potassium chloride

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas-51.310kcal/molReviewChase, 1998Data last reviewed in March, 1966
Quantity Value Units Method Reference Comment
gas,1 bar57.144cal/mol*KReviewChase, 1998Data last reviewed in March, 1966

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 2000. to 6000.
A 8.932300
B 0.189377
C -0.002318
D 0.000198
E -0.023795
F -54.06140
G 67.76231
H -51.31011
ReferenceChase, 1998
Comment Data last reviewed in March, 1966

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfliquid-100.81kcal/molReviewChase, 1998Data last reviewed in March, 1966
Quantity Value Units Method Reference Comment
liquid,1 bar20.71cal/mol*KReviewChase, 1998Data last reviewed in March, 1966
Quantity Value Units Method Reference Comment
Δfsolid-104.37kcal/molReviewChase, 1998Data last reviewed in March, 1966
Quantity Value Units Method Reference Comment
solid19.73cal/mol*KReviewChase, 1998Data last reviewed in March, 1966

Liquid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 1044. to 2000.
A 17.59010
B 0.000000
C 0.000000
D 0.000000
E 0.000000
F -106.0550
G 41.99830
H -100.8110
ReferenceChase, 1998
Comment Data last reviewed in March, 1966

Solid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 900.900. to 1044.
A 8.464620-171.4590
B 16.73870298.2459
C -21.84090-169.3390
D 12.5536033.80581
E 0.03667824.77801
F -107.34600.420670
G 26.05120-176.4180
H -104.3700-104.3700
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in March, 1966 Data last reviewed in March, 1966

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
1170. to 1466.4.610976910.833-176.083Barchuk and Dubovoi, 1973Coefficents calculated by NIST from author's data.
1094. to 1680.4.776657440.691-122.709Stull, 1947Coefficents calculated by NIST from author's data.

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Potassium ion (1+) + potassium chloride = (Potassium ion (1+) • potassium chloride)

By formula: K+ + ClK = (K+ • ClK)

Quantity Value Units Method Reference Comment
Δr41.2kcal/molMSChupka, 1959gas phase; Knudsen cell; M
Quantity Value Units Method Reference Comment
Δr19.6cal/mol*KMSChupka, 1959gas phase; Knudsen cell; M

3Pyridine, 1-oxide + potassium chloride = 3Pyridine + KClO3

By formula: 3C5H5NO + ClK = 3C5H5N + KClO3

Quantity Value Units Method Reference Comment
Δr75.2 ± 2.4kcal/molCmShaofeng and Pilcher, 1988solid phase; ALS

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
0.582 ± 0.010LPESMiller, Leopold, et al., 1986B
0.629995NBAEDe Vreugd, Wijnaendts van Resandt, et al., 1979B
>1.27001EIAEEbinghaus, 1964From (KCl)2; B

Ionization energy determinations

IE (eV) Method Reference Comment
10.5EIItoh, Sasamoto, et al., 1981LLK
8.3EIBloom and Williams, 1981LLK
8.4 ± 0.1PEPotts and Price, 1977LLK
8.4 ± 0.1PEPotts, Williams, et al., 1974LLK
10.1EIGrimley and Joyce, 1969RDSH
8.0 ± 0.3EIBloom, Hastie, et al., 1968RDSH
8.7PEGoodman, Allen, et al., 1974Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
K+11.0ClEIItoh, Sasamoto, et al., 1981LLK
K+25.22 ± 0.04Cl(-)PEPotts and Price, 1977LLK
K+10.6ClEIGrimley and Joyce, 1969RDSH
K+9.1 ± 0.3ClEIBloom, Hastie, et al., 1968RDSH
K+24.98 ± 0.04Cl(-)PEPotts and Price, 1977Vertical value; LLK

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Potassium ion (1+) + potassium chloride = (Potassium ion (1+) • potassium chloride)

By formula: K+ + ClK = (K+ • ClK)

Quantity Value Units Method Reference Comment
Δr41.2kcal/molMSChupka, 1959gas phase; Knudsen cell
Quantity Value Units Method Reference Comment
Δr19.6cal/mol*KMSChupka, 1959gas phase; Knudsen cell

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Barchuk and Dubovoi, 1973
Barchuk, V.T.; Dubovoi, P.G., Measurement of a Saturated Vapor Pressure Over Highly Volitile Salt Melts, Ukr. Khim. Zh. (Russ. Ed.), 1973, 39, 8, 838-840. [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Chupka, 1959
Chupka, W.A., Dissociation Energies of Some Gaseous Halide Complex Ions and the Hydrated Ion K(H2O)+, J. Chem. Phys., 1959, 40, 2, 458, https://doi.org/10.1063/1.1729974 . [all data]

Shaofeng and Pilcher, 1988
Shaofeng, L.; Pilcher, G., Enthalpy of formation of pyridine-N-oxide: the dissociation enthalpy of the (N-O) bond, J. Chem. Thermodyn., 1988, 20, 463-465. [all data]

Miller, Leopold, et al., 1986
Miller, T.M.; Leopold, D.G.; Murray, K.K.; Lineberger, W.C., Electron Affinities of the Alkali Halides and the Structure of their Negative Ions, J. Chem. Phys., 1986, 85, 5, 2368, https://doi.org/10.1063/1.451091 . [all data]

De Vreugd, Wijnaendts van Resandt, et al., 1979
De Vreugd, C.; Wijnaendts van Resandt, R.W.; Los, J.; Smith, B., Differential Cross Sections for Collisions of Negative Halogen Ions and Alkali Atoms, Chem. Phys., 1979, 42, 3, 305, https://doi.org/10.1016/0301-0104(79)80078-6 . [all data]

Ebinghaus, 1964
Ebinghaus, H.Z., Negative Ionen aus Alkalihalogeniden und Electronenaffinitaten der Alkalimetalle und Alkalihalogenide, Z. Naturfor., 1964, 19A, 727. [all data]

Itoh, Sasamoto, et al., 1981
Itoh, M.; Sasamoto, T.; Sata, T., Mass-spectrometric measurement of activities in both solid and liquid solutions of the KCl-NaCl system, Bull. Chem. Soc. Jpn., 1981, 54, 3391. [all data]

Bloom and Williams, 1981
Bloom, H.; Williams, D.J., A mass spectrometric study of the vapors above the molten salt systems LiCl-CuCl, LiBr-CuBr, and NaI-CuI, J. Chem. Phys., 1981, 75, 4636. [all data]

Potts and Price, 1977
Potts, A.W.; Price, W.C., Photoelectron studies of ionic materials using molecular beam techniques, Phys. Scr., 1977, 16, 191. [all data]

Potts, Williams, et al., 1974
Potts, A.W.; Williams, T.A.; Price, W.C., Photoelectron spectra and electronic structure of diatomic alkali halides, Proc. Roy. Soc. London A, 1974, 341, 147. [all data]

Grimley and Joyce, 1969
Grimley, R.T.; Joyce, T.E., A technique for the calibration of high-temperature mass spectrometers, J. Phys. Chem., 1969, 73, 3047. [all data]

Bloom, Hastie, et al., 1968
Bloom, H.; Hastie, J.W.; Morrison, J.D., Ionization and dissociation of the alkali halides by electron impact, J. Phys. Chem., 1968, 72, 3041. [all data]

Goodman, Allen, et al., 1974
Goodman, T.D.; Allen, J.D., Jr.; Cusachs, L.C.; Schweitzer, G.K., The photoelectron spectra of gaseous alkali halides, J. Electron Spectrosc. Relat. Phenom., 1974, 3, 289. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References