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1,1'-Biphenyl, 3,4'-dimethyl-

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Phase change data

Go To: Top, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
BS - Robert L. Brown and Stephen E. Stein

Quantity Value Units Method Reference Comment
Tboil569.KN/ABlades, Blades, et al., 1954Uncertainty assigned by TRC = 4. K; TRC
Tboil559.KN/AHey and Jackson, 1934Uncertainty assigned by TRC = 4. K; TRC
Quantity Value Units Method Reference Comment
Tfus283.KN/ASkvarchenko, Ling, et al., 1962Uncertainty assigned by TRC = 4. K; identified as melting point; TRC
Tfus278.KN/ASkvarchenko, Ling, et al., 1962Uncertainty assigned by TRC = 5. K; identified as freezing point; TRC
Tfus287.8KN/AJohnson, 1957Uncertainty assigned by TRC = 0.6 K; TRC
Tfus288.KN/ABlades, Blades, et al., 1954Uncertainty assigned by TRC = 3. K; TRC
Tfus287.7KN/AKruber, 1932Uncertainty assigned by TRC = 3. K; TRC

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
426.20.020Weast and Grasselli, 1989BS

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Mass spectrum (electron ionization)

Go To: Top, Phase change data, UV/Visible spectrum, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Chemical Concepts
NIST MS number 155245

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


UV/Visible spectrum

Go To: Top, Phase change data, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Victor Talrose, Alexander N. Yermakov, Alexy A. Usov, Antonina A. Goncharova, Axlexander N. Leskin, Natalia A. Messineva, Natalia V. Trusova, Margarita V. Efimkina

Spectrum

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UVVis spectrum
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Additional Data

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Source Kusakov, et al., 1963
Owner INEP CP RAS, NIST OSRD
Collection (C) 2007 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin INSTITUTE OF ENERGY PROBLEMS OF CHEMICAL PHYSICS, RAS
Source reference RAS UV No. 20064
Instrument unknown
Melting point 14.5
Boiling point 153/ 15 mm

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
PackedApiezon L170.1656.Kríz, Popl, et al., 1974 
PackedApiezon L185.1668.Kríz, Popl, et al., 1974 

Kovats' RI, polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillarySP-1000185.2267.Kríz, Popl, et al., 1974N2; Column length: 50. m; Column diameter: 0.25 mm
CapillarySP-1000200.2224.Kríz, Popl, et al., 1974N2; Column length: 50. m; Column diameter: 0.25 mm

References

Go To: Top, Phase change data, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Blades, Blades, et al., 1954
Blades, H.; Blades, A.; Steacie, E.W.R., The Kinetics of Pyrolysis of Toluene, Can. J. Chem., 1954, 32, 298-311. [all data]

Hey and Jackson, 1934
Hey, D.H.; Jackson, E.R.B., J. Chem. Soc., 1934, 1934, 645. [all data]

Skvarchenko, Ling, et al., 1962
Skvarchenko, V.R.; Ling, W.-L.; Sedykh, N.V.; Levina, R.Ya., Aromatic Hydrocarbons XXIII. Biphenyls, Zh. Obshch. Khim., 1962, 32, 217-22. [all data]

Johnson, 1957
Johnson, E.A., J. Chem. Soc., 1957, 1957, 4155. [all data]

Kruber, 1932
Kruber, O., Chem. Ber., 1932, 65, 1382. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Kusakov, et al., 1963
Kusakov, M.M., et al., Ultraviolet Absorption Spectra of Aromatic Hydrocarbons, 1963, 190. [all data]

Kríz, Popl, et al., 1974
Kríz, J.; Popl, M.; Mostecký, J., Retention indices of biphenyls and diphenylalkanes, J. Chromatogr., 1974, 97, 1, 3-13, https://doi.org/10.1016/S0021-9673(01)97577-6 . [all data]


Notes

Go To: Top, Phase change data, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, References