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sodium

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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Deltafgas107.5 ± 0.7kJ/molReviewCox, Wagman, et al., 1984CODATA Review value
Deltafgas107.30kJ/molReviewChase, 1998Data last reviewed in June, 1962
Quantity Value Units Method Reference Comment
gas,1 bar153.718 ± 0.003J/mol*KReviewCox, Wagman, et al., 1984CODATA Review value
gas,1 bar153.65J/mol*KReviewChase, 1998Data last reviewed in June, 1962

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 1170.525 - 6000.
A 20.80573
B 0.277206
C -0.392086
D 0.119634
E -0.008879
F 101.0386
G 178.7095
H 107.2999
ReferenceChase, 1998
Comment Data last reviewed in June, 1962

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Deltafliquid2.41kJ/molReviewChase, 1998Data last reviewed in June, 1962
Quantity Value Units Method Reference Comment
liquid,1 bar57.86J/mol*KReviewChase, 1998Data last reviewed in June, 1962
Quantity Value Units Method Reference Comment
solid,1 bar51.30 ± 0.20J/mol*KReviewCox, Wagman, et al., 1984CODATA Review value
Quantity Value Units Method Reference Comment
solid51.46J/mol*KReviewChase, 1998Data last reviewed in June, 1962

Liquid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 370.98 - 1170.525
A 40.25707
B -28.23849
C 20.69402
D -3.641872
E -0.079874
F -8.782300
G 113.6646
H 2.406001
ReferenceChase, 1998
Comment Data last reviewed in June, 1962

Solid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. - 370.
A 72.63675
B -9.491572
C -730.9322
D 1414.518
E -1.259377
F -21.79467
G 155.0963
H 0.000000
ReferenceChase, 1998
Comment Data last reviewed in June, 1962

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

0.5Chromium, hexacarbonylbis(η5-2,4-cyclopentadien-1-yl)di-, (Cr-Cr) (solution) + sodium (cr) = C8H5CrNaO3 (solution)

By formula: 0.5C16H10Cr2O6 (solution) + Na (cr) = C8H5CrNaO3 (solution)

Quantity Value Units Method Reference Comment
Deltar-285.1 ± 3.6kJ/molRSCKiss, Nolan, et al., 1994solvent: Tetrahydrofuran; The reaction enthalpy was calculated from the enthalpies of the following reactions: 0.5[Cr(Cp)(CO)3]2(solution) + (Na)[Cr(Cp)(CO)2(PPh3)](solution) = (Na)[Cr(Cp)(CO)3](solution) + Cr(Cp)(CO)2(PPh3)(solution), -34.9 ± 0.4 kJ/mol, Cr(Cp)(CO)2(PPh3)(solution) + (Na)(Ph2CO)(solution) = (Na)[Cr(Cp)(CO)2(PPh3)](solution) + Ph2CO(solution), -89.1 ± 2.5 kJ/mol, and Ph2CO(solution) + Na(cr) = (Na)(Ph2CO)(solution), -161.1 ± 2.5 kJ/mol Kiss, Nolan, et al., 1994.; MS

0.5C16H10Mo2O6 (solution) + sodium (cr) = C8H5MoNaO3 (solution)

By formula: 0.5C16H10Mo2O6 (solution) + Na (cr) = C8H5MoNaO3 (solution)

Quantity Value Units Method Reference Comment
Deltar-265.5 ± 3.6kJ/molRSCKiss, Nolan, et al., 1994solvent: Tetrahydrofuran; The reaction enthalpy was calculated from the enthalpies of the following reactions: 0.5[Mo(Cp)(CO)3]2(solution) + (Na)[Cr(Cp)(CO)2(PPh3)](solution) = (Na)[Mo(Cp)(CO)3](solution) + Cr(Cp)(CO)2(PPh3)(solution), -15.3 ± 0.4 kJ/mol, Cr(Cp)(CO)2(PPh3)(solution) + (Na)(Ph2CO)(solution) = (Na)[Cr(Cp)(CO)2(PPh3)](solution) + Ph2CO(solution), -89.1 ± 2.5 kJ/mol, and Ph2CO(solution) + Na(cr) = (Na)(Ph2CO)(solution), -161.1 ± 2.5 kJ/mol Kiss, Nolan, et al., 1994.; MS

0.5C26H30Mo2O6 (solution) + sodium (cr) = C13H15MoNaO3 (solution)

By formula: 0.5C26H30Mo2O6 (solution) + Na (cr) = C13H15MoNaO3 (solution)

