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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Deltafgas415.47kJ/molReviewChase, 1998Data last reviewed in March, 1978
Quantity Value Units Method Reference Comment
gas,1 bar180.49J/mol*KReviewChase, 1998Data last reviewed in March, 1978

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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View table.

Temperature (K) 3133.345 - 6000.
A 11.29253
B 6.989707
C -1.110305
D 0.122354
E 5.689278
F 423.5380
G 206.3591
H 415.4716
ReferenceChase, 1998
Comment Data last reviewed in March, 1978

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Deltafliquid12.40kJ/molReviewChase, 1998Data last reviewed in March, 1978
Quantity Value Units Method Reference Comment
liquid,1 bar34.76J/mol*KReviewChase, 1998Data last reviewed in March, 1978

Liquid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 1809. - 3133.345
A 46.02400
B -1.884667×10-8
C 6.094750×10-9
D -6.640301×10-10
E -8.246121×10-9
F -10.80543
G 72.54094
H 12.39502
ReferenceChase, 1998
Comment Data last reviewed in March, 1978

Solid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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View table.

Temperature (K) 298. - 700.700. - 1042.1042. - 1100.1100. - 1809.298. - 1809.
A 18.42868-57767.65-325.8859-776.738723.97449
B 24.64301137919.728.92876919.40058.367750
C -8.913720-122773.20.000000-383.71840.000277
D 9.66470638682.420.00000057.08148-0.000086
E -0.0126433993.080411.9629242.1369-0.000005
F -6.57302224078.67745.8231697.62340.268027
G 42.51488-87364.01241.8766-558.367462.06336
H 0.0000000.0000000.0000000.0000007.788015
ReferenceChase, 1998Chase, 1998Chase, 1998Chase, 1998Chase, 1998
Comment «alpha»-«delta» phase; Data last reviewed in March, 1978 «alpha»-«delta» phase; Data last reviewed in March, 1978 «alpha»-«delta» phase; Data last reviewed in March, 1978 «alpha»-«delta» phase; Data last reviewed in March, 1978 «gamma» phase; Data last reviewed in March, 1978

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Gas phase ion energetics data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

CFeO (g) = Carbon monoxide (g) + iron (g)

By formula: CFeO (g) = CO (g) + Fe (g)

Quantity Value Units Method Reference Comment
Deltar35. ± 15.kJ/molFA-SIFTSunderlin, Wang, et al., 1992MS
Deltar<163.kJ/molN/AVenkataraman, Bandukwalla, et al., 1989Method: Velocity distributions of photofragments from Fe(CO)5.; MS
Deltar87. ± 29.kJ/molN/AEngelking and Lineberger, 1979Please also see Compton and Stockdale, 1976. Method: LPS and collision with low energy electrons.; MS

Iron ion (1+) + iron = (Iron ion (1+) bullet iron)

By formula: Fe+ + Fe = (Fe+ bullet Fe)

Quantity Value Units Method Reference Comment
Deltar260.kJ/molCIDLoh, Lian, et al., 1988gas phase; M
Deltar261.kJ/molPDissTecklenberg, Bricker, et al., 1988gas phase; «DELTA»rH>; M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
268. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet iron) + iron = (Iron ion (1+) bullet 2iron)

By formula: (Fe+ bullet Fe) + Fe = (Fe+ bullet 2Fe)

Quantity Value Units Method Reference Comment
Deltar233.kJ/molPDissTecklenberg, Bricker, et al., 1988gas phase; «DELTA»rH<; M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
169. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 2iron) + iron = (Iron ion (1+) bullet 3iron)

By formula: (Fe+ bullet 2Fe) + Fe = (Fe+ bullet 3Fe)

Quantity Value Units Method Reference Comment
Deltar174.kJ/molCIDLoh, Lian, et al., 1988gas phase; M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
216. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(CAS Reg. No. 59700-48-0 bullet 4294967295iron) + iron = CAS Reg. No. 59700-48-0

By formula: (CAS Reg. No. 59700-48-0 bullet 4294967295Fe) + Fe = CAS Reg. No. 59700-48-0

