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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to Bi+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)7.2855 ± 0.0001eVN/AN/AL

Electron affinity determinations

EA (eV) Method Reference Comment
0.941999LPDBilodeau and Haugen, 2001Given: 0.942362(13) eV; B
0.947 ± 0.010LPESFeigerle, Corderman, et al., 1981B
0.94 ± 0.10LPESSobhy, Reveles, et al., 2009B
1.20 ± 0.25PDFeldmann, Rackwitx, et al., 1977B

Ionization energy determinations

IE (eV) Method Reference Comment
7.289EVALLide, 1992LL
7.28537 ± 0.00012SGeorge, Munsee, et al., 1985LBLHLM
7.28562 ± 0.00004SYoung, Mirza, et al., 1980LLK
7.2 ± 0.5EIWagner and Grimley, 1974LLK
7.289SMoore, 1970RDSH


Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bilodeau and Haugen, 2001
Bilodeau, R.C.; Haugen, H.K., Electron affinity of Bi using infrared laser photodetachment threshold spectroscopy - art. no. 024501, Phys. Rev. A, 2001, 64, 2, 024501, https://doi.org/10.1103/PhysRevA.64.024501 . [all data]

Feigerle, Corderman, et al., 1981
Feigerle, C.S.; Corderman, R.R.; Lineberger, W.C., Electron affinities of B, Al, Bi, and Pb, J. Chem. Phys., 1981, 74, 2, 1513, https://doi.org/10.1063/1.441174 . [all data]

Sobhy, Reveles, et al., 2009
Sobhy, M.A.; Reveles, J.U.; Gupta, U.; Khanna, S.N.; Castleman, A.W., Photoelectron imaging and theoretical investigation of bimetallic Bi1-2Ga0-2- and Pb-1-4(-) cluster anions, J. Chem. Phys., 2009, 130, 5, 054304, https://doi.org/10.1063/1.3069295 . [all data]

Feldmann, Rackwitx, et al., 1977
Feldmann, D.; Rackwitx, R.; Heinicke, E.; Kaiser, H.J., Photodetachment of Some Atomic Negative Ions: P-, As-, Sb-, Te-, Cr-, Ni-, Z. Physik A., 1977, 282, 2, 143-148, https://doi.org/10.1007/BF01408156 . [all data]

Lide, 1992
Lide, D.R. (Editor), Ionization potentials of atoms and atomic ions in Handbook of Chem. and Phys., 1992, 10-211. [all data]

George, Munsee, et al., 1985
George, S.; Munsee, J.K.; Verges, J., Newly observed 5f-ng transitions in Bi I spectrum, J. Opt. Soc. Am. B, 1985, 2, 1264. [all data]

Young, Mirza, et al., 1980
Young, W.A.; Mirza, M.Y.; Duley, W.W., Three-photon excitation of Rydberg series in lead and bismuth, J. Phys. B:, 1980, 13, 3175. [all data]

Wagner and Grimley, 1974
Wagner, L.C.; Grimley, R.T., A mass spectrometric study of the bismuth vapor system by the angular distribution technique, Chem. Phys. Lett., 1974, 29, 594. [all data]

Moore, 1970
Moore, C.E., Ionization potentials and ionization limits derived from the analyses of optical spectra, Natl. Stand. Ref. Data Ser., (U.S. Natl. Bur. Stand.), 1970, 34, 1. [all data]


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