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Gas Phase Heat Capacity (Shomate Equation)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 3504.616 - 6000.
A 14.59321
B 5.224644
C -1.078879
D 0.074000
E 2.309405
F 450.3365
G 190.2494
H 450.0018
ReferenceChase, 1998
Comment Data last reviewed in March, 1967
Temperature
(K)
Cp
(J/mol*K)

(J/mol*K)
-(G° - H°298.15)/T
(J/mol*K)
H° - H°298.15
(kJ/mol)
3505.23.03221.2201.270.22
3600.23.05221.8201.772.41
3700.23.07222.5202.374.72
3800.23.09223.1202.877.03
3900.23.10223.7203.379.34
4000.23.11224.3203.881.65
4100.23.12224.8204.383.96
4200.23.12225.4204.886.27
4300.23.12225.9205.388.58
4400.23.12226.5205.890.89
4500.23.11227.0206.393.21
4600.23.11227.5206.795.52
4700.23.10228.0207.297.83
4800.23.10228.5207.6100.1
4900.23.09228.9208.0102.4
5000.23.09229.4208.5104.8
5100.23.08229.9208.9107.1
5200.23.08230.3209.3109.4
5300.23.08230.8209.7111.7
5400.23.08231.2210.1114.0
5500.23.08231.6210.5116.3
5600.23.09232.0210.8118.6
5700.23.10232.4211.2120.9
5800.23.11232.8211.6123.2
5900.23.13233.2212.0125.5
6000.23.15233.6212.3127.8

References

Go To: Top, Gas Phase Heat Capacity (Shomate Equation), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]


Notes

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