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Ethylene

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Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Silver ion (1+) + Ethylene = (Silver ion (1+) bullet Ethylene)

By formula: Ag+ + C2H4 = (Ag+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar141.kJ/molHPMSGuo and Castleman, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar92.5J/mol*KN/AGuo and Castleman, 1991gas phase; Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
71.5750.HPMSGuo and Castleman, 1991gas phase; Entropy change calculated or estimated; M

(Silver ion (1+) bullet Ethylene) + Ethylene = (Silver ion (1+) bullet 2Ethylene)

By formula: (Ag+ bullet C2H4) + C2H4 = (Ag+ bullet 2C2H4)

Quantity Value Units Method Reference Comment
Deltar136.kJ/molHPMSGuo and Castleman, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar126.J/mol*KHPMSGuo and Castleman, 1991gas phase; M

Aluminum ion (1+) + Ethylene = (Aluminum ion (1+) bullet Ethylene)

By formula: Al+ + C2H4 = (Al+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar54.4 ± 8.4kJ/molCIDC,EqGStockigt, Schwarz, et al., 1996Anchored to theory; RCD

C2H4+ + Ethylene = (C2H4+ bullet Ethylene)

By formula: C2H4+ + C2H4 = (C2H4+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar66.1kJ/molPIOno, Linn, et al., 1984gas phase; M
Deltar76.1kJ/molPICeyer, Tiedemann, et al., 1979gas phase; M

(C2H4+ bullet Ethylene) + Ethylene = (C2H4+ bullet 2Ethylene)

By formula: (C2H4+ bullet C2H4) + C2H4 = (C2H4+ bullet 2C2H4)

Quantity Value Units Method Reference Comment
Deltar18.kJ/molPICeyer, Tiedemann, et al., 1979gas phase; M

C3H5+ + Ethylene = (C3H5+ bullet Ethylene)

By formula: C3H5+ + C2H4 = (C3H5+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar69.9kJ/molPICeyer, Tiedemann, et al., 1979gas phase; M

C3H9Si+ + Ethylene = (C3H9Si+ bullet Ethylene)

By formula: C3H9Si+ + C2H4 = (C3H9Si+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar98.7kJ/molPHPMSLi and Stone, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar161.J/mol*KPHPMSLi and Stone, 1989gas phase; M

C4H7+ + Ethylene = (C4H7+ bullet Ethylene)

By formula: C4H7+ + C2H4 = (C4H7+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar36.kJ/molPICeyer, Tiedemann, et al., 1979gas phase; M

C6HCrO6+ + Ethylene = (C6HCrO6+ bullet Ethylene)

By formula: C6HCrO6+ + C2H4 = (C6HCrO6+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar59.8 ± 5.0kJ/molICRCDHop and McMahon, 1991gas phase; Ar collision gas; M

Cobalt ion (1+) + Ethylene = (Cobalt ion (1+) bullet Ethylene)

By formula: Co+ + C2H4 = (Co+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar186. ± 9.2kJ/molCIDTSievers, Jarvis, et al., 1998RCD

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
179. (+7.1,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M
27. (+13.,-0.) CIDHaynes and Armentrout, 1994gas phase; «DELTA»rH>=, guided ion beam CID; M

(Cobalt ion (1+) bullet Ethylene) + Ethylene = (Cobalt ion (1+) bullet 2Ethylene)

By formula: (Co+ bullet C2H4) + C2H4 = (Co+ bullet 2C2H4)

Quantity Value Units Method Reference Comment
Deltar152. ± 14.kJ/molCIDTSievers, Jarvis, et al., 1998RCD

Chromium ion (1+) + Ethylene = (Chromium ion (1+) bullet Ethylene)

By formula: Cr+ + C2H4 = (Cr+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar96. ± 11.kJ/molCIDTSievers, Jarvis, et al., 1998RCD

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
125. (+19.,-0.) CIDArmentrout and Kickel, 1994gas phase; «DELTA»rH>=, guided ion beam CID; M

(Chromium ion (1+) bullet Ethylene) + Ethylene = (Chromium ion (1+) bullet 2Ethylene)

By formula: (Cr+ bullet C2H4) + C2H4 = (Cr+ bullet 2C2H4)

Quantity Value Units Method Reference Comment
Deltar108. ± 11.kJ/molCIDTSievers, Jarvis, et al., 1998RCD

Copper ion (1+) + Ethylene = (Copper ion (1+) bullet Ethylene)

By formula: Cu+ + C2H4 = (Cu+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar176. ± 14.kJ/molCIDTSievers, Jarvis, et al., 1998RCD

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
95. (+11.,-0.) CIDArmentrout and Kickel, 1994gas phase; «DELTA»rH>=, guided ion beam CID; M

(Copper ion (1+) bullet Ethylene) + Ethylene = (Copper ion (1+) bullet 2Ethylene)

By formula: (Cu+ bullet C2H4) + C2H4 = (Cu+ bullet 2C2H4)

Quantity Value Units Method Reference Comment
Deltar174. ± 13.kJ/molCIDTSievers, Jarvis, et al., 1998RCD