Quantity Value Units Method Reference Comment
Deltar-250.6 ± 6.0kJ/molRSCKiss, Nolan, et al., 1994solvent: Tetrahydrofuran; The reaction enthalpy was calculated from the enthalpies of the following reactions: 0.5[Mo(Cp*)(CO)3]2(solution) + (Na)[Cr(Cp)(CO)2(PPh3)](solution) = (Na)[Mo(Cp*)(CO)3](solution) + Cr(Cp)(CO)2(PPh3)(solution), Cr(Cp)(CO)2(PPh3)(solution) + (Na)(Ph2CO)(solution) = (Na)[Cr(Cp)(CO)2(PPh3)](solution) + Ph2CO(solution), -89.1 ± 2.5 kJ/mol, and Ph2CO(solution) + Na(cr) = (Na)(Ph2CO)(solution), -161.1 ± 2.5 kJ/mol Kiss, Nolan, et al., 1994.; MS

0.5C16H10O6W2 (solution) + sodium (cr) = C8H5NaO3W (solution)

By formula: 0.5C16H10O6W2 (solution) + Na (cr) = C8H5NaO3W (solution)

Quantity Value Units Method Reference Comment
Deltar-258.2 ± 6.0kJ/molRSCKiss, Nolan, et al., 1994solvent: Tetrahydrofuran; The reaction enthalpy was calculated from the enthalpies of the following reactions: 0.5[W(Cp)(CO)3]2(solution) + (Na)[Cr(Cp)(CO)2(PPh3)](solution) = (Na)[W(Cp)(CO)3](solution) + Cr(Cp)(CO)2(PPh3)(solution), Cr(Cp)(CO)2(PPh3)(solution) + (Na)(Ph2CO)(solution) = (Na)[Cr(Cp)(CO)2(PPh3)](solution) + Ph2CO(solution), -89.1 ± 2.5 kJ/mol, and Ph2CO(solution) + Na(cr) = (Na)(Ph2CO)(solution), -161.1 ± 2.5 kJ/mol Kiss, Nolan, et al., 1994.; MS

0.5Dicobalt octacarbonyl (solution) + sodium (cr) = C4CoNaO4 (solution)

By formula: 0.5C8Co2O8 (solution) + Na (cr) = C4CoNaO4 (solution)

Quantity Value Units Method Reference Comment
Deltar-318. ± 11.kJ/molRSCKiss, Nolan, et al., 1994solvent: Tetrahydrofuran; The reaction enthalpy was calculated from the enthalpies of the following reactions: 0.5Co2(CO)8(solution) + (Na)(Ph2CO)(solution) = (Na)[Co(CO)4](solution) + Ph2CO(solution), -157. ± 11. kJ/mol, and Ph2CO(solution) + Na(cr) = (Na)(Ph2CO)(solution), -161.1 ± 2.5 kJ/mol Kiss, Nolan, et al., 1994.; MS

4sodium + Ethene, chlorotrifluoro- = 2carbon + sodium chloride + 3sodium fluoride

By formula: 4Na + C2ClF3 = 2C + ClNa + 3FNa

Quantity Value Units Method Reference Comment
Deltar-1576.1 ± 5.4kJ/molCmKolesov, Zenkov, et al., 1963gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -1543. ± 5.4 kJ/mol; ALS

(CAS Reg. No. 58799-98-7 bullet 4294967295sodium) + sodium = CAS Reg. No. 58799-98-7

By formula: (CAS Reg. No. 58799-98-7 bullet 4294967295Na) + Na = CAS Reg. No. 58799-98-7

Quantity Value Units Method Reference Comment
Deltar58.7 ± 3.0kJ/molN/AMcHugh, Eaton, et al., 1989gas phase; Vertical Detachment Energy: 0.543±0.010 eV; B

Cyclobutane, octafluoro- + 4sodium = 4carbon + 8sodium fluoride

By formula: C4F8 + 4Na = 4C + 8FNa

Quantity Value Units Method Reference Comment
Deltar-2989. ± 9.2kJ/molCcbKolesov, Talakin, et al., 1968gas phase; Correction of Kolesov, Talakin, et al., 1964; ALS

(Sodium ion (1+) bullet 8sodium) + sodium = (Sodium ion (1+) bullet 9sodium)

By formula: (Na+ bullet 8Na) + Na = (Na+ bullet 9Na)

Quantity Value Units Method Reference Comment
Deltar75.3kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; «DELTA»rH<; M

(CAS Reg. No. 67291-87-6 bullet 4294967295sodium) + sodium = CAS Reg. No. 67291-87-6

By formula: (CAS Reg. No. 67291-87-6 bullet 4294967295Na) + Na = CAS Reg. No. 67291-87-6

