HOCl+


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   C


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Tx = 36150 ± 900 gas C-X Colbourne, Frost, et al., 1978

State:   B


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Tx = 28080 ± 900 gas B-X Colbourne, Frost, et al., 1978

State:   A


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

To = 7830 ± 160 gas A-X Colbourne, Frost, et al., 1978


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 2 Bend 1250 ± 80 gas PE Colbourne, Frost, et al., 1978
3 OCl stretch 700 ± 50 gas PE Colbourne, Frost, et al., 1978

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 3 OCl stretch 830 ± 50 gas PE Colbourne, Frost, et al., 1978

Additional references: Jacox, 1994, page 51

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Colbourne, Frost, et al., 1978
Colbourne, D.; Frost, D.C.; McDowell, C.A.; Westwood, N.P.C., The photoelectron spectra of the isoelectronic molecules hypochlorous acid HOCl chloramine NH2Cl, J. Chem. Phys., 1978, 68, 3574. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

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