Fluorine anion + Ethylene = (Fluorine anion bullet Ethylene)

By formula: F- + C2H4 = (F- bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar25. ± 13.kJ/molIMRBSullivan and Beauchamp, 1976gas phase; Structure: Roy and McMahon, 1985; B

Iron ion (1+) + Ethylene = (Iron ion (1+) bullet Ethylene)

By formula: Fe+ + C2H4 = (Fe+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar145. ± 11.kJ/molCIDTSievers, Jarvis, et al., 1998RCD

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
145. (+5.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet Ethylene) + Ethylene = (Iron ion (1+) bullet 2Ethylene)

By formula: (Fe+ bullet C2H4) + C2H4 = (Fe+ bullet 2C2H4)

Quantity Value Units Method Reference Comment
Deltar151. ± 15.kJ/molCIDTSievers, Jarvis, et al., 1998RCD

NH4+ + Ethylene = (NH4+ bullet Ethylene)

By formula: H4N+ + C2H4 = (H4N+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar42.kJ/molPHPMSDeakyne and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KN/ADeakyne and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
15.294.PHPMSDeakyne and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated; M

Lanthanum ion (1+) + Ethylene = (Lanthanum ion (1+) bullet Ethylene)

By formula: La+ + C2H4 = (La+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar220. ± 10.kJ/molPDissRanashinge and Freiser, 1992gas phase; M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
90.0 CIDArmentrout and Kickel, 1994gas phase; «DELTA»rH>=, guided ion beam CID; M

Manganese ion (1+) + Ethylene = (Manganese ion (1+) bullet Ethylene)

By formula: Mn+ + C2H4 = (Mn+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar91. ± 12.kJ/molCIDTSievers, Jarvis, et al., 1998RCD

(Manganese ion (1+) bullet Ethylene) + Ethylene = (Manganese ion (1+) bullet 2Ethylene)

By formula: (Mn+ bullet C2H4) + C2H4 = (Mn+ bullet 2C2H4)

Quantity Value Units Method Reference Comment
Deltar88. ± 14.kJ/molCIDTSievers, Jarvis, et al., 1998RCD

Sodium ion (1+) + Ethylene = (Sodium ion (1+) bullet Ethylene)

By formula: Na+ + C2H4 = (Na+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar43.1 ± 4.6kJ/molCIDTArmentrout and Rodgers, 2000RCD

Nickel ion (1+) + Ethylene = (Nickel ion (1+) bullet Ethylene)

By formula: Ni+ + C2H4 = (Ni+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar182. ± 11.kJ/molCIDTSievers, Jarvis, et al., 1998RCD

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
138. (+19.,-0.) CIDArmentrout and Kickel, 1994gas phase; «DELTA»rH>=, guided ion beam CID; M

(Nickel ion (1+) bullet Ethylene) + Ethylene = (Nickel ion (1+) bullet 2Ethylene)

By formula: (Ni+ bullet C2H4) + C2H4 = (Ni+ bullet 2C2H4)

Quantity Value Units Method Reference Comment
Deltar173. ± 14.kJ/molCIDTSievers, Jarvis, et al., 1998RCD

Rh+ + Ethylene = (Rh+ bullet Ethylene)

By formula: Rh+ + C2H4 = (Rh+ bullet C2H4)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
161. (+3.,-0.) CIDChen and Armetrout, 1995gas phase; guided ion beam CID; M

Scandium ion (1+) + Ethylene = (Scandium ion (1+) bullet Ethylene)

By formula: Sc+ + C2H4 = (Sc+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar220. ± 10.kJ/molPDissRanashinge and Freiser, 1992gas phase; M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
131. CIDArmentrout and Kickel, 1994gas phase; «DELTA»rH >=, guided ion beam CID; M

Titanium ion (1+) + Ethylene = (Titanium ion (1+) bullet Ethylene)

By formula: Ti+ + C2H4 = (Ti+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar146. ± 11.kJ/molCIDTSievers, Jarvis, et al., 1998RCD

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
119. CIDArmentrout and Kickel, 1994gas phase; «DELTA»rH>=, guided ion beam CID; M

Vanadium ion (1+) + Ethylene = (Vanadium ion (1+) bullet Ethylene)

By formula: V+ + C2H4 = (V+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar125. ± 7.9kJ/molCIDTSievers, Jarvis, et al., 1998RCD

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
117. CIDArmentrout and Kickel, 1994gas phase; «DELTA»rH>=, guided ion beam CID; M

(Vanadium ion (1+) bullet Ethylene) + Ethylene = (Vanadium ion (1+) bullet 2Ethylene)

By formula: (V+ bullet C2H4) + C2H4 = (V+ bullet 2C2H4)

Quantity Value Units Method Reference Comment
Deltar127. ± 14.kJ/molCIDTSievers, Jarvis, et al., 1998RCD

Yttrium ion (1+) + Ethylene = (Yttrium ion (1+) bullet Ethylene)

