1-Butanol
- Formula: C4H10O
- Molecular weight: 74.1216
- IUPAC Standard InChIKey: LRHPLDYGYMQRHN-UHFFFAOYSA-N
- CAS Registry Number: 71-36-3
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Butyl alcohol; n-Butan-1-ol; n-Butanol; n-Butyl alcohol; Butyl hydroxide; CCS 203; Hemostyp; Methylolpropane; Propylcarbinol; n-C4H9OH; Butanol; Butan-1-ol; 1-Hydroxybutane; Alcool butylique; Butanolo; Butylowy alkohol; Butyric alcohol; Propylmethanol; Butanolen; 1-Butyl alcohol; Rcra waste number U031; Butanol-1; NSC 62782
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Kovats' RI, non-polar column, isothermal
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-1 | HP-1 | HP-1 | HP-1 | HP-1 |
Column length (m) | 30. | 30. | 30. | 30. | 30. |
Carrier gas | |||||
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Temperature (C) | 0. | 10. | 20. | 30. | 40. |
I | 674.4 | 674.6 | 668.2 | 665.5 | 658.4 |
Reference | Wang, Liu, et al., 2005 | Wang, Liu, et al., 2005 | Wang, Liu, et al., 2005 | Wang, Liu, et al., 2005 | Wang, Liu, et al., 2005 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Packed | Packed | Capillary |
---|---|---|---|---|---|
Active phase | HP-1 | HP-1 | PMS-1000 | OV-1 | HP-101 |
Column length (m) | 30. | 30. | 2. | 50. | |
Carrier gas | N2 | He or N2 | H2 | ||
Substrate | Chromaton N-AW-DMCS | Gas-Chrom Q | |||
Column diameter (mm) | 0.25 | 0.25 | 0.2 | ||
Phase thickness (μm) | 0.25 | 0.25 | 0.2 | ||
Temperature (C) | 50. | 60. | 90. | 130. | 60. |
I | 653.1 | 648.2 | 642. | 645. | 653.30 |
Reference | Wang, Liu, et al., 2005 | Wang, Liu, et al., 2005 | Arutyunov, Kudryashov, et al., 2004 | Gurevich and Roshchina, 2003 | Garay, 2000 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-101 | SE-30 | SE-30 | SE-30 | SE-30 |
Column length (m) | 50. | 25. | 25. | 25. | 25. |
Carrier gas | H2 | He | He | He | He |
Substrate | |||||
Column diameter (mm) | 0.2 | 0.32 | 0.32 | 0.32 | 0.32 |
Phase thickness (μm) | 0.2 | 1. | 1. | 1. | 1. |
Temperature (C) | 60. | 100. | 110. | 120. | 130. |
I | 653.30 | 650.0 | 648.9 | 647.7 | 647.6 |
Reference | Garay, 2000 | Golovnya, Kuz'menko, et al., 2000 | Golovnya, Kuz'menko, et al., 2000 | Golovnya, Kuz'menko, et al., 2000 | Golovnya, Kuz'menko, et al., 2000 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | SE-30 | SE-30 | SE-30 | SE-30 | SE-30 |
Column length (m) | 25. | 25. | 25. | 25. | 25. |
Carrier gas | He | He | He | He | He |
Substrate | |||||
Column diameter (mm) | 0.32 | 0.32 | 0.32 | 0.32 | 0.32 |
Phase thickness (μm) | 1. | 1. | 1. | 1. | 1. |
Temperature (C) | 48. | 58. | 66. | 100. | 110. |
I | 661.9 | 659.2 | 657.3 | 650.0 | 648.9 |
Reference | Golovnya, Kuz'menko, et al., 2000 | Golovnya, Kuz'menko, et al., 2000 | Golovnya, Kuz'menko, et al., 2000 | Golovnya, Kuz'menko, et al., 2000, 2 | Golovnya, Kuz'menko, et al., 2000, 2 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | SE-30 | SE-30 | SE-30 | SE-30 | SE-30 |
Column length (m) | 25. | 25. | 25. | 25. | 25. |
Carrier gas | He | He | He | He | He |
Substrate | |||||
Column diameter (mm) | 0.32 | 0.32 | 0.32 | 0.32 | 0.32 |
Phase thickness (μm) | 1. | 1. | 1. | 1. | 1. |
Temperature (C) | 120. | 130. | 48. | 58. | 66. |
I | 647.7 | 647.6 | 661.9 | 659.2 | 657.3 |
