potassium chloride
- Formula: ClK
- Molecular weight: 74.551
- IUPAC Standard InChIKey: WCUXLLCKKVVCTQ-UHFFFAOYSA-M
- CAS Registry Number: 7447-40-7
- Chemical structure:
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Gas phase thermochemistry data
Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -51.310 | kcal/mol | Review | Chase, 1998 | Data last reviewed in March, 1966 |
Quantity | Value | Units | Method | Reference | Comment |
S°gas,1 bar | 57.144 | cal/mol*K | Review | Chase, 1998 | Data last reviewed in March, 1966 |
Gas Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (cal/mol*K)
H° = standard enthalpy (kcal/mol)
S° = standard entropy (cal/mol*K)
t = temperature (K) / 1000.
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Temperature (K) | 2000. to 6000. |
---|---|
A | 8.932300 |
B | 0.189377 |
C | -0.002318 |
D | 0.000198 |
E | -0.023795 |
F | -54.06140 |
G | 67.76231 |
H | -51.31011 |
Reference | Chase, 1998 |
Comment | Data last reviewed in March, 1966 |
Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°liquid | -100.81 | kcal/mol | Review | Chase, 1998 | Data last reviewed in March, 1966 |
Quantity | Value | Units | Method | Reference | Comment |
S°liquid,1 bar | 20.71 | cal/mol*K | Review | Chase, 1998 | Data last reviewed in March, 1966 |
Quantity | Value | Units | Method | Reference | Comment |
ΔfH°solid | -104.37 | kcal/mol | Review | Chase, 1998 | Data last reviewed in March, 1966 |
Quantity | Value | Units | Method | Reference | Comment |
S°solid | 19.73 | cal/mol*K | Review | Chase, 1998 | Data last reviewed in March, 1966 |
Liquid Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (cal/mol*K)
H° = standard enthalpy (kcal/mol)
S° = standard entropy (cal/mol*K)
t = temperature (K) / 1000.
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Temperature (K) | 1044. to 2000. |
---|---|
A | 17.59010 |
B | 0.000000 |
C | 0.000000 |
D | 0.000000 |
E | 0.000000 |
F | -106.0550 |
G | 41.99830 |
H | -100.8110 |
Reference | Chase, 1998 |
Comment | Data last reviewed in March, 1966 |
Solid Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (cal/mol*K)
H° = standard enthalpy (kcal/mol)
S° = standard entropy (cal/mol*K)
t = temperature (K) / 1000.
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Temperature (K) | 298. to 900. | 900. to 1044. |
---|---|---|
A | 8.464620 | -171.4590 |
B | 16.73870 | 298.2459 |
C | -21.84090 | -169.3390 |
D | 12.55360 | 33.80581 |
E | 0.036678 | 24.77801 |
F | -107.3460 | 0.420670 |
G | 26.05120 | -176.4180 |
H | -104.3700 | -104.3700 |
Reference | Chase, 1998 | Chase, 1998 |
Comment | Data last reviewed in March, 1966 | Data last reviewed in March, 1966 |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (atm)
T = temperature (K)
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Temperature (K) | A | B | C | Reference | Comment |
---|---|---|---|---|---|
1170. to 1466. | 4.61097 | 6910.833 | -176.083 | Barchuk and Dubovoi, 1973 | Coefficents calculated by NIST from author's data. |
1094. to 1680. | 4.77665 | 7440.691 | -122.709 | Stull, 1947 | Coefficents calculated by NIST from author's data. |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
By formula: K+ + ClK = (K+ • ClK)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 41.2 | kcal/mol | MS | Chupka, 1959 | gas phase; Knudsen cell; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 19.6 | cal/mol*K | MS | Chupka, 1959 | gas phase; Knudsen cell; M |
3 + = 3 + KClO3
By formula: 3C5H5NO + ClK = 3C5H5N + KClO3
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 75.2 ± 2.4 | kcal/mol | Cm | Shaofeng and Pilcher, 1988 | solid phase; ALS |
Gas phase ion energetics data
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess
Electron affinity determinations
EA (eV) | Method | Reference | Comment |
---|---|---|---|
0.582 ± 0.010 | LPES | Miller, Leopold, et al., 1986 | B |
0.629995 | NBAE | De Vreugd, Wijnaendts van Resandt, et al., 1979 | B |
>1.27001 | EIAE | Ebinghaus, 1964 | From (KCl)2; B |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
10.5 | EI | Itoh, Sasamoto, et al., 1981 | LLK |
8.3 | EI | Bloom and Williams, 1981 | LLK |
8.4 ± 0.1 | PE | Potts and Price, 1977 | LLK |
