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Ethylene

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

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Reactions 51 to 54

C3H5+ + Ethylene = (C3H5+ bullet Ethylene)

By formula: C3H5+ + C2H4 = (C3H5+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar69.9kJ/molPICeyer, Tiedemann, et al., 1979gas phase; M

C4H7+ + Ethylene = (C4H7+ bullet Ethylene)

By formula: C4H7+ + C2H4 = (C4H7+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar36.kJ/molPICeyer, Tiedemann, et al., 1979gas phase; M

Manganese ion (1+) + Ethylene = (Manganese ion (1+) bullet Ethylene)

By formula: Mn+ + C2H4 = (Mn+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar91. ± 12.kJ/molCIDTSievers, Jarvis, et al., 1998RCD

Sodium ion (1+) + Ethylene = (Sodium ion (1+) bullet Ethylene)

By formula: Na+ + C2H4 = (Na+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar43.1 ± 4.6kJ/molCIDTArmentrout and Rodgers, 2000RCD

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ceyer, Tiedemann, et al., 1979
Ceyer, S.T.; Tiedemann, P.W.; Ng, C.Y.; Mahan, B.H.; Lee, Y.T., Photoionization of Ethylene Clusters, J. Chem. Phys., 1979, 70, 5, 2138, https://doi.org/10.1063/1.437758 . [all data]

Sievers, Jarvis, et al., 1998
Sievers, M.R.; Jarvis, L.M.; Armentrout, P.B., Transition Metal Ethene Bonds: Thermochemistry of M+(C2H4)n (M=Ti-Cu, n=1 and 2) Complexes, J. Am. Chem. Soc., 1998, 120, 8, 1891, https://doi.org/10.1021/ja973834z . [all data]

Armentrout and Rodgers, 2000
Armentrout, P.B.; Rodgers, M.T., An Absolute Sodium Cation Affinity Scale: Threshold Collision-Induced Dissociation Experiments and ab Initio Theory, J. Phys. Chem A, 2000, 104, 11, 2238, https://doi.org/10.1021/jp991716n . [all data]


Notes

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