*KPHPMSEl-Shall, Olafsdottir, et al., 1991gas phase; M

cyclopentadienide anion + Acetonitrile = (cyclopentadienide anion bullet Acetonitrile)

By formula: C5H5- + C2H3N = (C5H5- bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar64.9 ± 4.2kJ/molTDAsMeot-ner, 1988, 2gas phase; B
Quantity Value Units Method Reference Comment
Deltar36. ± 4.2kJ/molTDAsMeot-ner, 1988, 2gas phase; B

(CH6N+ bullet Acetonitrile) + Methanethiol = (CH6N+ bullet Methanethiol bullet Acetonitrile)

By formula: (CH6N+ bullet C2H3N) + CH4S = (CH6N+ bullet CH4S bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar41.kJ/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar83.7J/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M

(C2H4N+ bullet Methyl Alcohol) + Acetonitrile = (C2H4N+ bullet Acetonitrile bullet Methyl Alcohol)

By formula: (C2H4N+ bullet CH4O) + C2H3N = (C2H4N+ bullet C2H3N bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar94.6kJ/molPHPMSEl-Shall, Olafsdottir, et al., 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar103.J/mol*KPHPMSEl-Shall, Olafsdottir, et al., 1991gas phase; M

(NH4+ bullet 2Acetonitrile) + Acetonitrile = (NH4+ bullet 3Acetonitrile)

By formula: (H4N+ bullet 2C2H3N) + C2H3N = (H4N+ bullet 3C2H3N)

Quantity Value Units Method Reference Comment
Deltar59.4kJ/molPHPMSLiebman, Romm, et al., 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar81.6J/mol*KPHPMSLiebman, Romm, et al., 1991gas phase; M

(NH4+ bullet 3Acetonitrile) + Acetonitrile = (NH4+ bullet 4Acetonitrile)

By formula: (H4N+ bullet 3C2H3N) + C2H3N = (H4N+ bullet 4C2H3N)

Quantity Value Units Method Reference Comment
Deltar49.0kJ/molPHPMSLiebman, Romm, et al., 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar92.9J/mol*KPHPMSLiebman, Romm, et al., 1991gas phase; M

C4H9O2+ + Acetonitrile = (C4H9O2+ bullet Acetonitrile)

By formula: C4H9O2+ + C2H3N = (C4H9O2+ bullet C2H3N)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
79.1320.ICRBromilow, Abboud, et al., 1980gas phase; switching reaction((CH3)2O)H+)(CH3)2O; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984; M

(NH4+ bullet Acetonitrile) + Acetonitrile = (NH4+ bullet 2Acetonitrile)

By formula: (H4N+ bullet C2H3N) + C2H3N = (H4N+ bullet 2C2H3N)

Quantity Value Units Method Reference Comment
Deltar88.7kJ/molPHPMSLiebman, Romm, et al., 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar106.J/mol*KPHPMSLiebman, Romm, et al., 1991gas phase; M

(CH6N+ bullet 2Acetonitrile) + Acetonitrile = (CH6N+ bullet 3Acetonitrile)

By formula: (CH6N+ bullet 2C2H3N) + C2H3N = (CH6N+ bullet 3C2H3N)

Quantity Value Units Method Reference Comment
Deltar56.1kJ/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar87.9J/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M

(Cesium ion (1+) bullet 2Acetonitrile) + Acetonitrile = (Cesium ion (1+) bullet 3Acetonitrile)

By formula: (Cs+ bullet 2C2H3N) + C2H3N = (Cs+ bullet 3C2H3N)

Quantity Value Units Method Reference Comment
Deltar59.8kJ/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

(Cesium ion (1+) bullet 3Acetonitrile) + Acetonitrile = (Cesium ion (1+) bullet 4Acetonitrile)

By formula: (Cs+ bullet 3C2H3N) + C2H3N = (Cs+ bullet 4C2H3N)

Quantity Value Units Method Reference Comment
Deltar50.6kJ/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
Deltar113.J/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

(Cesium ion (1+) bullet 4Acetonitrile) + Acetonitrile = (Cesium ion (1+) bullet 5Acetonitrile)

By formula: (Cs+ bullet 4C2H3N) + C2H3N = (Cs+ bullet 5C2H3N)

Quantity Value Units Method Reference Comment
Deltar45.6kJ/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
Deltar138.J/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

(Rubidium ion (1+) bullet 2Acetonitrile) + Acetonitrile = (Rubidium ion (1+) bullet 3Acetonitrile)

By formula: (Rb+ bullet 2C2H3N) + C2H3N = (Rb+ bullet 3C2H3N)

Quantity Value Units Method Reference Comment
Deltar65.7kJ/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
Deltar104.J/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

(Rubidium ion (1+) bullet 3Acetonitrile) + Acetonitrile = (Rubidium ion (1+) bullet 4Acetonitrile)

By formula: (Rb+ bullet 3C2H3N) + C2H3N = (Rb+ bullet 4C2H3N)

Quantity Value Units Method Reference Comment
Deltar52.3kJ/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
Deltar108.J/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meot-ner, 1988
Meot-ner, M., Ionic Hydrogen Bond and Ion Solvation. 6. Interaction Energies of the Acetate Ion with Organic Molecules. Comparison of CH3COO- with Cl-, CN-, and SH-, J. Am. Chem. Soc., 1988, 110, 12, 3854, https://doi.org/10.1021/ja00220a022 . [all data]

