rhenium


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

Dirhenium decacarbonyl (cr) = 10Carbon monoxide (g) + 2rhenium (cr)

By formula: C10O10Re2 (cr) = 10CO (g) + 2Re (cr)

Quantity Value Units Method Reference Comment
Δr539.7 ± 5.9kJ/molTD-HFCConnor, Skinner, et al., 1973 
Δr552.3 ± 3.0kJ/molHAL-HFCConnor, Skinner, et al., 1973 

C6H3O5Re (cr) = 5Carbon monoxide (g) + rhenium (cr) + Methane (g)

By formula: C6H3O5Re (cr) = 5CO (g) + Re (cr) + CH4 (g)

Quantity Value Units Method Reference Comment
Δr421.3 ± 8.4kJ/molHAL-HFCBrown, Connor, et al., 1974Please also see Pedley and Rylance, 1977.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Connor, Skinner, et al., 1973
Connor, J.A.; Skinner, H.A.; Virmani, Y., High temperature microcalorimetric studies of the thermal decomposition and iodination of polynuclear carbonyls of Fe, Co, Ru, Rh, Re, Os and Ir, Faraday Symp. Chem. Soc., 1973, 8, 18, https://doi.org/10.1039/fs9730800018 . [all data]

Brown, Connor, et al., 1974
Brown, D.L.S.; Connor, J.A.; Skinner, H.A., J. Organometal. Chem., 1974, 81, 403. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]


Notes

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