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t-CHCl=CHCl+


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   F,G


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 53000 T gas Lake and Thompson, 1970
Jonathan, Ross, et al., 1970
Wittel and Bock, 1974
von Niessen, Asbrink, et al., 1982

State:   E


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 36790 ± 320 gas Lake and Thompson, 1970
Jonathan, Ross, et al., 1970
Wittel and Bock, 1974
von Niessen, Asbrink, et al., 1982


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

ag 880 ± 80 gas PE Wittel and Bock, 1974

State:   D


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 33970 ± 320 gas Lake and Thompson, 1970
Jonathan, Ross, et al., 1970
Wittel and Bock, 1974
von Niessen, Asbrink, et al., 1982

State:   C


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 24290 ± 320 gas Lake and Thompson, 1970
Jonathan, Ross, et al., 1970
Wittel and Bock, 1974
von Niessen, Asbrink, et al., 1982


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

ag 720 ± 80 gas PE Wittel and Bock, 1974

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 19800 T gas Lake and Thompson, 1970
Jonathan, Ross, et al., 1970
Wittel and Bock, 1974
von Niessen, Asbrink, et al., 1982


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

ag 640 ± 80 gas PE Wittel and Bock, 1974

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 17910 ± 500 gas Lake and Thompson, 1970
Jonathan, Ross, et al., 1970
Wittel and Bock, 1974
von Niessen, Asbrink, et al., 1982


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

ag 600 ± 80 gas PE Wittel and Bock, 1974

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

ag 2 C=C stretch 1451 gas TPE TPI Lake and Thompson, 1970
Wittel and Bock, 1974
Woo, Wang, et al., 2004
Bae, Lee, et al., 2006
3 1257 gas TPE TPI Woo, Wang, et al., 2004
Bae, Lee, et al., 2006
4 CCl s-stretch 943 gas TPE TPI Lake and Thompson, 1970
Jonathan, Ross, et al., 1970
Wittel and Bock, 1974
Woo, Wang, et al., 2004
Bae, Lee, et al., 2006
5 CCl s-deform. 368 gas TPE TPI Lake and Thompson, 1970
Wittel and Bock, 1974
Woo, Wang, et al., 2004
Bae, Lee, et al., 2006
au 6 CH OPLA bend 871 ± 2 gas TPI Bae, Lee, et al., 2006
6 CH OPLA bend 840.0 Ar IR Zhou, Gong, et al., 2007
7 163 gas TPE TPI Woo, Wang, et al., 2004
Bae, Lee, et al., 2006
bg 8 873 gas TPE TPI Woo, Wang, et al., 2004
Bae, Lee, et al., 2006
bu 9 CH stretch 3068 ± 2 gas TPE Woo, Wang, et al., 2004
9 CH stretch 3066.1 Ar IR Zhou, Gong, et al., 2007
10 CH bend 1236 gas TPE TPI Woo, Wang, et al., 2004
Bae, Lee, et al., 2006
10 CH bend 1231.9 Ar IR Zhou, Gong, et al., 2007
11 CCl a-stretch 955 gas TPI Bae, Lee, et al., 2006
11 CCl a-stretch 950.1 Ar IR Zhou, Gong, et al., 2007
12 251 gas TPI Bae, Lee, et al., 2006

Additional references: Jacox, 1994, page 336

Notes

TTentative assignment or approximate value
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lake and Thompson, 1970
Lake, R.F.; Thompson, H., Photoelectron spectra of halogenated ethylenes, Proc. Roy. Soc. (London), 1970, A315, 323. [all data]

Jonathan, Ross, et al., 1970
Jonathan, N.; Ross, K.; Tomlinson, V., The photoelectron spectra of dichloroethylenes, Intern. J. Mass Spectrom. Ion Phys., 1970, 4, 51. [all data]

Wittel and Bock, 1974
Wittel, K.; Bock, H., Photoelektronenspekten und molekuleigenschaften. XXVII. Chlor- und bromathylene- beispiele fur anderungen in «pi»- und «sigma»-Systemen, Chem. Ber., 1974, 107, 317. [all data]

von Niessen, Asbrink, et al., 1982
von Niessen, W.; Asbrink, L.; Bieri, G., 30.4 nm He (II) photoelectron spectra of organic molecules Part VI. Halogeno-compounds (C, H, X; X = Cl, Br, I), J. Electron Spectrosc. Relat. Phenom., 1982, 26, 2, 173, https://doi.org/10.1016/0368-2048(82)85065-2 . [all data]

Woo, Wang, et al., 2004
Woo, H.K.; Wang, P.; Lau, K.C.; Xing, X.; Ng, C.Y., Vacuum Ultraviolet (VUV) Pulsed Field Ionization-Photoelectron and VUV-IR Photoinduced Rydberg Ionization Study of, J. Phys. Chem. A, 2004, 108, 45, 9637, https://doi.org/10.1021/jp040250s . [all data]

Bae, Lee, et al., 2006
Bae, Y.J.; Lee, M.; Kim, M.S., One-Photon Mass-Analyzed Threshold Ionization Spectroscopy (MATI) of, J. Phys. Chem. A, 2006, 110, 27, 8535, https://doi.org/10.1021/jp056347b . [all data]

Zhou, Gong, et al., 2007
Zhou, H.; Gong, Y.; Zhou, M., Infrared Spectra of Chlorinated Ethylene Cations: C, J. Phys. Chem. A, 2007, 111, 4, 603, https://doi.org/10.1021/jp066618y . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

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