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Acetic acid, trifluoro-, 1,2-dimethylbutyl ester, (R*,S*)-(+/-)-


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

2-Pentene, 3-methyl-, (E)- + Trifluoroacetic acid = Acetic acid, trifluoro-, 1,2-dimethylbutyl ester, (R*,S*)-(+/-)-

By formula: C6H12 + C2HF3O2 = C8H13F3O2

Quantity Value Units Method Reference Comment
Deltar-8.79 ± 0.06kcal/molCmWiberg and Hao, 1991liquid phase; Trifluoroacetolysis

Trifluoroacetic acid + 2-Pentene, 3-methyl-, (Z)- = Acetic acid, trifluoro-, 1,2-dimethylbutyl ester, (R*,S*)-(+/-)-

By formula: C2HF3O2 + C6H12 = C8H13F3O2

Quantity Value Units Method Reference Comment
Deltar-9.01 ± 0.02kcal/molCmWiberg and Hao, 1991liquid phase; Trifuoroacetolysis

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wiberg and Hao, 1991
Wiberg, K.B.; Hao, S., Enthalpies of hydration of alkenes. 4. Formation of acyclic tert-alcohols, J. Org. Chem., 1991, 56, 5108-5110. [all data]


Notes

Go To: Top, Reaction thermochemistry data, References