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Mercury(II) chloride


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Quantity Value Units Method Reference Comment
IE (evaluated)11.38 ± 0.01eVN/AN/AL

Ionization energy determinations

IE (eV) Method Reference Comment
11.380 ± 0.003PILinn, Brom, et al., 1983LBLHLM
11.5PELee and Potts, 1981LLK
11.37PEEland, 1970RDSH
11.5PEBoggess, Allen, et al., 1973Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Cl+16.72 ± 0.32HgClPILinn, Brom, et al., 1983LBLHLM
Cl+17.7 ± 0.3?EIKiser, Dillard, et al., 1969RDSH
ClHg+<=11.041ClPILinn, Brom, et al., 1983LBLHLM
HgCl+12.06 ± 0.26ClEIKiser, Dillard, et al., 1969RDSH
Hg+12.59 ± 0.18Cl2PILinn, Brom, et al., 1983LBLHLM

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Linn, Brom, et al., 1983
Linn, S.H.; Brom, J.M., Jr.; Tzeng, W.-B.; Ng, C.Y., Molecular beam photoionization study of HgCl2, J. Chem. Phys., 1983, 78, 37. [all data]

Lee and Potts, 1981
Lee, E.P.F.; Potts, A.W., Fine structure in the He(I)/He(II) photoelectron spectra of the metal valence (d) shells of the group IIB dihalides, J. Electron Spectrosc. Relat. Phenom., 1981, 22, 247. [all data]

Eland, 1970
Eland, J.H.D., Photoelectron spectra and chemical bonding of mercury(II) compounds, Intern. J. Mass Spectrom. Ion Phys., 1970, 4, 37. [all data]

Boggess, Allen, et al., 1973
Boggess, G.W.; Allen, J.D., Jr.; Schweitzer, G.K., The photoelectron spectra of gaseous zinc(II) and cadmium(II) chlorides, bromides, and iodides, J. Electron Spectrosc. Relat. Phenom., 1973, 2, 467. [all data]

Kiser, Dillard, et al., 1969
Kiser, R.W.; Dillard, J.G.; Dugger, D.L., Mass spectrometry of inorganic halides, Advan. Chem. Ser., 1969, 72, 153. [all data]


Notes

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