CH2NOH+


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   F


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Txx = 62200 ± 1000 gas Frost, Lau, et al., 1982

State:   E


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Txx = 55800 ± 1000 gas Frost, Lau, et al., 1982

State:   D


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Txx = 44500 ± 1000 gas Frost, Lau, et al., 1982

State:   C


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Txx = 34290 ± 320 gas Frost, Lau, et al., 1982
Dognon, Pouchan, et al., 1984

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Txx = 29370 ± 320 gas Dargelos and Sandorfy, 1977
Frost, Lau, et al., 1982
Dognon, Pouchan, et al., 1984

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Txx = 4280 ± 320 gas Dargelos and Sandorfy, 1977
Frost, Lau, et al., 1982
Dognon, Pouchan, et al., 1984


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' CNO bend 444 ± 80 gas PE Dognon, Pouchan, et al., 1984

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' NO stretch 928 ± 80 gas PE Dognon, Pouchan, et al., 1984

Additional references: Jacox, 1994, page 318

Notes

xxEnergy separation between the band maxima of both the excited state and the ground state of a molecular cation, derived from a photoelectron spectrum.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Frost, Lau, et al., 1982
Frost, D.C.; Lau, W.M.; McDowell, C.A.; Westwood, N.P.C., A study by He I photoelectron spectroscopy of monomeric nitrosomethane, the cis and trans dimers, and formaldoxime, J. Phys. Chem., 1982, 86, 3577. [all data]

Dognon, Pouchan, et al., 1984
Dognon, J.P.; Pouchan, C.; Dargelos, A.; Flament, J.P., Ab initio CI study and vibronic analysis of the photoelectron spectra of formaldoxime, Chem. Phys. Lett., 1984, 109, 492. [all data]

Dargelos and Sandorfy, 1977
Dargelos, A.; Sandorfy, C., The photoelectron and far-ultraviolet absorption spectra of simple oximes, J. Chem. Phys., 1977, 67, 3011. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

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