Reference | Golovnya, Kuz'menko, et al., 2000, 2 | Golovnya, Kuz'menko, et al., 2000, 2 | Golovnya, Kuz'menko, et al., 2000, 2 | Golovnya, Kuz'menko, et al., 2000, 2 | Golovnya, Kuz'menko, et al., 2000, 2 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Packed | Packed | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | Porapack Q | SE-30 | OV-1 | OV-1 | SE-54 |
Column length (m) | 1. | 0.25 | 25. | 25. | 25. |
Carrier gas | H2 | He | He | He | He |
Substrate | Gas Chrom Q (100-120 mesh) | ||||
Column diameter (mm) | 0.31 | 0.31 | 0.31 | ||
Phase thickness (μm) | 0.52 | 0.52 | 0.52 | ||
Temperature (C) | 200. | 120. | 60. | 75. | 60. |
I | 636. | 646. | 646.8 | 643.9 | 661.9 |
Reference | Gawdzik and Matynia, 1994 | Kowalski, 1992 | Guan, Kiraly, et al., 1989 | Guan, Kiraly, et al., 1989 | Guan, Kiraly, et al., 1989 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Packed | Packed | Packed | Packed |
---|---|---|---|---|---|
Active phase | SE-54 | OV-101 | SE-30 | OV-1 | SE-30 |
Column length (m) | 25. | 2. | 1. | 1.5 | 1. |
Carrier gas | He | N2 | He | N2 | N2 |
Substrate | Chromosorb W AW DMCS (80-100 mesh) | Chromaton N Super (75-100 mesh) | |||
Column diameter (mm) | 0.31 | ||||
Phase thickness (μm) | 0.52 | ||||
Temperature (C) | 75. | 120. | 170. | 120. | 120. |
I | 659.6 | 663. | 675. | 663. | 645. |
Reference | Guan, Kiraly, et al., 1989 | Fernández-Sánchez, Fernández-Torres, et al., 1987 | Voelkel, 1987 | Betts, 1986 | Betts, 1986 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Packed | Capillary | Capillary | Capillary | Packed |
---|---|---|---|---|---|
Active phase | SP-2100 | SE-30 | SE-30 | SE-30 | SE-30 |
Column length (m) | 1. | 25. | 25. | 25. | 200. |
Carrier gas | N2 | N2 | |||
Substrate | |||||
Column diameter (mm) | 0.33 | 0.33 | 0.33 | ||
Phase thickness (μm) | |||||
Temperature (C) | 120. | 100. | 120. | 80. | 120. |
I | 651. | 649. | 649. | 660. | 647. |
Reference | Betts, 1986 | Haken and Korhonen, 1985 | Haken and Korhonen, 1985 | Haken and Korhonen, 1985 | Stolyarov and Kartsova, 1984 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Packed | Packed | Packed | Capillary | Packed |
---|---|---|---|---|---|
Active phase | SE-30 | OV-1 | SE-30 | OV-1 | Squalane |
Column length (m) | 3. | 2. | 2. | 150. | 1. |
Carrier gas | Ar | He | |||
Substrate | Gas Chrom Q (80-100 mesh) | Gas Chrom Q | Gaschrom Q | ||
Column diameter (mm) | 0.50 | ||||
Phase thickness (μm) | |||||
Temperature (C) | 150. | 120. | 100. | 60. | 100. |
I | 650. | 645. | 637. | 645. | 649.9 |
Reference | Tiess, 1984 | Valko, Papp, et al., 1984 | Winskowski, 1983 | Nijs and Jacobs, 1981 | Gröbler and Bálizs, 1979 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Packed | Packed | Packed | Packed | Packed |
---|---|---|---|---|---|
Active phase | SE-30 | Apiezon L | Apiezon L | Apiezon L | Squalane |
Column length (m) | 3.7 | 2. | |||
Carrier gas | N2 | ||||
Substrate | Celatom AW silanized | Celite 545 | Celite 545 | Chromosorb G | |
Column diameter (mm) | |||||
Phase thickness (μm) | |||||
Temperature (C) | 150. | 120. | 160. | 70. | 100. |
I | 636. | 620. | 619. | 618. | 642. |
Reference | Haken, Nguyen, et al., 1979 | Bogoslovsky, Anvaer, et al., 1978 | Bogoslovsky, Anvaer, et al., 1978 | Bogoslovsky, Anvaer, et al., 1978 | Evans and Newton, 1976 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Packed | Packed | Capillary | Packed | Packed |
