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bismuth

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Reaction thermochemistry data

Go To: Top, Gas phase ion energetics data, IR Spectrum, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(CAS Reg. No. 121055-32-1 bullet 4294967295bismuth) + bismuth = CAS Reg. No. 121055-32-1

By formula: (CAS Reg. No. 121055-32-1 bullet 4294967295Bi) + Bi = CAS Reg. No. 121055-32-1

Quantity Value Units Method Reference Comment
Deltar226. ± 4.2kJ/molN/APolak, Ho, et al., 1991gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to Bi+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)7.2855 ± 0.0001eVN/AN/AL

Electron affinity determinations

EA (eV) Method Reference Comment
0.941999LPDBilodeau and Haugen, 2001Given: 0.942362(13) eV; B
0.947 ± 0.010LPESFeigerle, Corderman, et al., 1981B
0.94 ± 0.10LPESSobhy, Reveles, et al., 2009B
1.20 ± 0.25PDFeldmann, Rackwitx, et al., 1977B

Ionization energy determinations

IE (eV) Method Reference Comment
7.289EVALLide, 1992LL
7.28537 ± 0.00012SGeorge, Munsee, et al., 1985LBLHLM
7.28562 ± 0.00004SYoung, Mirza, et al., 1980LLK
7.2 ± 0.5EIWagner and Grimley, 1974LLK
7.289SMoore, 1970RDSH

IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Timothy J. Johnson, Tanya L. Myers, Yin-Fong Su, Russell G. Tonkyn, Molly Rose K. Kelly-Gorham, and Tyler O. Danby

Condensed Phase Spectrum

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IR spectrum
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Additional Data

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Owner Public domain
Origin Pacific Northwest National Laboratory Under IARPA Contract
Date March 2017
State solid
Instrument Bruker Tensor 37 FTIR
Aperture 6 mm
External diffuse reflectance accessory A 562-G integrating sphere
Beam splitter Ge on KBr
Diameter of detector port in sphere 2×2 mm, 60° field of view MCT
Sphere diameter 75 mm
Acquisition mode double-sided, forward-backward
Scanner velocity 40 kHz
Co-added scans 2048
Phase resolution 32.00
Phase correction Mertz
Zero filling
Spectral range 7,500 to 600 cm-1 saved; 7500 to 600 cm-1 reported
Resolution 0.96450084
Spectral resolution 4 cm-1
Wavenumber accuracy ± 0.4 cm-1
Apodization function Blackman-Harris 3-term
Low-pass filter Open
Switch gain on 512 points

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, IR Spectrum, NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Polak, Ho, et al., 1991
Polak, M.L.; Ho, J.; Gerber, G.; Lineberger, W.C., Photoelectron Spectroscopy of Negatively Charged Bismuth Clusters: Bi2-, Bi3-, and Bi4-, J. Chem. Phys., 1991, 95, 5, 3053, https://doi.org/10.1063/1.460862 . [all data]

Bilodeau and Haugen, 2001
Bilodeau, R.C.; Haugen, H.K., Electron affinity of Bi using infrared laser photodetachment threshold spectroscopy - art. no. 024501, Phys. Rev. A, 2001, 64, 2, 024501, https://doi.org/10.1103/PhysRevA.64.024501 . [all data]

Feigerle, Corderman, et al., 1981
Feigerle, C.S.; Corderman, R.R.; Lineberger, W.C., Electron affinities of B, Al, Bi, and Pb, J. Chem. Phys., 1981, 74, 2, 1513, https://doi.org/10.1063/1.441174 . [all data]

Sobhy, Reveles, et al., 2009
Sobhy, M.A.; Reveles, J.U.; Gupta, U.; Khanna, S.N.; Castleman, A.W., Photoelectron imaging and theoretical investigation of bimetallic Bi1-2Ga0-2- and Pb-1-4(-) cluster anions, J. Chem. Phys., 2009, 130, 5, 054304, https://doi.org/10.1063/1.3069295 . [all data]

Feldmann, Rackwitx, et al., 1977
Feldmann, D.; Rackwitx, R.; Heinicke, E.; Kaiser, H.J., Photodetachment of Some Atomic Negative Ions: P-, As-, Sb-, Te-, Cr-, Ni-, Z. Physik A., 1977, 282, 2, 143-148, https://doi.org/10.1007/BF01408156 . [all data]

Lide, 1992
Lide, D.R. (Editor), Ionization potentials of atoms and atomic ions in Handbook of Chem. and Phys., 1992, 10-211. [all data]

George, Munsee, et al., 1985
George, S.; Munsee, J.K.; Verges, J., Newly observed 5f-ng transitions in Bi I spectrum, J. Opt. Soc. Am. B, 1985, 2, 1264. [all data]

Young, Mirza, et al., 1980
Young, W.A.; Mirza, M.Y.; Duley, W.W., Three-photon excitation of Rydberg series in lead and bismuth, J. Phys. B:, 1980, 13, 3175. [all data]

Wagner and Grimley, 1974
Wagner, L.C.; Grimley, R.T., A mass spectrometric study of the bismuth vapor system by the angular distribution technique, Chem. Phys. Lett., 1974, 29, 594. [all data]

Moore, 1970
Moore, C.E., Ionization potentials and ionization limits derived from the analyses of optical spectra, Natl. Stand. Ref. Data Ser., (U.S. Natl. Bur. Stand.), 1970, 34, 1. [all data]


Notes

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