By formula: Y+ + C2H4 = (Y+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar220. ± 10.kJ/molPDissRanashinge and Freiser, 1992gas phase; M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
109. CIDArmentrout and Kickel, 1994gas phase; «DELTA»rH>=, guided ion beam CID; M

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Guo and Castleman, 1991
Guo, B.C.; Castleman, A.W., The Bonding Strength of Ag+(C2H4) and Ag+(C2H4)2 Complexes, Chem. Phys. Lett., 1991, 181, 1, 16, https://doi.org/10.1016/0009-2614(91)90214-T . [all data]

Stockigt, Schwarz, et al., 1996
Stockigt, D.; Schwarz, J.; Schwarz, H., Theoretical and Experimental Studies on the Bond Dissociation Energies of Al(methane)+, Al(acetylene)+, Al(ethene)+, and Al(ethane)+, J. Phys. Chem., 1996, 100, 21, 8786, https://doi.org/10.1021/jp960060k . [all data]

Ono, Linn, et al., 1984
Ono, Y.; Linn, S.H.; Tzeng, W.-B.; Ng, C.Y., A Study of the Unimolecular Decomposition of the (C2H4)2+ Complex, J. Chem. Phys., 1984, 80, 4, 1482, https://doi.org/10.1063/1.446897 . [all data]

Ceyer, Tiedemann, et al., 1979
Ceyer, S.T.; Tiedemann, P.W.; Ng, C.Y.; Mahan, B.H.; Lee, Y.T., Photoionization of Ethylene Clusters, J. Chem. Phys., 1979, 70, 5, 2138, https://doi.org/10.1063/1.437758 . [all data]

Li and Stone, 1989
Li, X.; Stone, J.A., Determination of the beta silicon effect from a mass spectrometric study of the association of trimethylsilylium ion with alkenes, J. Am. Chem. Soc., 1989, 111, 15, 5586, https://doi.org/10.1021/ja00197a013 . [all data]

Hop and McMahon, 1991
Hop, C.E.C.A.; McMahon, T.B., High Pressure Mass Spectrometric Observation of Metal Carbonyl Alkyl Adduct Ions of Novel Structure, Inorg. Chem., 1991, 30, 13, 2828, https://doi.org/10.1021/ic00013a025 . [all data]

Sievers, Jarvis, et al., 1998
Sievers, M.R.; Jarvis, L.M.; Armentrout, P.B., Transition Metal Ethene Bonds: Thermochemistry of M+(C2H4)n (M=Ti-Cu, n=1 and 2) Complexes, J. Am. Chem. Soc., 1998, 120, 8, 1891, https://doi.org/10.1021/ja973834z . [all data]

Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L., Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]

Haynes and Armentrout, 1994
Haynes, C.L.; Armentrout, P.B., Thermochemistry and Structures of CoC3H6+: Metallacyclic and Metal-Alkene Isomers, Organomettalics, 1994, 13, 9, 3480, https://doi.org/10.1021/om00021a022 . [all data]

Sullivan and Beauchamp, 1976
Sullivan, S.A.; Beauchamp, J.L., Competition between proton transfer and elimination in the reactions of strong bases with fluoroethanes in the gas phase. Influence of base strength on reactivity, J. Am. Chem. Soc., 1976, 98, 1160. [all data]

Roy and McMahon, 1985
Roy, M.; McMahon, T.B., The Anomalous Gas Phase Acidity of Ethyl Fluoride. An ab initio Investigation of the Importance of Hydrogen Bonding between Fluoride and sp2 and sp C-H Bonds., Can. J. Chem., 1985, 63, 3, 708, https://doi.org/10.1139/v85-117 . [all data]

Deakyne and Meot-Ner (Mautner), 1985
Deakyne, C.A.; Meot-Ner (Mautner), M., Unconventional Ionic Hydrogen Bonds. 2. NH+ pi. Complexes of Onium Ions with Olefins and Benzene Derivatives, J. Am. Chem. Soc., 1985, 107, 2, 474, https://doi.org/10.1021/ja00288a034 . [all data]

Ranashinge and Freiser, 1992
Ranashinge, Y.A.; Freiser, B.S., Gas-Phase Photodissociation of MC2H2+ (M = Sc, Y, La). Determination of D0(M+ - C2H2), Chem. Phys. Let., 1992, 200, 1-2, 135, https://doi.org/10.1016/0009-2614(92)87058-W . [all data]

Armentrout and Rodgers, 2000
Armentrout, P.B.; Rodgers, M.T., An Absolute Sodium Cation Affinity Scale: Threshold Collision-Induced Dissociation Experiments and ab Initio Theory, J. Phys. Chem A, 2000, 104, 11, 2238, https://doi.org/10.1021/jp991716n . [all data]

Chen and Armetrout, 1995
Chen, Y.M.; Armetrout, P.B., Activation of C2H6, C3H8, and c-C3H6 by Gas-Phase Rh+ and the Thermochemistry of Rh-Ligand Complexes, J. Am. Chem. Soc., 1995, 117, 36, 9291, https://doi.org/10.1021/ja00141a022 . [all data]


Notes

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