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tin

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Deltafgas301.2 ± 1.5kJ/molReviewCox, Wagman, et al., 1984CODATA Review value
Quantity Value Units Method Reference Comment
gas,1 bar168.492 ± 0.004J/mol*KReviewCox, Wagman, et al., 1984CODATA Review value

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
solid,1 bar51.18 ± 0.08J/mol*KReviewCox, Wagman, et al., 1984 white phase; CODATA Review value

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director

Quantity Value Units Method Reference Comment
Tfus505.15KN/AAnonymous, 1988Uncertainty assigned by TRC = 1. K; nominal value, from the catalog; TRC
Tfus505.11KN/AAnonymous, 1988Uncertainty assigned by TRC = 0.0005 K; nominal value, from the catalog; TRC
Tfus504.87KN/ACallanan, Sullivan, et al., 1985Uncertainty assigned by TRC = 0.3 K; TRC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
1765. - 2543.6.5959416866.81115.465Stull, 1947Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(CAS Reg. No. 64177-64-6 bullet 4294967295tin) + tin = CAS Reg. No. 64177-64-6

By formula: (CAS Reg. No. 64177-64-6 bullet 4294967295Sn) + Sn = CAS Reg. No. 64177-64-6

Quantity Value Units Method Reference Comment
Deltar263.6 ± 1.8kJ/molN/AHo, Polak, et al., 1992gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to Sn+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)7.34381eVN/AN/AL

Electron affinity determinations

EA (eV) Method Reference Comment
1.1121LPDVandevraye, Drag, et al., 2013Given: 1.112070±0.000002 eV; B
1.112074 ± 0.000044LPDScheer, Bilodeau, et al., 1998Given: 1.112067(15) eV; B
1.113 ± 0.020LPESMiller, Miller, et al., 1986B
1.15 ± 0.15PDFeldmann, Rackwitz, et al., 1977B

Ionization energy determinations

IE (eV) Method Reference Comment
7.3 ± 0.2EIMakarov and Zbezhneva, 1993LL
7.34381EVALLide, 1992LL
7.4 ± 0.3EILau, Brittain, et al., 1981LLK
7.34392 ± 0.00002SBrown, Tilford, et al., 1977LLK
7.871SBrown, Tilford, et al., 1977LLK
7.28 ± 0.07EICabaud, Hoareau, et al., 1972LLK
7.34381SMoore, 1970RDSH

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cox, Wagman, et al., 1984
Cox, J.D.; Wagman, D.D.; Medvedev, V.A., CODATA Key Values for Thermodynamics, Hemisphere Publishing Corp., New York, 1984, 1. [all data]

Anonymous, 1988
Anonymous, X., , NBS Spec. Publ. (U. S.) 260, 1988. [all data]

Callanan, Sullivan, et al., 1985
Callanan, J.E.; Sullivan, S.A.; Vecchia, D.F., Feasibility Study for the Development of Standards Using Differential Scanning Calorimetry, Natl. Bur. Stand. Spec. Publ. 260-99 1985, 1985. [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Ho, Polak, et al., 1992
Ho, J.; Polak, M.L.; Lineberger, W.C., Photoelectron Spectroscopy of Group-IV Heavy Metal Dimers - Sn2-, Pb2-, and SnPb-, J. Chem. Phys., 1992, 96, 1, 144, https://doi.org/10.1063/1.462503 . [all data]

Vandevraye, Drag, et al., 2013
Vandevraye, M.; Drag, C.; Blondel, C., Electron affinity of tin measured by photodetachment microscopy, J. Phys. B: Atom. Mol. Opt. Phys., 2013, 46, 12, 125002, https://doi.org/10.1088/0953-4075/46/12/125002 . [all data]

Scheer, Bilodeau, et al., 1998
Scheer, M.; Bilodeau, R.C.; Brodie, C.A.; Haugen, H.K., Systematic study of the stable states of C-, Si-, Ge-, and Sn- via infrared laser spectroscopy, Phys. Rev. A, 1998, 58, 4, 2844-2856, https://doi.org/10.1103/PhysRevA.58.2844 . [all data]

Miller, Miller, et al., 1986
Miller, T.M.; Miller, A.E.S.; Lineberger, W.C., Electron Affinities of Ge and Sn, Phys. Rev. A, 1986, 33, 5, 3558, https://doi.org/10.1103/PhysRevA.33.3558 . [all data]

Feldmann, Rackwitz, et al., 1977
Feldmann, D.; Rackwitz, R.; Heincke, H.; Kaiser, H.J., Photoabsolung von Elektronen der Ionen B-, Ga-, In-, Tl-, Ge-, und Pb-, Z. Naturforschung A, 1977, 32, 302. [all data]

Makarov and Zbezhneva, 1993
Makarov, A.V.; Zbezhneva, S.G., Use of high-temperature mass spectrometry for analysis of the vapour phase of some substances used in film deposition, Vysokochist. Veshchestva, 1993, 1, 124. [all data]

Lide, 1992
Lide, D.R. (Editor), Ionization potentials of atoms and atomic ions in Handbook of Chem. and Phys., 1992, 10-211. [all data]

Lau, Brittain, et al., 1981
Lau, K.H.; Brittain, R.D.; Hildenbrand, D.L., The dissociation energy of AsO from gaseous equilibrium measurements, Chem. Phys. Lett., 1981, 81, 227. [all data]

Brown, Tilford, et al., 1977
Brown, C.M.; Tilford, S.G.; Ginter, M.L., Absorption spectrum of Sn I between 1580 and 2040 Å, J. Opt. Soc. Am., 1977, 67, 607. [all data]

Cabaud, Hoareau, et al., 1972
Cabaud, B.; Hoareau, A.; Nounou, P.; Uzan, R., Etude des processus d'ionisation a haute temperature des vapeurs metalliques par couplage d'une cellule de knudsen et d'une source fox. II. Interpretation des processus d'autoionisation des vapeurs metalliques monoatomiques et influence delatemperature sur les courbes d'efficacite d'ionisation., Int. J. Mass Spectrom. Ion Phys., 1972, 8, 181. [all data]

Moore, 1970
Moore, C.E., Ionization potentials and ionization limits derived from the analyses of optical spectra, Natl. Stand. Ref. Data Ser., (U.S. Natl. Bur. Stand.), 1970, 34, 1. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, References