Ethene, chloro-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil259.45KN/ADreisbach and Martin, 1949Uncertainty assigned by TRC = 0.2 K; TRC
Tboil259.05KN/AStull, 1946Uncertainty assigned by TRC = 0.4 K; TRC
Tboil259.3KN/ADana, Burdick, et al., 1927Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Tfus94.43KN/AMcDonald, Shrader, et al., 1959Uncertainty assigned by TRC = 0.1 K; TRC
Tfus119.36KN/ADreisbach, 1955Uncertainty assigned by TRC = 0.02 K; TRC
Tfus113.5KN/ADana, Burdick, et al., 1927Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Ttriple119.31KN/ALebedev, Rabinovich, et al., 1967Uncertainty assigned by TRC = 0.02 K; TRC
Quantity Value Units Method Reference Comment
Δvap5.0 ± 0.2kcal/molReviewManion, 2002derived from vapor pressure data of Dana, Burdick, et al., 1927 plus a correction for non-ideality; DRB

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
5.57245.AStephenson and Malanowski, 1987Based on data from 209. - 260. K. See also McDonald, Shrader, et al., 1959, 2 and Dykyj, 1970.; AC
5.43265.N/ADanov and Golubev, 1967Based on data from 243. - 288. K.; AC
5.47258.N/AHaccuria and Mathieu, 1967Based on data from 213. - 273. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference
165.3 - 259.43.98027892.757-35.051McDonald, Shrader, et al., 1959, 2

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Reference Comment
1.175119.31Lebedev, Rabinovich, et al., 1967, 2DH
1.18119.3Domalski and Hearing, 1996AC

Entropy of fusion

ΔfusS (cal/mol*K) Temperature (K) Reference Comment
9.85119.31Lebedev, Rabinovich, et al., 1967, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dreisbach and Martin, 1949
Dreisbach, R.R.; Martin, R.A., Physical Data on Some Organic Compounds, Ind. Eng. Chem., 1949, 41, 2875-8. [all data]

Stull, 1946
Stull, D.R., Anal. Chem., 1946, 18, 234. [all data]

Dana, Burdick, et al., 1927
Dana, L.I.; Burdick, J.N.; Jenkins, A.C., SOME PHYSICAL PROPERTIES OF VINYL CHLORIDE, J. Am. Chem. Soc., 1927, 49, 11, 2801, https://doi.org/10.1021/ja01410a021 . [all data]

McDonald, Shrader, et al., 1959
McDonald, R.A.; Shrader, S.A.; Stull, D.R., Vapor Pressures and Freezing Points of 30 Organics, J. Chem. Eng. Data, 1959, 4, 311. [all data]

Dreisbach, 1955
Dreisbach, R.R., Physical Properties of Chemical Compounds, Advances in Chemistry Series No. 15, Am. Chem. Soc.: Washington, D. C., 1955. [all data]

Lebedev, Rabinovich, et al., 1967
Lebedev, B.V.; Rabinovich, I.B.; Budarina, V.A., Heat Capacity of vinyl chloride, polyvinylchloride and polyvinylidene chloride in the region of 60-300 K, Polym. Sci. USSR (Engl. Transl.), 1967, 9, 545. [all data]

Manion, 2002
Manion, J.A., Evaluated Enthalpies of Formation of the Stable Closed Shell C1 and C2 Chlorinated Hydrocarbons, J. Phys. Chem. Ref. Data, 2002, 31, 1, 123-172, https://doi.org/10.1063/1.1420703 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

McDonald, Shrader, et al., 1959, 2
McDonald, R.A.; Shrader, S.A.; Stull, D.R., Vapor Pressures and Freezing Points of Thirty Pure Organic Compounds., J. Chem. Eng. Data, 1959, 4, 4, 311-313, https://doi.org/10.1021/je60004a009 . [all data]

Dykyj, 1970
Dykyj, J., Petrochemica, 1970, 10, 2, 51. [all data]

Danov and Golubev, 1967
Danov, S.M.; Golubev, Y.D., Tr. Khim. Khim. Tekhnol, 1967, 52. [all data]

Haccuria and Mathieu, 1967
Haccuria, M.; Mathieu, M.P., Ind. Chim. Belg., 1967, 32, 165. [all data]

Lebedev, Rabinovich, et al., 1967, 2
Lebedev, B.V.; Rabinovich, I.B.; Budarina, V.A., Heat capacity of vinyl chloride, polyvinylchloride and polyvinylidene chloride in the region of 60-300°K, Polymer Sci., 1967, USSR 9A, 545-552. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]


Notes

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