Quantity Value Units Method Reference Comment
Deltar395. ± 17.kJ/molN/ADrechsler, Boesl, et al., 1997gas phase; B
Deltar395. ± 29.kJ/molTherEngelking and Lineberger, 1977gas phase; B

C12Fe3O12 (cr) = 12Carbon monoxide (g) + 3iron (cr)

By formula: C12Fe3O12 (cr) = 12CO (g) + 3Fe (cr)

Quantity Value Units Method Reference Comment
Deltar516. ± 12.kJ/molTD-HFCConnor, Skinner, et al., 1973MS
Deltar526. ± 13.kJ/molHAL-HFCConnor, Skinner, et al., 1973MS

C6H4FeO4 (l) = 4Carbon monoxide (g) + iron (cr) + Ethylene (g)

By formula: C6H4FeO4 (l) = 4CO (g) + Fe (cr) + C2H4 (g)

Quantity Value Units Method Reference Comment
Deltar192.5 ± 8.4kJ/molHAL-HFCBrown, Connor, et al., 1976MS
Deltar185.4kJ/molTD-HFCBrown, Connor, et al., 1976MS

C9Fe2O9 (cr) = 9Carbon monoxide (g) + 2iron (cr)

By formula: C9Fe2O9 (cr) = 9CO (g) + 2Fe (cr)

Quantity Value Units Method Reference Comment
Deltar415.9 ± 4.3kJ/molTD-HFCConnor, Skinner, et al., 1973MS
Deltar413.4 ± 4.9kJ/molHAL-HFCConnor, Skinner, et al., 1973MS

(Iron ion (1+) bullet 3Carbon monoxide bullet 2iron) + Carbon monoxide = (Iron ion (1+) bullet 4Carbon monoxide bullet 2iron)

By formula: (Fe+ bullet 3CO bullet 2Fe) + CO = (Fe+ bullet 4CO bullet 2Fe)

Quantity Value Units Method Reference Comment
Deltar238.kJ/molPDissTecklenberg, Bricker, et al., 1988gas phase; «DELTA»rH<; M

(Iron ion (1+) bullet 10iron) + iron = (Iron ion (1+) bullet 11iron)

By formula: (Fe+ bullet 10Fe) + Fe = (Fe+ bullet 11Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
334. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 11iron) + iron = (Iron ion (1+) bullet 12iron)

By formula: (Fe+ bullet 11Fe) + Fe = (Fe+ bullet 12Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
408. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 12iron) + iron = (Iron ion (1+) bullet 13iron)

By formula: (Fe+ bullet 12Fe) + Fe = (Fe+ bullet 13Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
281. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 13iron) + iron = (Iron ion (1+) bullet 14iron)

By formula: (Fe+ bullet 13Fe) + Fe = (Fe+ bullet 14Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
377. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 14iron) + iron = (Iron ion (1+) bullet 15iron)

By formula: (Fe+ bullet 14Fe) + Fe = (Fe+ bullet 15Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
319. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 15iron) + iron = (Iron ion (1+) bullet 16iron)

By formula: (Fe+ bullet 15Fe) + Fe = (Fe+ bullet 16Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
323. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 16iron) + iron = (Iron ion (1+) bullet 17iron)

By formula: (Fe+ bullet 16Fe) + Fe = (Fe+ bullet 17Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
311. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 17iron) + iron = (Iron ion (1+) bullet 18iron)

By formula: (Fe+ bullet 17Fe) + Fe = (Fe+ bullet 18Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
373. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 9iron) + iron = (Iron ion (1+) bullet 10iron)

By formula: (Fe+ bullet 9Fe) + Fe = (Fe+ bullet 10Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
308. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 3iron) + iron = (Iron ion (1+) bullet 4iron)

By formula: (Fe+ bullet 3Fe) + Fe = (Fe+ bullet 4Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
260. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 4iron) + iron = (Iron ion (1+) bullet 5iron)