Quantity Value Units Method Reference Comment
Deltar126.8 ± 2.5kJ/molN/AMiller, Leopold, et al., 1986gas phase; B

(CAS Reg. No. 71892-04-1 bullet 4294967295sodium) + sodium = CAS Reg. No. 71892-04-1

By formula: (CAS Reg. No. 71892-04-1 bullet 4294967295Na) + Na = CAS Reg. No. 71892-04-1

Quantity Value Units Method Reference Comment
Deltar199.9 ± 1.3kJ/molN/AMiller, Leopold, et al., 1986gas phase; B

Benzophenone (solution) + sodium (cr) = C13H10NaO (solution)

By formula: C13H10O (solution) + Na (cr) = C13H10NaO (solution)

Quantity Value Units Method Reference Comment
Deltar-161.1 ± 2.5kJ/molRSCKiss, Nolan, et al., 1994solvent: Tetrahydrofuran; MS

(Iodide bullet 4294967295sodium) + sodium = Iodide

By formula: (I- bullet 4294967295Na) + Na = I-

Quantity Value Units Method Reference Comment
Deltar82.0 ± 9.6kJ/molN/AMiller, Leopold, et al., 1986gas phase; B

(CAS Reg. No. 70377-22-9 bullet 4294967295sodium) + sodium = CAS Reg. No. 70377-22-9

By formula: (CAS Reg. No. 70377-22-9 bullet 4294967295Na) + Na = CAS Reg. No. 70377-22-9

Quantity Value Units Method Reference Comment
Deltar114. ± 8.4kJ/molN/AMiller, Leopold, et al., 1986gas phase; B

(Sodium ion (1+) bullet 10sodium) + sodium = (Sodium ion (1+) bullet 11sodium)

By formula: (Na+ bullet 10Na) + Na = (Na+ bullet 11Na)

Quantity Value Units Method Reference Comment
Deltar65.7kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) bullet 11sodium) + sodium = (Sodium ion (1+) bullet 12sodium)

By formula: (Na+ bullet 11Na) + Na = (Na+ bullet 12Na)

Quantity Value Units Method Reference Comment
Deltar87.0kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) bullet 12sodium) + sodium = (Sodium ion (1+) bullet 13sodium)

By formula: (Na+ bullet 12Na) + Na = (Na+ bullet 13Na)

Quantity Value Units Method Reference Comment
Deltar69.5kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) bullet 13sodium) + sodium = (Sodium ion (1+) bullet 14sodium)

By formula: (Na+ bullet 13Na) + Na = (Na+ bullet 14Na)

Quantity Value Units Method Reference Comment
Deltar76.1kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) bullet 14sodium) + sodium = (Sodium ion (1+) bullet 15sodium)

By formula: (Na+ bullet 14Na) + Na = (Na+ bullet 15Na)

Quantity Value Units Method Reference Comment
Deltar66.5kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) bullet 15sodium) + sodium = (Sodium ion (1+) bullet 16sodium)

By formula: (Na+ bullet 15Na) + Na = (Na+ bullet 16Na)

Quantity Value Units Method Reference Comment
Deltar79.1kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) bullet 16sodium) + sodium = (Sodium ion (1+) bullet 17sodium)

By formula: (Na+ bullet 16Na) + Na = (Na+ bullet 17Na)

Quantity Value Units Method Reference Comment
Deltar82.8kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) bullet 17sodium) + sodium = (Sodium ion (1+) bullet 18sodium)

By formula: (Na+ bullet 17Na) + Na = (Na+ bullet 18Na)

Quantity Value Units Method Reference Comment
Deltar87.0kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) bullet 18sodium) + sodium = (Sodium ion (1+) bullet 19sodium)

By formula: (Na+ bullet 18Na) + Na = (Na+ bullet 19Na)

Quantity Value Units Method Reference Comment
Deltar82.0kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) bullet 19sodium) + sodium = (Sodium ion (1+) bullet 20sodium)

By formula: (Na+ bullet 19Na) + Na = (Na+ bullet 20Na)

Quantity Value Units Method Reference Comment
Deltar89.5kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) bullet 22sodium) + sodium = (Sodium ion (1+) bullet 23sodium)

By formula: (Na+ bullet 22Na) + Na = (Na+ bullet 23Na)

Quantity Value Units Method Reference Comment
Deltar71.5kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) bullet 23sodium) + sodium = (Sodium ion (1+) bullet 24sodium)

By formula: (Na+ bullet 23Na) + Na = (Na+ bullet 24Na)

