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copper

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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Deltafgas337.4 ± 1.2kJ/molReviewCox, Wagman, et al., 1984CODATA Review value
Deltafgas337.60kJ/molReviewChase, 1998Data last reviewed in June, 1977
Quantity Value Units Method Reference Comment
gas,1 bar166.398 ± 0.004J/mol*KReviewCox, Wagman, et al., 1984CODATA Review value
gas,1 bar166.40J/mol*KReviewChase, 1998Data last reviewed in June, 1977

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 2843.261 - 6000.
A -80.48635
B 49.35865
C -7.578061
D 0.404960
E 133.3382
F 519.9331
G 193.5351
H 337.6003
ReferenceChase, 1998
Comment Data last reviewed in June, 1977

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Deltafliquid11.86kJ/molReviewChase, 1998Data last reviewed in June, 1977
Quantity Value Units Method Reference Comment
liquid,1 bar41.62J/mol*KReviewChase, 1998Data last reviewed in June, 1977
Quantity Value Units Method Reference Comment
solid,1 bar33.15 ± 0.08J/mol*KReviewCox, Wagman, et al., 1984CODATA Review value
Quantity Value Units Method Reference Comment
solid33.17J/mol*KReviewChase, 1998Data last reviewed in June, 1977

Liquid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 1358. - 2843.
A 32.84450
B -0.000084
C 0.000032
D -0.000004
E -0.000028
F -1.804901
G 73.92310
H 11.85730
ReferenceChase, 1998
Comment Data last reviewed in June, 1977

Solid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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View table.

Temperature (K) 298. - 1358.
A 17.72891
B 28.09870
C -31.25289
D 13.97243
E 0.068611
F -6.056591
G 47.89592
H 0.000000
ReferenceChase, 1998
Comment Data last reviewed in June, 1977

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director

Quantity Value Units Method Reference Comment
Tfus1357.95KN/AAnonymous, 1988Uncertainty assigned by TRC = 0.2 K; nominal value, from the catalog

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(CAS Reg. No. 107865-35-0 bullet 4294967295copper) + copper = CAS Reg. No. 107865-35-0

By formula: (CAS Reg. No. 107865-35-0 bullet 4294967295Cu) + Cu = CAS Reg. No. 107865-35-0

Quantity Value Units Method Reference Comment
Deltar158. ± 15.kJ/molN/ASpasov, Lee, et al., 2000gas phase; 0 K dissociation energy
Deltar151. ± 5.9kJ/molTherLeopold, Ho, et al., 1987gas phase; Affinity: shift in apparent EA from lesser-solvated ion. Ignores any neutral-neutral bond.

(CAS Reg. No. 69670-04-8 bullet 4294967295copper) + copper = CAS Reg. No. 69670-04-8

By formula: (CAS Reg. No. 69670-04-8 bullet 4294967295Cu) + Cu = CAS Reg. No. 69670-04-8

Quantity Value Units Method Reference Comment
Deltar233. ± 15.kJ/molN/ASpasov, Lee, et al., 2000gas phase; 0 K dissociation energy
Deltar250. ± 42.kJ/molN/AHo, Ervin, et al., 1990gas phase; Vertical Detachment Energy: 2.37±0.01 eV.

(CAS Reg. No. 108658-51-1 bullet 4294967295copper) + copper = CAS Reg. No. 108658-51-1

By formula: (CAS Reg. No. 108658-51-1 bullet 4294967295Cu) + Cu = CAS Reg. No. 108658-51-1

Quantity Value Units Method Reference Comment
Deltar186. ± 12.kJ/molN/ASpasov, Lee, et al., 2000gas phase; 0 K dissociation energy

(CAS Reg. No. 108658-52-2 bullet 4294967295copper) + copper = CAS Reg. No. 108658-52-2

By formula: (CAS Reg. No. 108658-52-2 bullet 4294967295Cu) + Cu = CAS Reg. No. 108658-52-2

Quantity Value Units Method Reference Comment
Deltar227. ± 12.kJ/molN/ASpasov, Lee, et al., 2000gas phase; 0 K dissociation energy

(CAS Reg. No. 108658-53-3 bullet 4294967295copper) + copper = CAS Reg. No. 108658-53-3

By formula: (CAS Reg. No. 108658-53-3 bullet 4294967295Cu) + Cu = CAS Reg. No. 108658-53-3

Quantity Value Units Method Reference Comment
Deltar246. ± 29.kJ/molN/ASpasov, Lee, et al., 2000gas phase; 0 K dissociation energy

(CAS Reg. No. 108658-54-4 bullet 4294967295copper) + copper = CAS Reg. No. 108658-54-4

By formula: (CAS Reg. No. 108658-54-4 bullet 4294967295Cu) + Cu = CAS Reg. No. 108658-54-4

Quantity Value Units Method Reference Comment
Deltar277. ± 21.kJ/molN/ASpasov, Lee, et al., 2000gas phase; 0 K dissociation energy

(CAS Reg. No. 108658-55-5 bullet 4294967295copper) + copper = CAS Reg. No. 108658-55-5

By formula: (CAS Reg. No. 108658-55-5 bullet 4294967295Cu) + Cu = CAS Reg. No. 108658-55-5

Quantity Value Units Method Reference Comment
Deltar233. ± 29.kJ/molN/ASpasov, Lee, et al., 2000gas phase; 0 K dissociation energy

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cox, Wagman, et al., 1984
Cox, J.D.; Wagman, D.D.; Medvedev, V.A., CODATA Key Values for Thermodynamics, Hemisphere Publishing Corp., New York, 1984, 1. [all data]

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Anonymous, 1988
Anonymous, X., , NBS Spec. Publ. (U. S.) 260, 1988. [all data]

Spasov, Lee, et al., 2000
Spasov, V.A.; Lee, T.H.; Ervin, K.M., Threshold collision-induced dissociation of anionic copper clusters and copper cluster monocarbonyls, J. Chem. Phys., 2000, 112, 4, 1713-1720, https://doi.org/10.1063/1.480736 . [all data]

Leopold, Ho, et al., 1987
Leopold, D.G.; Ho, J.; Lineberger, W.C., Photoelectron Spectroscopy of Mass-selected Metal Cluster Anions. I. Cun-, n=1-10, J. Chem. Phys., 1987, 86, 4, 1715, https://doi.org/10.1063/1.452170 . [all data]

Ho, Ervin, et al., 1990
Ho, J.; Ervin, K.M.; Lineberger, W.C., Photoelectron Spectroscopy of Metal Cluster Anions - Cun-, Agn-, and Aun-, J. Chem. Phys., 1990, 93, 10, 6987, https://doi.org/10.1063/1.459475 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, References