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diethyl sulphoxide

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

View reactions leading to C4H10OS+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)8.75eVN/AN/AL

Ionization energy determinations

IE (eV) Method Reference Comment
8.75 ± 0.03EIPotzinger, Stracke, et al., 1975LLK
8.76PEBock and Solouki, 1974Vertical value; LLK
8.76PEBock and Solouki, 1972Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CH3OS+12.04 ± 0.08C2H4+CH3EIPotzinger, Stracke, et al., 1975LLK
C2H5+11.9 ± 0.2C2H5SOEIPotzinger, Stracke, et al., 1975LLK
C2H6OS+9.86 ± 0.08C2H4EIPotzinger, Stracke, et al., 1975LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Potzinger, Stracke, et al., 1975
Potzinger, P.; Stracke, H.-U.; Kupper, W.; Gollnick, K., Ionisierungs- und Auftrittspotentialmessungen an Dialkylsulfoxiden, Z. Naturforsch. A:, 1975, 30, 340. [all data]

Bock and Solouki, 1974
Bock, H.; Solouki, B., Photoelektronenspektren und molekuleigenschaften, XXXV. Sulfoxide X2SO - beispiele fur den nutzen von korrelations - diagrammen bei der diskussion von substituenteneffekten und von geometrischen storungen, Chem. Ber., 1974, 107, 2299. [all data]

Bock and Solouki, 1972
Bock, H.; Solouki, B., The sulfoxide bond, Angew. Chem. Int. Ed. Engl., 1972, 11, 436. [all data]


Notes

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