O2CuO2

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 15330 ± 320 gas Wu, Desai, et al., 1997

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
ag OO s-stretch 1010 ± 90 gas PE Wu, Desai, et al., 1997
b1u OO a-stretch 1110.1 Ar IR Darling, Garton-Sprenger, et al., 1974
Tevault, Mowery, et al., 1981
Gong and Zhou, 2009

Additional references: Jacox, 1998, page 299

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wu, Desai, et al., 1997
Wu, H.; Desai, S.R.; Wang, L., Chemical Bonding between Cu and Oxygen - Copper Oxides versus O2 Complexes: A Study of CuOx(x=0-6) Species by Anion Photoelectron Spectroscopy, J. Phys. Chem., 1997, 101, 11, 2103, https://doi.org/10.1021/jp9631442 . [all data]

Darling, Garton-Sprenger, et al., 1974
Darling, J.H.; Garton-Sprenger, M.B.; Ogden, J.S., Matrix isolation studies on reactions of metal atoms. The characterisation of Cu(O2)2 and Cr(O2)2, Sympos. Faraday Soc., 1974, 8, 75, https://doi.org/10.1039/fs9730800075 . [all data]

Tevault, Mowery, et al., 1981
Tevault, D.E.; Mowery, R.L.; De Marco, R.A.; Smardzewski, R.R., Matrix reactions of copper atoms and ozone molecules. Infrared spectrum of CuO, J. Chem. Phys., 1981, 74, 8, 4342, https://doi.org/10.1063/1.441676 . [all data]

Gong and Zhou, 2009
Gong, Y.; Zhou, M., Formation and characterization of the CuO5, CuO4 and CuO4- complexes in solid argon, Phys. Chem. Chem. Phys., 2009, 11, 39, 8714, https://doi.org/10.1039/b909999a . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Notes

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