1,3,5-C6H3Cl3+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   F
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 29530 ± 800 gas Maier and Marthaler, 1978

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 20900 ± 160 gas Maier and Marthaler, 1978

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 17510 ± 160 gas Maier and Marthaler, 1978

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 15410 ± 5 gas B-X 575 770 Maier and Marthaler, 1978
Miller, Bondybey, et al., 1979
Cossart-Magos, Cossart, et al., 1979
To = 15266 Ne B-X 580 710 Miller, Bondybey, et al., 1979
To = 14886 Ar B-X 580 730 Miller, Bondybey, et al., 1979
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1' 2 1096 gas LF EM Miller, Bondybey, et al., 1979
Cossart-Magos, Cossart, et al., 1979
2 1096 Ne LF Miller, Bondybey, et al., 1979
Bondybey, Miller, et al., 1979
2 1091 Ar LF Miller, Bondybey, et al., 1979
3 978 gas LF Miller, Bondybey, et al., 1979
3 974 Ne LF Miller, Bondybey, et al., 1979
Bondybey, Miller, et al., 1979
3 970 Ar LF Miller, Bondybey, et al., 1979
4 358 gas LF Miller, Bondybey, et al., 1979
4 368 Ar LF Miller, Bondybey, et al., 1979
e' 9 1510 gas LF Miller, Bondybey, et al., 1979
9 1510 Ne LF Miller, Bondybey, et al., 1979
Bondybey, Miller, et al., 1979
9 1508 Ar LF Miller, Bondybey, et al., 1979
10 1417 gas LF Miller, Bondybey, et al., 1979
10 1412 Ne LF Miller, Bondybey, et al., 1979
Bondybey, Miller, et al., 1979
10 1411 Ar LF Miller, Bondybey, et al., 1979
11 995 Ne LF Miller, Bondybey, et al., 1979
Bondybey, Miller, et al., 1979
12 809 Ar LF Miller, Bondybey, et al., 1979
13 428 gas LF EM Miller, Bondybey, et al., 1979
Cossart-Magos, Cossart, et al., 1979
13 427 Ne LF Bondybey, Miller, et al., 1979
13 426 Ar LF Miller, Bondybey, et al., 1979
14 181 gas LF EM Miller, Bondybey, et al., 1979
Cossart-Magos, Cossart, et al., 1979
14 195 Nw LF Miller, Bondybey, et al., 1979
Bondybey, Miller, et al., 1979
14 190 Ar LF Miller, Bondybey, et al., 1979

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1' 1 2925 gas EM Cossart-Magos, Cossart, et al., 1979
2 1189 gas PE EM Maier and Marthaler, 1978
Cossart-Magos, Cossart, et al., 1979
2 1190 Ne LF Miller, Bondybey, et al., 1979
Bondybey, Miller, et al., 1979
2 1183 Ar LF Miller, Bondybey, et al., 1979
3 1068 gas EM Cossart-Magos, Cossart, et al., 1979
982 Ne LF Bondybey, Miller, et al., 1979
4 438 gas LF Miller, Bondybey, et al., 1979
4 442 Ne LF Miller, Bondybey, et al., 1979
Bondybey, Miller, et al., 1979
e' 9 1584 gas EM Cossart-Magos, Cossart, et al., 1979
9 1588 Ne LF Bondybey, Miller, et al., 1979
10 1519 gas EM Cossart-Magos, Cossart, et al., 1979
11 1074 Ne LF Bondybey, Miller, et al., 1979
13 498 gas EF EM Maier and Marthaler, 1978
Cossart-Magos, Cossart, et al., 1979
13 501 Ne LF Miller, Bondybey, et al., 1979
Bondybey, Miller, et al., 1979
14 191 gas LF Miller, Bondybey, et al., 1979
14 195 Ne LF Miller, Bondybey, et al., 1979
Bondybey, Miller, et al., 1979

Additional references: Jacox, 1994, page 434

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Maier and Marthaler, 1978
Maier, J.P.; Marthaler, O., Emission spectra of the radical cations of 1,3-dichlorobenzene, 1,4-dichlorobenzene and 1,3,5-trichlorobenzene in the gas phase, Chem. Phys., 1978, 32, 419. [all data]

Miller, Bondybey, et al., 1979
Miller, T.A.; Bondybey, V.E.; English, J.H., The vibrationally resolved electronic spectrum of the sym-trichlorobenzene radical cation in gas and condensed phases, J. Chem. Phys., 1979, 70, 6, 2919, https://doi.org/10.1063/1.437830 . [all data]

Cossart-Magos, Cossart, et al., 1979
Cossart-Magos, C.; Cossart, D.; Leach, S., Jahn---Teller effects in substituted benzene cations. III. Gas phase emission spectrum of sym-C6Cl3H+3, Chem. Phys., 1979, 41, 3, 363, https://doi.org/10.1016/0301-0104(79)80040-3 . [all data]

Bondybey, Miller, et al., 1979
Bondybey, V.E.; Miller, T.A.; English, J.H., Laser induced fluorescence spectra of symmetrically substituted trihalobenzene radical cations, J. Chem. Phys., 1979, 71, 3, 1088, https://doi.org/10.1063/1.438474 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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