Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

lithium chloride

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.

Gas phase ion energetics data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

Quantity Value Units Method Reference Comment
IE (evaluated)9.57eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)827.kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity800.5kJ/molN/AHunter and Lias, 1998HL

Electron affinity determinations

EA (eV) Method Reference Comment
0.593 ± 0.010LPESMiller, Leopold, et al., 1986B
0.610 ± 0.020LPESCarlstein, Peterson, et al., 1976B
>1.27998EIAEEbinghaus, 1964From (LiCl)2; B

Ionization energy determinations

IE (eV) Method Reference Comment
10.0EIBloom and Williams, 1981LLK
9.57PIBerkowitz, Batson, et al., 1980LLK
10.1EIBerkowitz, Tasman, et al., 1962RDSH
10.01 ± 0.02PEPotts and Lee, 1979Vertical value; LLK
9.80 ± 0.10PEPoole, Jenkin, et al., 1973Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Li+10.17ClPIBerkowitz, Batson, et al., 1980LLK
Li+10.6ClEIBerkowitz, Tasman, et al., 1962RDSH


Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Miller, Leopold, et al., 1986
Miller, T.M.; Leopold, D.G.; Murray, K.K.; Lineberger, W.C., Electron Affinities of the Alkali Halides and the Structure of their Negative Ions, J. Chem. Phys., 1986, 85, 5, 2368, https://doi.org/10.1063/1.451091 . [all data]

Carlstein, Peterson, et al., 1976
Carlstein, J.L.; Peterson, J.R.; Lineberger, W.C., Binding of an electron by the field of a molecular dipole - LiCl-, Chem. Phys. Lett., 1976, 37, 5. [all data]

Ebinghaus, 1964
Ebinghaus, H.Z., Negative Ionen aus Alkalihalogeniden und Electronenaffinitaten der Alkalimetalle und Alkalihalogenide, Z. Naturfor., 1964, 19A, 727. [all data]

Bloom and Williams, 1981
Bloom, H.; Williams, D.J., A mass spectrometric study of the vapors above the molten salt systems LiCl-CuCl, LiBr-CuBr, and NaI-CuI, J. Chem. Phys., 1981, 75, 4636. [all data]

Berkowitz, Batson, et al., 1980
Berkowitz, J.; Batson, C.H.; Goodman, G.L., Photoionization of lithium chloride vapors: The structure and stability of alkali halide molecules and ions, J. Chim. Phys., 1980, 77, 631. [all data]

Berkowitz, Tasman, et al., 1962
Berkowitz, J.; Tasman, H.A.; Chupka, W.A., Double-oven experiments with lithium halide vapors, J. Chem. Phys., 1962, 36, 2170. [all data]

Potts and Lee, 1979
Potts, A.W.; Lee, E.P.F., Photoelectron spectra and electronic structure of lithium halide monomers and dimers, J. Chem. Soc. Faraday Trans. 2, 1979, 75, 941. [all data]

Poole, Jenkin, et al., 1973
Poole, R.T.; Jenkin, J.G.; Leckey, R.C.G.; Liesegang, J., Photoelectron study of the alkali chlorides, Chem. Phys. Lett., 1973, 22, 101. [all data]


Go To: Top, Gas phase ion energetics data, References