---|---|---|---|---|---|
Active phase | Squalane | Squalane | Squalane | SE-30 | SE-30 |
Column length (m) | 2. | 2. | 50. | 1. | 1. |
Carrier gas | N2 | N2 | Ar | Ar | |
Substrate | Chromosorb G | Chromosorb G | Chromosorb W AW DMCS HP (80-100 mesh) | Chromosorb W AW DMCS HP (80-100 mesh) | |
Column diameter (mm) | 0.25 | ||||
Phase thickness (μm) | |||||
Temperature (C) | 100. | 100. | 60. | 100. | 120. |
I | 644. | 645. | 630. | 650. | 643. |
Reference | Evans and Newton, 1976 | Evans and Newton, 1976 | Ryba, 1976 | Pías and Gascó, 1975 | Pías and Gascó, 1975 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Packed | Packed | Packed | Capillary | Packed |
---|---|---|---|---|---|
Active phase | SE-30 | SE-30 | Apiezon M | Apiezon L | Apiezon L |
Column length (m) | 1. | 3.7 | 2.1 | 100. | 3. |
Carrier gas | Ar | N2 | N2 | CH4 | |
Substrate | Chromosorb W AW DMCS HP (80-100 mesh) | Celaton (62-72 mesh) | Chromosorb W | ||
Column diameter (mm) | 0.3 | ||||
Phase thickness (μm) | |||||
Temperature (C) | 140. | 150. | 130. | 120. | 100. |
I | 643. | 644. | 627. | 673. | 637. |
Reference | Pías and Gascó, 1975 | Ashes and Haken, 1974 | Golovnya and Garbuzov, 1974 | Agrawal, Tesarík, et al., 1972 | Wagaman and Smith, 1971 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Packed | Packed |
---|---|---|
Active phase | Squalane | SE-30 |
Column length (m) | 2. | |
Carrier gas | ||
Substrate | Chromosorb G | Chromosorb W |
Column diameter (mm) | ||
Phase thickness (μm) | ||
Temperature (C) | 50. | 100. |
I | 625. | 655. |
Reference | Mira and Sanchez, 1970 | Zarazir, Chovin, et al., 1970 |
Comment | MSDC-RI | MSDC-RI |
References
Go To: Top, Kovats' RI, non-polar column, isothermal, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Wang, Liu, et al., 2005
Wang, Y.; Liu, J.; Li, N.; Shi, G.; Jiang, G.; Ma, W.,
Preliminary study of the retention behavior for different compounds using cryogenic chromatography at different initial temperatures,
Microchem. J., 2005, 81, 2, 184-190, https://doi.org/10.1016/j.microc.2005.02.003
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Arutyunov, Kudryashov, et al., 2004
Arutyunov, Y.I.; Kudryashov, S.Y.; Onuchak, L.A.,
Analysis of Mixtures Containing Unknown Components by Gas Chromatography: Determination of Molecular Mass,
J. Anal. Chem. USSR (Engl. Transl.), 2004, 59, 4, 358-365. [all data]
Gurevich and Roshchina, 2003
Gurevich, K.B.; Roshchina, T.M.,
G as chromatography study of silica modified with polyfluoroalkyl groups,
J. Chromatogr. A, 2003, 1008, 97-103. [all data]
Garay, 2000
Garay, F.,
Application of a flow-tunable, serially coupled gas chromatographic capillary column system for the analysis of complex mixtures,
Chromatographia Sup., 2000, 51, 1, s108-s120, https://doi.org/10.1007/BF02492792
. [all data]
Golovnya, Kuz'menko, et al., 2000
Golovnya, R.V.; Kuz'menko, T.e.; Samusenko, A.L.,
Method for prediction of the ability of analyte for self-association in pure liquid, Proceedings 23rd ISCC; CD-ROM, 2000, retrieved from http://www.richrom.com/assets/CD23PDF/a09.pdf. [all data]
Golovnya, Kuz'menko, et al., 2000, 2
Golovnya, R.V.; Kuz'menko, T.E.; Samusenko, A.L.,
Gas-chromatographic method of evaluation of n-alkanol ability for self-association in pure liquid,
