1-Butanol
- Formula: C4H10O
- Molecular weight: 74.1216
- IUPAC Standard InChIKey: LRHPLDYGYMQRHN-UHFFFAOYSA-N
- CAS Registry Number: 71-36-3
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Butyl alcohol; n-Butan-1-ol; n-Butanol; n-Butyl alcohol; Butyl hydroxide; CCS 203; Hemostyp; Methylolpropane; Propylcarbinol; n-C4H9OH; Butanol; Butan-1-ol; 1-Hydroxybutane; Alcool butylique; Butanolo; Butylowy alkohol; Butyric alcohol; Propylmethanol; Butanolen; 1-Butyl alcohol; Rcra waste number U031; Butanol-1; NSC 62782
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Kovats' RI, polar column, isothermal
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Column type | Capillary | Capillary | Capillary | Packed | Packed |
---|---|---|---|---|---|
Active phase | Carbowax 20M | Supelcowax-10 | Supelcowax-10 | Carbowax 20M | Carbowax 20M |
Column length (m) | 31.3 | 30. | 60. | 2. | 3.5 |
Carrier gas | He | N2 | N2 | N2 | |
Substrate | Chromosorb W AW DMCS | Chromosorb W-AW | |||
Column diameter (mm) | 0.53 | 0.32 | 0.75 | ||
Phase thickness (μm) | 0.54 | 0.25 | |||
Temperature (C) | 70. | 60. | 60. | 120. | 80. |
I | 1120. | 1147.5 | 1146. | 1178. | 1126. |
Reference | Annino and Villalobos, 1999 | Castello, Vezzani, et al., 1994 | Castello, Vezzani, et al., 1991 | Fernández-Sánchez, Fernández-Torres, et al., 1987 | Kersten and Poole, 1987 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Packed | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | PEG-20M | OV-351 | OV-351 | OV-351 | OV-351 |
Column length (m) | 1. | 25. | 25. | 25. | 25. |
Carrier gas | N2 | N2 | N2 | N2 | |
Substrate | |||||
Column diameter (mm) | 0.32 | 0.32 | 0.32 | 0.32 | |
Phase thickness (μm) | |||||
Temperature (C) | 120. | 100. | 120. | 140. | 80. |
I | 1104. | 1148. | 1124. | 1153. | 1131. |
Reference | Betts, 1986 | Haken and Korhonen, 1985 | Haken and Korhonen, 1985 | Haken and Korhonen, 1985 | Haken and Korhonen, 1985 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Packed |
---|---|---|---|---|---|
Active phase | Carbowax 20M | Carbowax 20M | Carbowax 20M | Carbowax 20M | PEG-20M |
Column length (m) | 2. | ||||
Carrier gas | N2 | ||||
Substrate | Chromaton N AW HMDS | ||||
Column diameter (mm) | |||||
Phase thickness (μm) | |||||
Temperature (C) | 100. | 110. | 120. | 90. | 120. |
I | 1133.33 | 1130.99 | 1129.04 | 1135.08 | 1135. |
Reference | Podmaniczky, Szepesy, et al., 1985 | Podmaniczky, Szepesy, et al., 1985 | Podmaniczky, Szepesy, et al., 1985 | Podmaniczky, Szepesy, et al., 1985 | Stolyarov and Kartsova, 1984 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Packed | Packed | Packed | Packed | Packed |
---|---|---|---|---|---|
Active phase | Carbowax 20M | PEG-2000 | PEG-2000 | PEG-2000 | PEG-2000 |
Column length (m) | 2. | 3. | 3. | 3. | 3. |
Carrier gas | N2 | He | He | He | He |
Substrate | Kieselgur (60-100 mesh) | Celite 545 (44-60 mesh) | Celite 545 (44-60 mesh) | Celite 545 (44-60 mesh) | Celite 545 (44-60 mesh) |
Column diameter (mm) | |||||
Phase thickness (μm) | |||||
Temperature (C) | 75. | 120. | 150. | 152. | 179. |
I | 1178. | 1120. | 1118. | 1152. | 1137. |
Reference | Goebel, 1982 | Anderson, Jurel, et al., 1973 | Anderson, Jurel, et al., 1973 | Anderson, Jurel, et al., 1973 | Anderson, Jurel, et al., 1973 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Packed | Packed | Packed | Packed | Packed |
---|---|---|---|---|---|
Active phase | PEG-2000 | PEG-2000 | Carbowax 20M | Polyethylene Glycol 4000 | Polyethylene Glycol 4000 |
Column length (m) | 3. | 3. | 2. | 6. | 6. |
Carrier gas | He | He | |||
Substrate | Celite 545 (44-60 mesh) | Celite 545 (44-60 mesh) | Chromosorb W | Chromosorb P | Chromosorb P |
Column diameter (mm) | |||||
Phase thickness (μm) | |||||
Temperature (C) | 180. | 200. | 100. | 100. | 120. |
I | 1115. | 1136. | 1138. | 1152. | 1143. |
Reference | Anderson, Jurel, et al., 1973 | Anderson, Jurel, et al., 1973 | Zarazir, Chovin, et al., 1970 | Bonastre and Grenier, 1968 | Bonastre and Grenier, 1968 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Packed | Packed |
---|---|---|
Active phase | Polyethylene Glycol 4000 | Polyethylene Glycol 4000 |
Column length (m) | 6. | 6. |
Carrier gas | ||
Substrate | Chromosorb P | Chromosorb P |
Column diameter (mm) | ||
Phase thickness (μm) | ||