Quantity Value Units Method Reference Comment
Deltar79.1kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) bullet 24sodium) + sodium = (Sodium ion (1+) bullet 25sodium)

By formula: (Na+ bullet 24Na) + Na = (Na+ bullet 25Na)

Quantity Value Units Method Reference Comment
Deltar76.1kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) bullet 25sodium) + sodium = (Sodium ion (1+) bullet 26sodium)

By formula: (Na+ bullet 25Na) + Na = (Na+ bullet 26Na)

Quantity Value Units Method Reference Comment
Deltar81.2kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) bullet 26sodium) + sodium = (Sodium ion (1+) bullet 27sodium)

By formula: (Na+ bullet 26Na) + Na = (Na+ bullet 27Na)

Quantity Value Units Method Reference Comment
Deltar76.1kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) bullet 27sodium) + sodium = (Sodium ion (1+) bullet 28sodium)

By formula: (Na+ bullet 27Na) + Na = (Na+ bullet 28Na)

Quantity Value Units Method Reference Comment
Deltar84.1kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) bullet 28sodium) + sodium = (Sodium ion (1+) bullet 29sodium)

By formula: (Na+ bullet 28Na) + Na = (Na+ bullet 29Na)

Quantity Value Units Method Reference Comment
Deltar82.8kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) bullet 29sodium) + sodium = (Sodium ion (1+) bullet 30sodium)

By formula: (Na+ bullet 29Na) + Na = (Na+ bullet 30Na)

Quantity Value Units Method Reference Comment
Deltar85.8kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) bullet 30sodium) + sodium = (Sodium ion (1+) bullet 31sodium)

By formula: (Na+ bullet 30Na) + Na = (Na+ bullet 31Na)

Quantity Value Units Method Reference Comment
Deltar81.2kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) bullet 31sodium) + sodium = (Sodium ion (1+) bullet 32sodium)

By formula: (Na+ bullet 31Na) + Na = (Na+ bullet 32Na)

Quantity Value Units Method Reference Comment
Deltar87.9kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) bullet 32sodium) + sodium = (Sodium ion (1+) bullet 33sodium)

By formula: (Na+ bullet 32Na) + Na = (Na+ bullet 33Na)

Quantity Value Units Method Reference Comment
Deltar88.7kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) bullet 33sodium) + sodium = (Sodium ion (1+) bullet 34sodium)

By formula: (Na+ bullet 33Na) + Na = (Na+ bullet 34Na)

Quantity Value Units Method Reference Comment
Deltar91.6kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) bullet 34sodium) + sodium = (Sodium ion (1+) bullet 35sodium)

By formula: (Na+ bullet 34Na) + Na = (Na+ bullet 35Na)

Quantity Value Units Method Reference Comment
Deltar82.0kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) bullet 35sodium) + sodium = (Sodium ion (1+) bullet 36sodium)

By formula: (Na+ bullet 35Na) + Na = (Na+ bullet 36Na)

Quantity Value Units Method Reference Comment
Deltar87.0kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) bullet 9sodium) + sodium = (Sodium ion (1+) bullet 10sodium)

By formula: (Na+ bullet 9Na) + Na = (Na+ bullet 10Na)

Quantity Value Units Method Reference Comment
Deltar75.3kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) bullet 2sodium) + sodium = (Sodium ion (1+) bullet 3sodium)

By formula: (Na+ bullet 2Na) + Na = (Na+ bullet 3Na)

Quantity Value Units Method Reference Comment
Deltar56.1kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) bullet 3sodium) + sodium = (Sodium ion (1+) bullet 4sodium)

By formula: (Na+ bullet 3Na) + Na = (Na+ bullet 4Na)

Quantity Value Units Method Reference Comment
Deltar84.1kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) bullet 4sodium) + sodium = (Sodium ion (1+) bullet 5sodium)

By formula: (Na+ bullet 4Na) + Na = (Na+ bullet 5Na)

Quantity Value Units Method Reference Comment
Deltar57.7kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) bullet 5sodium) + sodium = (Sodium ion (1+) bullet 6sodium)

By formula: (Na+ bullet 5Na) + Na = (Na+ bullet 6Na)

Quantity Value Units Method Reference Comment
Deltar110.kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) bullet 6sodium) + sodium = (Sodium ion (1+) bullet 7sodium)

By formula: (Na+ bullet 6Na) + Na = (Na+ bullet 7Na)

Quantity Value Units Method Reference Comment
Deltar73.2kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) bullet 7sodium) + sodium = (Sodium ion (1+) bullet 8sodium)