Deakyne, Meot-Ner (Mautner), et al., 1986
Deakyne, C.A.; Meot-Ner (Mautner), M.; Campbell, C.L.; Hughes, M.G.; Murphy, S.P., Multicomponent Cluster Ions. 1. The Acetonitrile - Water System, J. Chem. Phys., 1986, 90, 4648. [all data]

Davidson and Kebarle, 1976
Davidson, W.R.; Kebarle, P., Ionic Solvation by Aprotic Solvents. Gas Phase Solvation of the Alkali Ions by Acetonitrile, J. Am. Chem. Soc., 1976, 98, 20, 6125, https://doi.org/10.1021/ja00436a010 . [all data]

Meot-ner, 1988, 2
Meot-ner, M., The Ionic Hydrogen Bond and Solvation. 7. Interaction Energies of Carbanions with Solvent Molecules, J. Am. Chem. Soc., 1988, 110, 12, 3858, https://doi.org/10.1021/ja00220a022 . [all data]

Mackay, Rakshit, et al., 1982
Mackay, G.I.; Rakshit, A.B.; Bohme, D.K., An Experimental Study of the Reactivity and Relative Basicity of the Methoxide Anion in the Gas Phase at Room Temperature, and their Perturbation by Methanol Solvent, Can. J. Chem., 1982, 60, 20, 2594, https://doi.org/10.1139/v82-373 . [all data]

Valina, 2001
Valina, A.B., Collision-Induced Dissociation and Theoretical Studies of Na+-Acetonitrile Complexes, J. Phys. Chem. A, 2001, 105, 49, 11057, https://doi.org/10.1021/jp0128123 . [all data]

Chowdhury, Grimsrud, et al., 1987
Chowdhury, S.; Grimsrud, E.P.; Kebarle, P., Bonding of Charged Delocalized Anions to Protic and Dipolar Aprotic Solvent Molecules, J. Phys. Chem., 1987, 91, 10, 2551, https://doi.org/10.1021/j100294a021 . [all data]

Chowdhury, 1987
Chowdhury, S. Grimsrud, Bonding of Charge Delocalized Anions to Protic and Dipolar Aprotic Solvents, J. Phys. Chem., 1987, 91, 10, 2551, https://doi.org/10.1021/j100294a021 . [all data]

Bromilow, Abboud, et al., 1980
Bromilow, J.; Abboud, J.L.M.; Lebrilla, C.B.; Taft, R.W.; Scorrano, G.; Lucchini, V., Oxonium Ions. Solvation by Single Acetonitrile Molecules in the Gas Phase and by Bulk Solvents, J. Am. Chem. Soc., 1980, 103, 18, 5448, https://doi.org/10.1021/ja00408a028 . [all data]

Grimsrud and Kebarle, 1973
Grimsrud, E.P.; Kebarle, P., Gas Phase Ion Equilibria Studies of the Solvation of the Hydrogen Ion by Methanol, Dimethyl Ether and Water. Effect of Hydrogen Bonding, J. Am. Chem. Soc., 1973, 95, 24, 7939, https://doi.org/10.1021/ja00805a002 . [all data]

Tzeng, Wei, et al., 1991
Tzeng, W.B.; Wei, S.; Castleman, A.W., Stability, Structure and Binding - Energies of Solvated Cluster Ions - Ammonia Acetonitrile and Ammonia Acetaldehyde Systems, J. Phys. Chem., 1991, 95, 15, 5757, https://doi.org/10.1021/j100168a011 . [all data]

El-Shall, Olafsdottir, et al., 1991
El-Shall, M.S.; Olafsdottir, S.; Meot-ner (Mautner), M.; Sieck, L.W., Energy effects on cluster ion distributions: Beam expansion and thermochemical studies on mixed clusters of methanol and acetonitrile, Chem. Phys. Lett., 1991, 185, 3-4, 193, https://doi.org/10.1016/S0009-2614(91)85046-Y . [all data]

Meot-Ner (Mautner) and Sieck, 1985
Meot-Ner (Mautner), M.; Sieck, L.W., The Ionic Hydrogen Bond and Ion Solvation. 4. SH+ O and NH+ S Bonds. Correlations with Proton Affinity. Mutual Effects of Weak and Strong Ligands in Mixed Clusters, J. Phys. Chem., 1985, 89, 24, 5222, https://doi.org/10.1021/j100270a021 . [all data]

Liebman, Romm, et al., 1991
Liebman, J.F.; Romm, M.J.; Meot-Ner (Mautner), M.; Cybulski, S.M.; Scheiner, S., Isotropy in ionic interactions. 2. How spherical is the ammonium ion? Comparison of the gas-phase clustering energies and condensed-phase thermochemistry of K+ and NH4+, J. Phys. Chem., 1991, 95, 3, 1112, https://doi.org/10.1021/j100156a018 . [all data]

Lias, Liebman, et al., 1984
Lias, S.G.; Liebman, J.F.; Levin, R.D., Evaluated gas phase basicities and proton affinities of molecules heats of formation of protonated molecules, J. Phys. Chem. Ref. Data, 1984, 13, 695. [all data]


Notes

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