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CH2=S radical anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Deltafgas56. ± 13.kJ/molR-EAMoran and Ellison, 1987 

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Td = 3750 ± 185 gas Moran and Ellison, 1987
Moran and Ellison, 1988

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 3 CS stretch 860 ± 220 gas PE Moran and Ellison, 1987
Moran and Ellison, 1988
b1 4 OPLA 450 ± 120 gas PE Moran and Ellison, 1987
Moran and Ellison, 1988

Additional references: Jacox, 1994, page 149

Notes

dPhotodissociation threshold

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Moran and Ellison, 1987
Moran, S.; Ellison, G.B., Electron spectroscopy of CH2S-, Int. J. Mass Spectrom. Ion Processes, 1987, 80, 83. [all data]

Moran and Ellison, 1988
Moran, S.; Ellison, G.B., Photoelectron Spectroscopy of Sulfur Ions, J. Phys. Chem., 1988, 92, 7, 1794, https://doi.org/10.1021/j100318a021 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

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