Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

vanadium

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Gas phase ion energetics data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to V+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)6.746 ± 0.002eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)859.4kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity836.8kJ/molN/AHunter and Lias, 1998HL

Electron affinity determinations

EA (eV) Method Reference Comment
0.526 ± 0.012LPESFeigerle, Corderman, et al., 1981B

Ionization energy determinations

IE (eV) Method Reference Comment
6.746 ± 0.002LSJames, Kowalczyk, et al., 1994LL
6.743EVALLide, 1992LL
6.7463LSPage and Gudeman, 1990LL
6.740SKelly, 1987LBLHLM
6.740 ± 0.002SSugar and Corliss, 1985LBLHLM
6.83PEDyke, Gravenor, et al., 1985LBLHLM
~7.5EIOwzarski and Franzen, 1974LLK
7. ± 1.EIFarber and Srivastava, 1973LLK
6.74SMoore, 1970RDSH

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Feigerle, Corderman, et al., 1981
Feigerle, C.S.; Corderman, R.R.; Bobashev, S.V.; Lineberger, W.C., Binding Energies and Structure of Transition Metal Negative Ions, J. Chem. Phys., 1981, 74, 3, 1580, https://doi.org/10.1063/1.441289 . [all data]

James, Kowalczyk, et al., 1994
James, A.M.; Kowalczyk, P.; Langlois, E.; Campbell, M.D.; Ogawa, A.; Simard, B., Resonant two photon ionization spectroscopy of the molecules V2, VNb, and Nb2, J. Chem. Phys., 1994, 101, 4485. [all data]

Lide, 1992
Lide, D.R. (Editor), Ionization potentials of atoms and atomic ions in Handbook of Chem. and Phys., 1992, 10-211. [all data]

Page and Gudeman, 1990
Page, R.H.; Gudeman, C.S., Completing the iron period: Double-resonance, fluorescence-dip rydberg spectroscopy and ionization potentials of titanium, vanadium, iron, cobalt, and nickel, J. Opt. Soc. Am. B, 1990, 1761. [all data]

Kelly, 1987
Kelly, R.L., Atomic and ionic spectrum lines of hydrogen through kryton, J. Phys. Chem. Ref. Data, 1987, 16. [all data]

Sugar and Corliss, 1985
Sugar, J.; Corliss, C., Atomic energy levels of the iron period elements: Potassium through nickel, J. Phys. Chem. Ref. Data, 1985, 14. [all data]

Dyke, Gravenor, et al., 1985
Dyke, J.M.; Gravenor, B.W.J.; Hastings, M.P.; Josland, G.D.; Morris, A., Gas phase high temperature photoelectron spectroscopy: An investigation of the transition metals scandium and vanadium, J. Electron Spectrosc. Relat. Phenom., 1985, 35, 65. [all data]

Owzarski and Franzen, 1974
Owzarski, T.P.; Franzen, H.F., High temperature mass spectrometry, vaporization, and thermodynamics of vanadium monosulfide, J. Chem. Phys., 1974, 60, 1113. [all data]

Farber and Srivastava, 1973
Farber, M.; Srivastava, R.D., Effusion-mass spectrometric study of thermodynamic properties of vanadium and vanadium nitride, J. Chem. Soc. Faraday Trans. 1, 1973, 69, 390. [all data]

Moore, 1970
Moore, C.E., Ionization potentials and ionization limits derived from the analyses of optical spectra, Natl. Stand. Ref. Data Ser., (U.S. Natl. Bur. Stand.), 1970, 34, 1. [all data]


Notes

Go To: Top, Gas phase ion energetics data, References