Russ. Chem. Bull. (Engl. Transl.), 2000, 49, 2, 317-320, https://doi.org/10.1007/BF02494680
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Gawdzik and Matynia, 1994
Gawdzik, B.; Matynia, T.,
Characterization of methacrylic ester of p,p'-dihydroxydiphenylpropane diglicydyl ether - divinylbenzene porous copolymers for GC,
Chromatographia, 1994, 38, 9/10, 643-648, https://doi.org/10.1007/BF02277169
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Kowalski, 1992
Kowalski, W.J.,
Free radical crosslinking of the gas chromatographic stationary phase containing europium chelates,
Chromatographia, 1992, 34, 5-8, 266-268, https://doi.org/10.1007/BF02268356
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Guan, Kiraly, et al., 1989
Guan, Y.; Kiraly, J.; Rijks, J.A.,
Interactive retention index database for compound identification in temperature-programmed capillary gas chromatography,
J. Chromatogr., 1989, 472, 129-143, https://doi.org/10.1016/S0021-9673(00)94101-3
. [all data]
Fernández-Sánchez, Fernández-Torres, et al., 1987
Fernández-Sánchez, E.; Fernández-Torres, A.; García-Domínguez, J.A.; García-Muñoz, J.; Menéndez, V.; Molera, M.J.; Santiuste, J.M.; Pertierra-Rimada, E.,
Mixed stationary phases in gas-liquid chromatography. Partition coefficients and retention indices in OV-101-OV-25, OV-101-Carbowax 20M and OV-225-SP-2340 mixtures,
J. Chromatogr., 1987, 410, 13-29, https://doi.org/10.1016/S0021-9673(00)90031-1
. [all data]
Voelkel, 1987
Voelkel, A.,
Retention Indices and Thermodynamic Functions of Solution for Model Non-Ionic Surfactants in Standard Stationary Phases Determined by Gas Chromatography,
J. Chromatogr., 1987, 387, 95-104, https://doi.org/10.1016/S0021-9673(01)94516-9
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Betts, 1986
Betts, T.J.,
Triangular Characterization of Gas Chromatographic Stationary Phases,
J. Chromatogr., 1986, 354, 1-6, https://doi.org/10.1016/S0021-9673(01)87005-9
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Haken and Korhonen, 1985
Haken, J.K.; Korhonen, I.O.O.,
Gas chromatography of homologous esters. XXVII. Retention increments of C1-C18 primary alkanols and their 2-chloropropanoyl and 3-chloropropanoyl derivatives on SE-30 and OV-351 capillary columns,
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Stolyarov and Kartsova, 1984
Stolyarov, B.V.; Kartsova, L.A.,
Comparative experimental estimation of polarity and selectivity of stationary phases in gas chromatography by means of Forschneider-McReynolds constants and on the basis of thermodynamic characteristics,
Zh. Anal. Khim., 1984, 39, 5, 883-889. [all data]
Tiess, 1984
Tiess, D.,
Gaschromatographische Retentionsindices von 125 leicht- bis mittelflüchtigen organischen Substanzen toxikologisch-analytischer Relevanz auf SE-30,
Wiss. Z. Wilhelm-Pieck-Univ. Rostock Math. Naturwiss. Reihe, 1984, 33, 6-9. [all data]
Valko, Papp, et al., 1984
Valko, K.; Papp, O.; Darvas, F.,
Selection of Gas Chromatographic Stationary Phase Pairs for Characterization of the 1-Octanol-Water Partition Coefficient,
J. Chromatogr., 1984, 301, 355-364, https://doi.org/10.1016/S0021-9673(01)89210-4
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Winskowski, 1983
Winskowski, J.,
Gaschromatographische Identifizierung von Stoffen anhand von Indexziffem und unterschiedlichen Detektoren,