Temperature (C) | 140. | 80. |
I | 1135. | 1160. |
Reference | Bonastre and Grenier, 1968 | Bonastre and Grenier, 1968 |
Comment | MSDC-RI | MSDC-RI |
References
Go To: Top, Kovats' RI, polar column, isothermal, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Annino and Villalobos, 1999
Annino, R.; Villalobos, R.,
A strategy for the simplification and solution of complex chromatographic analysis problems utilizing two-dimensional mapping of retention indexes followed by computer modeling of heart cuts from serially coupled columns containing different stationary phases,
J. Hi. Res. Chromatogr., 1999, 22, 10, 589-593. [all data]
Castello, Vezzani, et al., 1994
Castello, G.; Vezzani, S.; Moretti, P.,
The selectivity and polarity of carbon layer open tubular capillary columns modified with a polar liquid phase,
J. Hi. Res. Chromatogr., 1994, 17, 1, 31-36, https://doi.org/10.1002/jhrc.1240170108
. [all data]
Castello, Vezzani, et al., 1991
Castello, G.; Vezzani, S.; Gerbino, T.,
Gas chromatographic separation and automatic identification of complex mixtures of organic solvents in indrustrial wates,
J. Chromatogr., 1991, 585, 2, 273-280, https://doi.org/10.1016/0021-9673(91)85088-W
. [all data]
Fernández-Sánchez, Fernández-Torres, et al., 1987
Fernández-Sánchez, E.; Fernández-Torres, A.; García-Domínguez, J.A.; García-Muñoz, J.; Menéndez, V.; Molera, M.J.; Santiuste, J.M.; Pertierra-Rimada, E.,
Mixed stationary phases in gas-liquid chromatography. Partition coefficients and retention indices in OV-101-OV-25, OV-101-Carbowax 20M and OV-225-SP-2340 mixtures,
J. Chromatogr., 1987, 410, 13-29, https://doi.org/10.1016/S0021-9673(00)90031-1
. [all data]
Kersten and Poole, 1987
Kersten, B.R.; Poole, C.F.,
Influence of concurrent retention mechanisms on the determination of stationary phase selectivity in gas chromatography,
J. Chromatogr., 1987, 399, 1-31, https://doi.org/10.1016/S0021-9673(00)96108-9
. [all data]
Betts, 1986
Betts, T.J.,
Triangular Characterization of Gas Chromatographic Stationary Phases,
J. Chromatogr., 1986, 354, 1-6, https://doi.org/10.1016/S0021-9673(01)87005-9
. [all data]
Haken and Korhonen, 1985
Haken, J.K.; Korhonen, I.O.O.,
Gas chromatography of homologous esters. XXVII. Retention increments of C1-C18 primary alkanols and their 2-chloropropanoyl and 3-chloropropanoyl derivatives on SE-30 and OV-351 capillary columns,
J. Chromatogr., 1985, 319, 131-142, https://doi.org/10.1016/S0021-9673(01)90548-5
. [all data]
Podmaniczky, Szepesy, et al., 1985
Podmaniczky, L.; Szepesy, L.; Lakszner, K.; Schomburg, G.,
Relationship between thermodynamic characteristics and isothermal retention indices,
Chromatographia, 1985, 20, 10, 623-628, https://doi.org/10.1007/BF02263223
. [all data]
Stolyarov and Kartsova, 1984
Stolyarov, B.V.; Kartsova, L.A.,
Comparative experimental estimation of polarity and selectivity of stationary phases in gas chromatography by means of Forschneider-McReynolds constants and on the basis of thermodynamic characteristics,
Zh. Anal. Khim., 1984, 39, 5, 883-889. [all data]
Goebel, 1982
Goebel, K.-J.,
Gaschromatographische Identifizierung Niedrig Siedender Substanzen Mittels Retentionsindices und Rechnerhilfe,
J. Chromatogr., 1982, 235, 1, 119-127, https://doi.org/10.1016/S0021-9673(00)95793-5
. [all data]
Anderson, Jurel, et al., 1973
Anderson, A.; Jurel, S.; Shymanska, M.; Golender, L.,
Gas-liquid chromatography of some aliphatic and heterocyclic mono- and pollyfunctional amines. VII. Retention indices of amines in some polar and unpolar stationary phases,
Latv. PSR Zinat. Akad. Vestis Kim. Ser., 1973, 1, 51-63. [all data]
Zarazir, Chovin, et al., 1970
Zarazir, D.; Chovin, P.; Guiochon, G.,
Identification of hydroxylic compounds and their derivatives by gas chromatography,
Chromatographia, 1970, 3, 4, 180-195, https://doi.org/10.1007/BF02269018
. [all data]
Bonastre and Grenier, 1968
Bonastre, J.; Grenier, P.,
Contribution à l'étude de la polarité des phases stationnaires en chromatographie gaz-liquide. III. Calcul des coefficients d'activité relatifs et des indices de rétention de quelques alcools aliphatiques,
Bull. Soc. Chim. Fr., 1968, 1, 118-125. [all data]
Notes
Go To: Top, Kovats' RI, polar column, isothermal, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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