By formula: (Na+ bullet 7Na) + Na = (Na+ bullet 8Na)

Quantity Value Units Method Reference Comment
Deltar126.kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) bullet sodium) + sodium = (Sodium ion (1+) bullet 2sodium)

By formula: (Na+ bullet Na) + Na = (Na+ bullet 2Na)

Quantity Value Units Method Reference Comment
Deltar133.kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

4sodium + Tetrafluoromethane = carbon + 4sodium fluoride

By formula: 4Na + CF4 = C + 4FNa

Quantity Value Units Method Reference Comment
Deltar-1362. ± 9.2kJ/molCcbVorob'ev and Skuratov, 1960gas phase; ALS

Ethene, tetrafluoro- + 4sodium = 4sodium fluoride + 2Carbon

By formula: C2F4 + 4Na = 4FNa + 2C

Quantity Value Units Method Reference Comment
Deltar-1611. ± 4.6kJ/molCmKolesov, Zenkov, et al., 1962gas phase; ALS

8sodium + Perfluoropropane = 3carbon + 8sodium fluoride

By formula: 8Na + C3F8 = 3C + 8FNa

Quantity Value Units Method Reference Comment
Deltar-2761. ± 7.1kJ/molCcbKolesov, Talakin, et al., 1967gas phase; ALS

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cox, Wagman, et al., 1984
Cox, J.D.; Wagman, D.D.; Medvedev, V.A., CODATA Key Values for Thermodynamics, Hemisphere Publishing Corp., New York, 1984, 1. [all data]

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Kiss, Nolan, et al., 1994
Kiss, G.; Nolan, S.P.; Hoff, C.D., Inorg. Chim. Acta, 1994, 227, 285. [all data]

Kolesov, Zenkov, et al., 1963
Kolesov, V.P.; Zenkov, I.D.; Skuratov, S.M., Standard enthalpy of formation of chlorotrifluoroethylene, Russ. J. Phys. Chem. (Engl. Transl.), 1963, 37, 115-116. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

McHugh, Eaton, et al., 1989
McHugh, K.M.; Eaton, J.G.; Lee, G.H.; Sarkas, H.W.; Kidder, L.H.; Snodgrass, J.T.; Manaa, M.R.; Bowen, K.H., Photoelectron Spectra of the alkali metal cluster Anions: Na-,n=2-5, K-,n=2-7, Rb-,n=2-3, and Cs-,n=2-3, J. Chem. Phys., 1989, 91, 6, 3792, https://doi.org/10.1063/1.456861 . [all data]

Kolesov, Talakin, et al., 1968
Kolesov, V.P.; Talakin, O.G.; Skuratov, S.M., Enthalpy of formation of some specimens of amorphous carbon, Russ. J. Phys. Chem. (Engl. Transl.), 1968, 42, 1218-1220. [all data]

Kolesov, Talakin, et al., 1964
Kolesov, V.P.; Talakin, O.G.; Skuratov, S.M., Standard enthalpy of formation of perfluorocyclobutane, Russ. J. Phys. Chem. (Engl. Transl.), 1964, 38, 930-931. [all data]

Brechignac, Cahuzac, et al., 1989
Brechignac, C.; Cahuzac, P.; Leygnier, J.; Weiner, J., Dynamics of Unimolecular Dissociation of Sodium Cluster Ions, J. Chem. Phys., 1989, 90, 3, 1492, https://doi.org/10.1063/1.456675 . [all data]

Miller, Leopold, et al., 1986
Miller, T.M.; Leopold, D.G.; Murray, K.K.; Lineberger, W.C., Electron Affinities of the Alkali Halides and the Structure of their Negative Ions, J. Chem. Phys., 1986, 85, 5, 2368, https://doi.org/10.1063/1.451091 . [all data]

Vorob'ev and Skuratov, 1960
Vorob'ev, A.F.; Skuratov, S.M., Standard enthalpies of formation of CF4, Zh. Neorg. Khim., 1960, 5, 1398-1401. [all data]

Kolesov, Zenkov, et al., 1962
Kolesov, V.P.; Zenkov, I.D.; Skuratov, S.M., The standard enthalpy of formation of tetrafluoroethylene, Russ. J. Phys. Chem. (Engl. Transl.), 1962, 36, 45-47. [all data]

Kolesov, Talakin, et al., 1967
Kolesov, V.P.; Talakin, O.G.; Skuratov, S.M., Standard enthalpy of formation of perfluoropropane and enthalpies of formation of normal perfluoroalkanes, Vestn. Mosk. Univ. Khim., 1967, 22, 38-42. [all data]


Notes

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