Chromatographia, 1983, 17, 3, 160-165, https://doi.org/10.1007/BF02271041
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Nijs and Jacobs, 1981
Nijs, H.H.; Jacobs, P.A.,
On-Line Single Run Analysis of Effluents from a Fischer-Tropsch Reactor,
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Gröbler and Bálizs, 1979
Gröbler, A.; Bálizs, G.,
Investigations on mixed gas chromatographic stationary phases. Part I. Dependence of the retention index on the composition of the stationary phase,
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Haken, Nguyen, et al., 1979
Haken, J.K.; Nguyen, A.; Wainwright, M.S.,
Application of linear extrathermodynamic relationships to alcohols, aldehydes, ketones, amd ethoxy alcohols,
J. Chromatogr., 1979, 179, 1, 75-85, https://doi.org/10.1016/S0021-9673(00)80658-5
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Bogoslovsky, Anvaer, et al., 1978
Bogoslovsky, Yu.N.; Anvaer, B.I.; Vigdergauz, M.S.,
Chromatographic constants in gas chromatography (in Russian), Standards Publ. House, Moscow, 1978, 192. [all data]
Evans and Newton, 1976
Evans, M.B.; Newton, R.,
Inverse gas chromatography in the study of polymer degradation. Part I. Oxidation of squalene as a model for the oxidative degradation of natural rubber,
Chromatographia, 1976, 9, 11, 561-566, https://doi.org/10.1007/BF02275963
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Ryba, 1976
Ryba, M.,
Unlösliche Restfilme er stationären Flüssigkeit in gas-chromatographischen Glaskapillaren,
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Pías and Gascó, 1975
Pías, J.B.; Gascó, L.,
GC Retention Data of Alcohols and Benzoyl Derivatives of Alcohols,
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Ashes and Haken, 1974
Ashes, J.R.; Haken, J.K.,
Gas chromatography of homologous esters. VI. Structure-retention increments of aliphatic esters,
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Golovnya and Garbuzov, 1974
Golovnya, R.V.; Garbuzov, V.G.,
Effect of heteroatom in aliphatic sulfur- and oxygen-containing compounds on the values of the retention indices in gas chromatography,
Izv. Akad. Nauk SSSR Ser. Khim., 1974, 7, 1519-1521. [all data]
Agrawal, Tesarík, et al., 1972
Agrawal, B.B.; Tesarík, K.; Janák, J.,
Gas chromatographic characterization of sulphur compounds in the 93-162° gasoline cut from Romashkino crude oil using Kováts retention indices,
J. Chromatogr., 1972, 65, 1, 207-215, https://doi.org/10.1016/S0021-9673(00)86933-2
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Wagaman and Smith, 1971
Wagaman, K.L.; Smith, T.G.,
Use of hydrocarbons as carrier gases in GLC,
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Mira and Sanchez, 1970
Mira, J.M.; Sanchez, L.G.,
Polarity of the Gas Chromatographic Stationary Phases and Retention Indices of Aliphatic Esters, Ketones and Alcohols,
Anal. Chim. Acta., 1970, 50, 2, 315-321, https://doi.org/10.1016/0003-2670(70)80071-X
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Zarazir, Chovin, et al., 1970
Zarazir, D.; Chovin, P.; Guiochon, G.,
Identification of hydroxylic compounds and their derivatives by gas chromatography,
Chromatographia, 1970, 3, 4, 180-195, https://doi.org/10.1007/BF02269018
. [all data]
Notes
Go To: Top, Kovats' RI, non-polar column, isothermal, References
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