potassium

• Formula: K
• Molecular weight: 39.0983
• IUPAC Standard InChI: InChI=1S/K Copy

  
• IUPAC Standard InChIKey: ZLMJMSJWJFRBEC-UHFFFAOYSA-N Copy
• CAS Registry Number: 7440-09-7
• Chemical structure:
  This structure is also available as a 2d Mol file
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• Information on this page:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Reaction thermochemistry data
  • References
  • Notes
• Other data available:
  • Phase change data
  • Gas phase ion energetics data
  • Ion clustering data
• Data at other public NIST sites:
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  • Computational Chemistry Comparison and Benchmark Database
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  • X-ray Photoelectron Spectroscopy Database, version 5.0
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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gas Phase Heat Capacity (Shomate Equation)

C_p° = A + B*t + C*t² + D*t³ + E/t²
H° − H°_298.15= A*t + B*t²/2 + C*t³/3 + D*t⁴/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t²/2 + D*t³/3 − E/(2*t²) + G
    C_p = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Liquid Phase Heat Capacity (Shomate Equation)

C_p° = A + B*t + C*t² + D*t³ + E/t²
H° − H°_298.15= A*t + B*t²/2 + C*t³/3 + D*t⁴/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t²/2 + D*t³/3 − E/(2*t²) + G
    C_p = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Solid Phase Heat Capacity (Shomate Equation)

C_p° = A + B*t + C*t² + D*t³ + E/t²
H° − H°_298.15= A*t + B*t²/2 + C*t³/3 + D*t⁴/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t²/2 + D*t³/3 − E/(2*t²) + G
    C_p = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

( • 10) +  = ( • 11)

By formula: (K⁺ • 10K) + K = (K⁺ • 11K)

( • 11) +  = ( • 12)

By formula: (K⁺ • 11K) + K = (K⁺ • 12K)

( • 12) +  = ( • 13)

By formula: (K⁺ • 12K) + K = (K⁺ • 13K)

( • 13) +  = ( • 14)

By formula: (K⁺ • 13K) + K = (K⁺ • 14K)

( • 14) +  = ( • 15)

By formula: (K⁺ • 14K) + K = (K⁺ • 15K)

( • 15) +  = ( • 16)

By formula: (K⁺ • 15K) + K = (K⁺ • 16K)

( • 16) +  = ( • 17)

By formula: (K⁺ • 16K) + K = (K⁺ • 17K)

( • 17) +  = ( • 18)

By formula: (K⁺ • 17K) + K = (K⁺ • 18K)

( • 18) +  = ( • 19)

By formula: (K⁺ • 18K) + K = (K⁺ • 19K)

( • 19) +  = ( • 20)

By formula: (K⁺ • 19K) + K = (K⁺ • 20K)

( • 20) +  = ( • 21)

By formula: (K⁺ • 20K) + K = (K⁺ • 21K)

( • 21) +  = ( • 22)

By formula: (K⁺ • 21K) + K = (K⁺ • 22K)

( • 22) +  = ( • 23)

By formula: (K⁺ • 22K) + K = (K⁺ • 23K)

( • 23) +  = ( • 24)

By formula: (K⁺ • 23K) + K = (K⁺ • 24K)

( • 9) +  = ( • 10)

By formula: (K⁺ • 9K) + K = (K⁺ • 10K)

( • 2) +  = ( • 3)

By formula: (K⁺ • 2K) + K = (K⁺ • 3K)

( • 3) +  = ( • 4)

By formula: (K⁺ • 3K) + K = (K⁺ • 4K)

( • 4) +  = ( • 5)

By formula: (K⁺ • 4K) + K = (K⁺ • 5K)

( • 5) +  = ( • 6)

By formula: (K⁺ • 5K) + K = (K⁺ • 6K)

( • 6) +  = ( • 7)

By formula: (K⁺ • 6K) + K = (K⁺ • 7K)

( • 7) +  = ( • 8)

By formula: (K⁺ • 7K) + K = (K⁺ • 8K)

( • 8) +  = ( • 9)

By formula: (K⁺ • 8K) + K = (K⁺ • 9K)

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cox, Wagman, et al., 1984
Cox, J.D.; Wagman, D.D.; Medvedev, V.A., CODATA Key Values for Thermodynamics, Hemisphere Publishing Corp., New York, 1984, 1. [all data]

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Brechignac, Cahuzac, et al., 1990
Brechignac, C.; Cahuzac, P.; Carlier, F.; De Frutos, M.; Leyniger, J., Cohesive Energies of (K)n+ 5<n<200 from Photoevaporation Experiments, J. Chem. Phys., 1990, 93, 10, 7449, https://doi.org/10.1063/1.459418 . [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, References

• Symbols used in this document:
  

  S°gas,1 bar	Entropy of gas at standard conditions (1 bar)
  S°liquid,1 bar	Entropy of liquid at standard conditions (1 bar)
  S°solid	Entropy of solid at standard conditions
  S°solid,1 bar	Entropy of solid at standard conditions (1 bar)
  ΔfH°gas	Enthalpy of formation of gas at standard conditions
  ΔfH°liquid	Enthalpy of formation of liquid at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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