HCF radical anion
- Formula: CHF-
- Molecular weight: 32.0176
- CAS Registry Number: 71267-42-0
- Information on this page:
- Other data available:
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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CHF- + = CH2F
By formula: CHF- + H+ = CH2F
|rH°||398.6 ± 1.5||kcal/mol||G+TS||Born, Ingemann, et al., 1994||gas phase; Between EtNH2 and Me2NH|
|rH°||394.3 ± 5.2||kcal/mol||D-EA||Gilles, Ervin, et al., 1992||gas phase; Triplet state of neutral: 14.9±0.4 kcal/mol higher than singlet|
|rG°||390.5 ± 1.4||kcal/mol||IMRB||Born, Ingemann, et al., 1994||gas phase; Between EtNH2 and Me2NH|
|rG°||386.2 ± 5.3||kcal/mol||H-TS||Gilles, Ervin, et al., 1992||gas phase; Triplet state of neutral: 14.9±0.4 kcal/mol higher than singlet|
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Born, Ingemann, et al., 1994
Born, M.; Ingemann, S.; Nibbering, N.M.M., Heats of formation of mono-halogen-substituted carbenes. Stability and reactivity of CHX(center dot-) (X=F, Cl, Pr, and I) radical anions, J. Am. Chem. Soc., 1994, 116, 16, 7210, https://doi.org/10.1021/ja00095a025 . [all data]
Gilles, Ervin, et al., 1992
Gilles, M.K.; Ervin, K.M.; Ho, J.; Lineberger, W.C., Negative Ion Photoelectron Spectroscopy of HCF-, HCCl-, HCBr-, and HCI- - Photoelectron Angular Distributions and Neutral Triplet Excitation, J. Phys. Chem., 1992, 96, 3, 1130, https://doi.org/10.1021/j100182a021 . [all data]
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- Symbols used in this document:
rG° Free energy of reaction at standard conditions rH° Enthalpy of reaction at standard conditions
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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