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1-Butanol

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Enthalpy of vaporization at standard conditions (nominally 298.15 K, 1 atm.)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

DeltavapH° (kJ/mol) Method Reference Comment
52.42N/AMajer and Svoboda, 1985 
51.7N/ASchmeling and Strey, 2010Based on data from 243. - 303. K.; AC
48.4N/ANasirzadeh, Zimin, et al., 2004Based on data from 298. - 363. K.; AC
52.5CGCChickos, Hosseini, et al., 1995Based on data from 323. - 373. K.; AC
55.2N/AGracia, Sánchez, et al., 1992Based on data from 283. - 323. K.; AC
52.1CFuchs, Peacock, et al., 1982AC
52.34 ± 0.03CPolak and Benson, 1971ALS
52.34 ± 0.02CPolak and Benson, 1971AC
52.3N/AGundry, Harrop, et al., 1969DRB
52.3 ± 0.1CWadsö, Murto, et al., 1966AC
52.30 ± 0.08CWadso, 1966ALS
51.0 ± 0.1CMcCurdy and Laidler, 1963AC
52.80 ± 0.84VGreen, 1960ALS
51.9 ± 0.4CSkinner and Snelson, 1960ALS
51.4N/ASkinner and Snelson, 1960DRB
43.81 ± 0.04VMathews, 1926ALS; Data excluded from overall average

References

Go To: Top, Enthalpy of vaporization at standard conditions (nominally 298.15 K, 1 atm.), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Schmeling and Strey, 2010
Schmeling, T.; Strey, K., Equilibrium Vapor Pressure Measurements for the n-Alcohols in the Temperature Range from -30 °C to + 30 °C, Berichte der Bunsengesellschaft für physikalische Chemie, 2010, 87, 10, 871-874, https://doi.org/10.1002/bbpc.19830871008 . [all data]

Nasirzadeh, Zimin, et al., 2004
Nasirzadeh, Karamat; Zimin, Denys; Neueder, Roland; Kunz, Werner, Vapor-Pressure Measurements of Liquid Solutions at Different Temperatures: Apparatus for Use over an Extended Temperature Range and Some New Data, J. Chem. Eng. Data, 2004, 49, 3, 607-612, https://doi.org/10.1021/je034197x . [all data]

Chickos, Hosseini, et al., 1995
Chickos, James S.; Hosseini, Sarah; Hesse, Donald G., Determination of vaporization enthalpies of simple organic molecules by correlations of changes in gas chromatographic net retention times, Thermochimica Acta, 1995, 249, 41-62, https://doi.org/10.1016/0040-6031(95)90670-3 . [all data]

Gracia, Sánchez, et al., 1992
Gracia, M.; Sánchez, F.; Pérez, P.; Valero, J.; Gutiérrez Losa, C., Vapour pressures of (butan-1-ol + hexane) at temperatures between 283.10 K and 323.12 K, The Journal of Chemical Thermodynamics, 1992, 24, 5, 463-471, https://doi.org/10.1016/S0021-9614(05)80118-1 . [all data]

Fuchs, Peacock, et al., 1982
Fuchs, Richard; Peacock, L. Alan; Stephenson, W. Kirk, Enthalpies of interaction of polar and nonpolar molecules with aromatic solvents, Can. J. Chem., 1982, 60, 15, 1953-1958, https://doi.org/10.1139/v82-273 . [all data]

Polak and Benson, 1971
Polak, J.; Benson, G.C., Enthalpies of vaporization of some aliphatic alcohols, J. Chem. Thermodyn., 1971, 3, 235-242. [all data]

Gundry, Harrop, et al., 1969
Gundry, H.A.; Harrop, D.; Head, A.J.; Lewis, G.B., Thermodynamic properties of organic oxygen compounds. 21. Enthalpies of combustion of benzoic acid, pentan-1-ol, octan-1-ol, and hexadecan-1-ol, J. Chem. Thermodyn., 1969, 1, 321-332. [all data]

Wadsö, Murto, et al., 1966
Wadsö, Ingemar; Murto, Maija-Leena; Bergson, Göran; Ehrenberg, L.; Brunvoll, J.; Bunnenberg, E.; Djerassi, Carl; Records, Ruth, Heats of Vaporization for a Number of Organic Compounds at 25 degrees C., Acta Chem. Scand., 1966, 20, 544-552, https://doi.org/10.3891/acta.chem.scand.20-0544 . [all data]

Wadso, 1966
Wadso, I., Acta Chem. Scand., 1966, 20, 544. [all data]

McCurdy and Laidler, 1963
McCurdy, K.G.; Laidler, K.J., HEATS OF VAPORIZATION OF A SERIES OF ALIPHATIC ALCOHOLS, Can. J. Chem., 1963, 41, 8, 1867-1871, https://doi.org/10.1139/v63-274 . [all data]

Green, 1960
Green, J.H.S., Revision of the values of the heats of formation of normal alcohols, Chem. Ind. (London), 1960, 1215-1216. [all data]

Skinner and Snelson, 1960
Skinner, H.A.; Snelson, A., The heats of combustion of the four isomeric butyl alcohols, Trans. Faraday Soc., 1960, 56, 1776-1783. [all data]

Mathews, 1926
Mathews, J.H., The accurate measurement of heats of vaporization of liquids, J. Am. Chem. Soc., 1926, 48, 562-576. [all data]


Notes

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