By formula: (Fe+ bullet 4Fe) + Fe = (Fe+ bullet 5Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
315. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 5iron) + iron = (Iron ion (1+) bullet 6iron)

By formula: (Fe+ bullet 5Fe) + Fe = (Fe+ bullet 6Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
320. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 6iron) + iron = (Iron ion (1+) bullet 7iron)

By formula: (Fe+ bullet 6Fe) + Fe = (Fe+ bullet 7Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
252. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 7iron) + iron = (Iron ion (1+) bullet 8iron)

By formula: (Fe+ bullet 7Fe) + Fe = (Fe+ bullet 8Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
281. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 8iron) + iron = (Iron ion (1+) bullet 9iron)

By formula: (Fe+ bullet 8Fe) + Fe = (Fe+ bullet 9Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
284. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet iron) + Carbon monoxide = (Iron ion (1+) bullet Carbon monoxide bullet iron)

By formula: (Fe+ bullet Fe) + CO = (Fe+ bullet CO bullet Fe)

Quantity Value Units Method Reference Comment
Deltar245.kJ/molPDissTecklenberg, Bricker, et al., 1988gas phase; «DELTA»rH<; M

(CAS Reg. No. 64899-88-3 bullet 4294967295iron) + iron = CAS Reg. No. 64899-88-3

By formula: (CAS Reg. No. 64899-88-3 bullet 4294967295Fe) + Fe = CAS Reg. No. 64899-88-3

Quantity Value Units Method Reference Comment
Deltar180. ± 29.kJ/molN/AStevens, Feigerle, et al., 1983gas phase; B

C12FeO12Ru2 (cr) = 12Carbon monoxide (g) + iron (cr) + 2ruthenium (cr)

By formula: C12FeO12Ru2 (cr) = 12CO (g) + Fe (cr) + 2Ru (cr)

Quantity Value Units Method Reference Comment
Deltar565. ± 10.kJ/molTD-HFCBaev, Connor, et al., 1981MS

C12Fe2O12Ru (cr) = 12Carbon monoxide (g) + 2iron (cr) + ruthenium (cr)

By formula: C12Fe2O12Ru (cr) = 12CO (g) + 2Fe (cr) + Ru (cr)

Quantity Value Units Method Reference Comment
Deltar494. ± 7.kJ/molTD-HFCBaev, Connor, et al., 1981MS

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to Fe+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)7.9024 ± 0.0001eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)754.kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity731.1kJ/molN/AHunter and Lias, 1998HL

Electron affinity determinations

EA (eV) Method Reference Comment
0.31 ± 0.20D-EAMiller, Miller, et al., 1993Acidity stronger than EtCO2H, comparable to HCO2H.; B
0.1510 ± 0.0030LPESLeopold and Lineberger, 1986B
0.164 ± 0.035LPESEngelking and Lineberger, 1979, 2B
0.140 ± 0.050LPESEngelking and Lineberger, 1976B
<0.25 ± 0.20EIAECompton and Stockdale, 1976From Fe(CO)5; B

Ionization energy determinations

IE (eV) Method Reference Comment
7.92EIRussell, Solouki, et al., 1995LL
7.9024EVALLide, 1992LL
7.870SKelly, 1987LBLHLM
7.9023 ± 0.0001SSugar and Corliss, 1985LBLHLM
7.90PEDyke, Gravenor, et al., 1982LBLHLM
7.7 ± 0.2EIClements and Sale, 1976LLK
8.0 ± 0.5EIHildenbrand, 1975LLK
7.870SMoore, 1970RDSH

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Iron ion (1+) + iron = (Iron ion (1+) bullet iron)

By formula: Fe+ + Fe = (Fe+ bullet Fe)

Quantity Value Units Method Reference Comment
Deltar260.kJ/molCIDLoh, Lian, et al., 1988gas phase
Deltar261.kJ/molPDissTecklenberg, Bricker, et al., 1988gas phase; «DELTA»rH>

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
268. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

(Iron ion (1+) bullet iron) + iron = (Iron ion (1+) bullet 2iron)

