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copper

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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Deltafgas80.64 ± 0.29kcal/molReviewCox, Wagman, et al., 1984CODATA Review value
Deltafgas80.688kcal/molReviewChase, 1998Data last reviewed in June, 1977
Quantity Value Units Method Reference Comment
gas,1 bar39.7701 ± 0.001cal/mol*KReviewCox, Wagman, et al., 1984CODATA Review value
gas,1 bar39.771cal/mol*KReviewChase, 1998Data last reviewed in June, 1977

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 2843.261 - 6000.
A -19.23670
B 11.79700
C -1.811201
D 0.096788
E 31.86860
F 124.2670
G 46.25600
H 80.68841
ReferenceChase, 1998
Comment Data last reviewed in June, 1977

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Deltafliquid2.835kcal/molReviewChase, 1998Data last reviewed in June, 1977
Quantity Value Units Method Reference Comment
liquid,1 bar9.947cal/mol*KReviewChase, 1998Data last reviewed in June, 1977
Quantity Value Units Method Reference Comment
solid,1 bar7.92 ± 0.02cal/mol*KReviewCox, Wagman, et al., 1984CODATA Review value
Quantity Value Units Method Reference Comment
solid7.928cal/mol*KReviewChase, 1998Data last reviewed in June, 1977

Liquid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 1358. - 2843.
A 7.850024
B -0.000020
C 0.000008
D -9.991277×10-7
E -0.000007
F -0.431382
G 17.66805
H 2.833963
ReferenceChase, 1998
Comment Data last reviewed in June, 1977

Solid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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View table.

Temperature (K) 298. - 1358.
A 4.237312
B 6.715751
C -7.469620
D 3.339491
E 0.016398
F -1.447560
G 11.44740
H 0.000000
ReferenceChase, 1998
Comment Data last reviewed in June, 1977

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(CAS Reg. No. 107865-35-0 bullet 4294967295copper) + copper = CAS Reg. No. 107865-35-0

By formula: (CAS Reg. No. 107865-35-0 bullet 4294967295Cu) + Cu = CAS Reg. No. 107865-35-0

Quantity Value Units Method Reference Comment
Deltar37.8 ± 3.5kcal/molN/ASpasov, Lee, et al., 2000gas phase; 0 K dissociation energy
Deltar36.2 ± 1.4kcal/molTherLeopold, Ho, et al., 1987gas phase; Affinity: shift in apparent EA from lesser-solvated ion. Ignores any neutral-neutral bond.

(CAS Reg. No. 69670-04-8 bullet 4294967295copper) + copper = CAS Reg. No. 69670-04-8

By formula: (CAS Reg. No. 69670-04-8 bullet 4294967295Cu) + Cu = CAS Reg. No. 69670-04-8

Quantity Value Units Method Reference Comment
Deltar55.8 ± 3.5kcal/molN/ASpasov, Lee, et al., 2000gas phase; 0 K dissociation energy
Deltar60. ± 10.kcal/molN/AHo, Ervin, et al., 1990gas phase; Vertical Detachment Energy: 2.37±0.01 eV.

(CAS Reg. No. 108658-51-1 bullet 4294967295copper) + copper = CAS Reg. No. 108658-51-1

By formula: (CAS Reg. No. 108658-51-1 bullet 4294967295Cu) + Cu = CAS Reg. No. 108658-51-1

Quantity Value Units Method Reference Comment
Deltar44.5 ± 2.8kcal/molN/ASpasov, Lee, et al., 2000gas phase; 0 K dissociation energy

(CAS Reg. No. 108658-52-2 bullet 4294967295copper) + copper = CAS Reg. No. 108658-52-2

By formula: (CAS Reg. No. 108658-52-2 bullet 4294967295Cu) + Cu = CAS Reg. No. 108658-52-2

Quantity Value Units Method Reference Comment
Deltar54.2 ± 2.8kcal/molN/ASpasov, Lee, et al., 2000gas phase; 0 K dissociation energy

(CAS Reg. No. 108658-53-3 bullet 4294967295copper) + copper = CAS Reg. No. 108658-53-3

By formula: (CAS Reg. No. 108658-53-3 bullet 4294967295Cu) + Cu = CAS Reg. No. 108658-53-3

Quantity Value Units Method Reference Comment
Deltar58.8 ± 6.9kcal/molN/ASpasov, Lee, et al., 2000gas phase; 0 K dissociation energy

(CAS Reg. No. 108658-54-4 bullet 4294967295copper) + copper = CAS Reg. No. 108658-54-4

By formula: (CAS Reg. No. 108658-54-4 bullet 4294967295Cu) + Cu = CAS Reg. No. 108658-54-4

Quantity Value Units Method Reference Comment
Deltar66.2 ± 5.1kcal/molN/ASpasov, Lee, et al., 2000gas phase; 0 K dissociation energy

(CAS Reg. No. 108658-55-5 bullet 4294967295copper) + copper = CAS Reg. No. 108658-55-5

By formula: (CAS Reg. No. 108658-55-5 bullet 4294967295Cu) + Cu = CAS Reg. No. 108658-55-5

Quantity Value Units Method Reference Comment
Deltar55.6 ± 6.9kcal/molN/ASpasov, Lee, et al., 2000gas phase; 0 K dissociation energy

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cox, Wagman, et al., 1984
Cox, J.D.; Wagman, D.D.; Medvedev, V.A., CODATA Key Values for Thermodynamics, Hemisphere Publishing Corp., New York, 1984, 1. [all data]

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Spasov, Lee, et al., 2000
Spasov, V.A.; Lee, T.H.; Ervin, K.M., Threshold collision-induced dissociation of anionic copper clusters and copper cluster monocarbonyls, J. Chem. Phys., 2000, 112, 4, 1713-1720, https://doi.org/10.1063/1.480736 . [all data]

Leopold, Ho, et al., 1987
Leopold, D.G.; Ho, J.; Lineberger, W.C., Photoelectron Spectroscopy of Mass-selected Metal Cluster Anions. I. Cun-, n=1-10, J. Chem. Phys., 1987, 86, 4, 1715, https://doi.org/10.1063/1.452170 . [all data]

Ho, Ervin, et al., 1990
Ho, J.; Ervin, K.M.; Lineberger, W.C., Photoelectron Spectroscopy of Metal Cluster Anions - Cun-, Agn-, and Aun-, J. Chem. Phys., 1990, 93, 10, 6987, https://doi.org/10.1063/1.459475 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, References