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lithium chloride

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

Quantity Value Units Method Reference Comment
IE (evaluated)9.57eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)827.kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity800.5kJ/molN/AHunter and Lias, 1998HL

Electron affinity determinations

EA (eV) Method Reference Comment
0.593 ± 0.010LPESMiller, Leopold, et al., 1986B
0.610 ± 0.020LPESCarlstein, Peterson, et al., 1976B
>1.27998EIAEEbinghaus, 1964From (LiCl)2; B

Ionization energy determinations

IE (eV) Method Reference Comment
10.0EIBloom and Williams, 1981LLK
9.57PIBerkowitz, Batson, et al., 1980LLK
10.1EIBerkowitz, Tasman, et al., 1962RDSH
10.01 ± 0.02PEPotts and Lee, 1979Vertical value; LLK
9.80 ± 0.10PEPoole, Jenkin, et al., 1973Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Li+10.17ClPIBerkowitz, Batson, et al., 1980LLK
Li+10.6ClEIBerkowitz, Tasman, et al., 1962RDSH

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Miller, Leopold, et al., 1986
Miller, T.M.; Leopold, D.G.; Murray, K.K.; Lineberger, W.C., Electron Affinities of the Alkali Halides and the Structure of their Negative Ions, J. Chem. Phys., 1986, 85, 5, 2368, https://doi.org/10.1063/1.451091 . [all data]

Carlstein, Peterson, et al., 1976
Carlstein, J.L.; Peterson, J.R.; Lineberger, W.C., Binding of an electron by the field of a molecular dipole - LiCl-, Chem. Phys. Lett., 1976, 37, 5. [all data]

Ebinghaus, 1964
Ebinghaus, H.Z., Negative Ionen aus Alkalihalogeniden und Electronenaffinitaten der Alkalimetalle und Alkalihalogenide, Z. Naturfor., 1964, 19A, 727. [all data]

Bloom and Williams, 1981
Bloom, H.; Williams, D.J., A mass spectrometric study of the vapors above the molten salt systems LiCl-CuCl, LiBr-CuBr, and NaI-CuI, J. Chem. Phys., 1981, 75, 4636. [all data]

Berkowitz, Batson, et al., 1980
Berkowitz, J.; Batson, C.H.; Goodman, G.L., Photoionization of lithium chloride vapors: The structure and stability of alkali halide molecules and ions, J. Chim. Phys., 1980, 77, 631. [all data]

Berkowitz, Tasman, et al., 1962
Berkowitz, J.; Tasman, H.A.; Chupka, W.A., Double-oven experiments with lithium halide vapors, J. Chem. Phys., 1962, 36, 2170. [all data]

Potts and Lee, 1979
Potts, A.W.; Lee, E.P.F., Photoelectron spectra and electronic structure of lithium halide monomers and dimers, J. Chem. Soc. Faraday Trans. 2, 1979, 75, 941. [all data]

Poole, Jenkin, et al., 1973
Poole, R.T.; Jenkin, J.G.; Leckey, R.C.G.; Liesegang, J., Photoelectron study of the alkali chlorides, Chem. Phys. Lett., 1973, 22, 101. [all data]


Notes

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