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platinum

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

H6Cl2N2Pt (cr) = platinum (cr) + 2Hydrogen chloride (g) + (4/3)Ammonia (g) + (1/3)Nitrogen (g)

By formula: H6Cl2N2Pt (cr) = Pt (cr) + 2HCl (g) + (4/3)H3N (g) + (1/3)N2 (g)

Quantity Value Units Method Reference Comment
Deltar52.9 ± 0.7kcal/molTD-HFCAl Takhin, Skinner, et al., 1983MS

(CAS Reg. No. 151247-65-3 bullet 4294967295platinum) + platinum = CAS Reg. No. 151247-65-3

By formula: (CAS Reg. No. 151247-65-3 bullet 4294967295Pt) + Pt = CAS Reg. No. 151247-65-3

Quantity Value Units Method Reference Comment
Deltar113.0 ± 6.9kcal/molN/AGrushow and Ervin, 1997gas phase; B

(CAS Reg. No. 119177-55-8 bullet 4294967295platinum) + platinum = CAS Reg. No. 119177-55-8

By formula: (CAS Reg. No. 119177-55-8 bullet 4294967295Pt) + Pt = CAS Reg. No. 119177-55-8

Quantity Value Units Method Reference Comment
Deltar100.9 ± 9.8kcal/molN/AErvin, Ho, et al., 1988gas phase; B

(CAS Reg. No. 151247-64-2 bullet 4294967295platinum) + platinum = CAS Reg. No. 151247-64-2

By formula: (CAS Reg. No. 151247-64-2 bullet 4294967295Pt) + Pt = CAS Reg. No. 151247-64-2

Quantity Value Units Method Reference Comment
Deltar99.2 ± 6.9kcal/molN/AGrushow and Ervin, 1997gas phase; B

(CAS Reg. No. 153298-77-2 bullet 4294967295platinum) + platinum = CAS Reg. No. 153298-77-2

By formula: (CAS Reg. No. 153298-77-2 bullet 4294967295Pt) + Pt = CAS Reg. No. 153298-77-2

Quantity Value Units Method Reference Comment
Deltar67.2 ± 1.5kcal/molN/AHo, Polak, et al., 1993gas phase; B

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Al Takhin, Skinner, et al., 1983
Al Takhin, G.; Skinner, H.A.; Zaki, A.A., J. Chem. Soc., Dalton Trans., 1983, 2323.. [all data]

Grushow and Ervin, 1997
Grushow, A.; Ervin, K.M., Ligand and Metal Binding Energies in Platinum Carbonyl Cluster Anions: Collision Induced Dissociation of PtM- and Ptm(CO)n-, J. Chem. Phys., 1997, 106, 23, 9580, https://doi.org/10.1063/1.474116 . [all data]

Ervin, Ho, et al., 1988
Ervin, K.M.; Ho, J.; Lineberger, W.C., Electronic and Vibrational Structure of Transition Metal Trimers: Photoelectron Spectra of Ni3-, Pd3- and Pt3-, J. Chem. Phys., 1988, 89, 8, 4514, https://doi.org/10.1063/1.454791 . [all data]

Ho, Polak, et al., 1993
Ho, J.; Polak, M.L.; Ervin, K.M.; Lineberger, W.C., Photoelectron Spectroscopy of Nickel Group Dimers - Ni2(-), Pd2(-), and Pt2(-), J. Chem. Phys., 1993, 99, 11, 8542, https://doi.org/10.1063/1.465577 . [all data]


Notes

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