8.4 ± 0.1 | PE | Potts, Williams, et al., 1974 | LLK |
10.1 | EI | Grimley and Joyce, 1969 | RDSH |
8.0 ± 0.3 | EI | Bloom, Hastie, et al., 1968 | RDSH |
8.7 | PE | Goodman, Allen, et al., 1974 | Vertical value; LLK |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
K+ | 11.0 | Cl | EI | Itoh, Sasamoto, et al., 1981 | LLK |
K+ | 25.22 ± 0.04 | Cl(-) | PE | Potts and Price, 1977 | LLK |
K+ | 10.6 | Cl | EI | Grimley and Joyce, 1969 | RDSH |
K+ | 9.1 ± 0.3 | Cl | EI | Bloom, Hastie, et al., 1968 | RDSH |
K+ | 24.98 ± 0.04 | Cl(-) | PE | Potts and Price, 1977 | Vertical value; LLK |
Ion clustering data
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
By formula: K+ + ClK = (K+ • ClK)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 41.2 | kcal/mol | MS | Chupka, 1959 | gas phase; Knudsen cell |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 19.6 | cal/mol*K | MS | Chupka, 1959 | gas phase; Knudsen cell |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Barchuk and Dubovoi, 1973
Barchuk, V.T.; Dubovoi, P.G.,
Measurement of a Saturated Vapor Pressure Over Highly Volitile Salt Melts,
Ukr. Khim. Zh. (Russ. Ed.), 1973, 39, 8, 838-840. [all data]
Stull, 1947
Stull, Daniel R.,
Vapor Pressure of Pure Substances. Organic and Inorganic Compounds,
Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022
. [all data]
Chupka, 1959
Chupka, W.A.,
Dissociation Energies of Some Gaseous Halide Complex Ions and the Hydrated Ion K(H2O)+,
J. Chem. Phys., 1959, 40, 2, 458, https://doi.org/10.1063/1.1729974
. [all data]
Shaofeng and Pilcher, 1988
Shaofeng, L.; Pilcher, G.,
Enthalpy of formation of pyridine-N-oxide: the dissociation enthalpy of the (N-O) bond,
J. Chem. Thermodyn., 1988, 20, 463-465. [all data]
Miller, Leopold, et al., 1986
Miller, T.M.; Leopold, D.G.; Murray, K.K.; Lineberger, W.C.,
Electron Affinities of the Alkali Halides and the Structure of their Negative Ions,
J. Chem. Phys., 1986, 85, 5, 2368, https://doi.org/10.1063/1.451091
. [all data]
De Vreugd, Wijnaendts van Resandt, et al., 1979
De Vreugd, C.; Wijnaendts van Resandt, R.W.; Los, J.; Smith, B.,
Differential Cross Sections for Collisions of Negative Halogen Ions and Alkali Atoms,
Chem. Phys., 1979, 42, 3, 305, https://doi.org/10.1016/0301-0104(79)80078-6
. [all data]
Ebinghaus, 1964
Ebinghaus, H.Z.,
Negative Ionen aus Alkalihalogeniden und Electronenaffinitaten der Alkalimetalle und Alkalihalogenide,
Z. Naturfor., 1964, 19A, 727. [all data]
Itoh, Sasamoto, et al., 1981
Itoh, M.; Sasamoto, T.; Sata, T.,
Mass-spectrometric measurement of activities in both solid and liquid solutions of the KCl-NaCl system,
Bull. Chem. Soc. Jpn., 1981, 54, 3391. [all data]
Bloom and Williams, 1981
Bloom, H.; Williams, D.J.,
A mass spectrometric study of the vapors above the molten salt systems LiCl-CuCl, LiBr-CuBr, and NaI-CuI,
J. Chem. Phys., 1981, 75, 4636. [all data]
Potts and Price, 1977
Potts, A.W.; Price, W.C.,
Photoelectron studies of ionic materials using molecular beam techniques,
Phys. Scr., 1977, 16, 191. [all data]
Potts, Williams, et al., 1974
Potts, A.W.; Williams, T.A.; Price, W.C.,
Photoelectron spectra and electronic structure of diatomic alkali halides,
Proc. Roy. Soc. London A, 1974, 341, 147. [all data]
Grimley and Joyce, 1969
Grimley, R.T.; Joyce, T.E.,
A technique for the calibration of high-temperature mass spectrometers,
J. Phys. Chem., 1969, 73, 3047. [all data]
Bloom, Hastie, et al., 1968
Bloom, H.; Hastie, J.W.; Morrison, J.D.,
Ionization and dissociation of the alkali halides by electron impact,
J. Phys. Chem., 1968, 72, 3041. [all data]
Goodman, Allen, et al., 1974
Goodman, T.D.; Allen, J.D., Jr.; Cusachs, L.C.; Schweitzer, G.K.,
The photoelectron spectra of gaseous alkali halides,
J. Electron Spectrosc. Relat. Phenom., 1974, 3, 289. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References
- Symbols used in this document:
AE Appearance energy EA Electron affinity S°gas,1 bar Entropy of gas at standard conditions (1 bar) S°liquid,1 bar Entropy of liquid at standard conditions (1 bar) S°solid Entropy of solid at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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