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Monomethyl carbonate


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

Monomethyl carbonate = Carbon dioxide + Methyl Alcohol

By formula: C2H4O3 = CO2 + CH4O

Quantity Value Units Method Reference Comment
Deltar18. ± 2.kJ/molKinBehrendt and Gattow, 1973solid phase
Deltar13. ± 4.kJ/molEqkHemmaplardh and King, 1972gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Behrendt and Gattow, 1973
Behrendt, W.; Gattow, G., Uber Chalkogenolates. LXII. Untersuchungen uber Halbester der Kohlensaure 2. Darstellung und Eigenschaften der Monomethylkohlensaure, Z. Anorg. Allg. Chem., 1973, 398, 198-206. [all data]

Hemmaplardh and King, 1972
Hemmaplardh, B.; King, A.D., Jr., Solubility of methanol in compressed nitrogen, argon, methane, ethylene, ethane, carbon dioxide, and nitrous oxide. Evidence for association of carbon dioxide with methanol in the gas phase, J. Phys. Chem., 1972, 76, 2170-2175. [all data]


Notes

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