By formula: (Fe+ bullet Fe) + Fe = (Fe+ bullet 2Fe)

Quantity Value Units Method Reference Comment
Deltar233.kJ/molPDissTecklenberg, Bricker, et al., 1988gas phase; «DELTA»rH<

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
169. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

(Iron ion (1+) bullet 2iron) + iron = (Iron ion (1+) bullet 3iron)

By formula: (Fe+ bullet 2Fe) + Fe = (Fe+ bullet 3Fe)

Quantity Value Units Method Reference Comment
Deltar174.kJ/molCIDLoh, Lian, et al., 1988gas phase

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
216. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

(Iron ion (1+) bullet 3iron) + iron = (Iron ion (1+) bullet 4iron)

By formula: (Fe+ bullet 3Fe) + Fe = (Fe+ bullet 4Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
260. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

(Iron ion (1+) bullet 4iron) + iron = (Iron ion (1+) bullet 5iron)

By formula: (Fe+ bullet 4Fe) + Fe = (Fe+ bullet 5Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
315. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

(Iron ion (1+) bullet 5iron) + iron = (Iron ion (1+) bullet 6iron)

By formula: (Fe+ bullet 5Fe) + Fe = (Fe+ bullet 6Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
320. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

(Iron ion (1+) bullet 6iron) + iron = (Iron ion (1+) bullet 7iron)

By formula: (Fe+ bullet 6Fe) + Fe = (Fe+ bullet 7Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
252. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

(Iron ion (1+) bullet 7iron) + iron = (Iron ion (1+) bullet 8iron)

By formula: (Fe+ bullet 7Fe) + Fe = (Fe+ bullet 8Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
281. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

(Iron ion (1+) bullet 8iron) + iron = (Iron ion (1+) bullet 9iron)

By formula: (Fe+ bullet 8Fe) + Fe = (Fe+ bullet 9Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
284. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

(Iron ion (1+) bullet 9iron) + iron = (Iron ion (1+) bullet 10iron)

By formula: (Fe+ bullet 9Fe) + Fe = (Fe+ bullet 10Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
308. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

(Iron ion (1+) bullet 10iron) + iron = (Iron ion (1+) bullet 11iron)

By formula: (Fe+ bullet 10Fe) + Fe = (Fe+ bullet 11Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
334. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

(Iron ion (1+) bullet 11iron) + iron = (Iron ion (1+) bullet 12iron)

By formula: (Fe+ bullet 11Fe) + Fe = (Fe+ bullet 12Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
408. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

(Iron ion (1+) bullet 12iron) + iron = (Iron ion (1+) bullet 13iron)

By formula: (Fe+ bullet 12Fe) + Fe = (Fe+ bullet 13Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
281. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

(Iron ion (1+) bullet 13iron) + iron = (Iron ion (1+) bullet 14iron)

By formula: (Fe+ bullet 13Fe) + Fe = (Fe+ bullet 14Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
377. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

(Iron ion (1+) bullet 14iron) + iron = (Iron ion (1+) bullet 15iron)

By formula: (Fe+ bullet 14Fe) + Fe = (Fe+ bullet 15Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
319. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

(Iron ion (1+) bullet 15iron) + iron = (Iron ion (1+) bullet 16iron)

By formula: (Fe+ bullet 15Fe) + Fe = (Fe+ bullet 16Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
323. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

(Iron ion (1+) bullet 16iron) + iron = (Iron ion (1+) bullet 17iron)

By formula: (Fe+ bullet 16Fe) + Fe = (Fe+ bullet 17Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
311. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

(Iron ion (1+) bullet 17iron) + iron = (Iron ion (1+) bullet 18iron)

By formula: (Fe+ bullet 17Fe) + Fe = (Fe+ bullet 18Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
373. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Sunderlin, Wang, et al., 1992
Sunderlin, L.S.; Wang, D.; Squires, R.R., Metal Carbonyl Bond Strengths in Fe(CO)n- and Ni(CO)n-, J. Am. Chem. Soc., 1992, 114, 8, 2788, https://doi.org/10.1021/ja00034a004 . [all data]

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Notes

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