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D-Mannitol

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafsolid-1337.5kJ/molCcbMcClaine, 1947ALS
Deltafsolid-1337.2 ± 0.79kJ/molCcbParks, West, et al., 1946ALS
Quantity Value Units Method Reference Comment
Deltacsolid-3053.kJ/molCcbBaer and Flehmig, 1969Corresponding «DELTA»fsolid = -1309. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacsolid-3045.7kJ/molCmParks and Manchester, 1952From heat of solution; Corresponding «DELTA»fsolid = -1316.1 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacsolid-3025. ± 2.kJ/molCcbMcClaine, 1947Corresponding «DELTA»fsolid = -1337. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacsolid-3024.7 ± 1.8kJ/molCcbParks, West, et al., 1946Corresponding «DELTA»fsolid = -1337.1 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
solid,1 bar238.5J/mol*KN/AParks, Kelley, et al., 1929Extrapolation below 90 K, 64.02 J/mol*K. Revision of previous data.; DH
solid,1 bar253.1J/mol*KN/AParks and Anderson, 1926Extrapolation below 90 K, 78.66 J/mol*K.; DH

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
239.00298.15Lian, Chen, et al., 1982DH
244.8303.Spaght, Thomas, et al., 1932T = 30 to 200°C.; DH
236.0294.1Parks and Anderson, 1926T = 88 to 294 K. Value is unsmoothed experimental datum.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

McClaine, 1947
McClaine, L.A., Thermodynamic data for some compounds containing carbon, hydrogen and oxygen, Ph.D. Thesis for Stanford University, 1947, 1-57. [all data]

Parks, West, et al., 1946
Parks, G.S.; West, T.J.; Naylor, B.F.; Fujii, P.S.; McClaine, L.A., Thermal data on organic compounds. XXIII. Modern combustion data for fourteen hydrocarbons and five polyhydroxy alcohols, J. Am. Chem. Soc., 1946, 68, 2524-2527. [all data]

Baer and Flehmig, 1969
Baer, E.; Flehmig, H.-H., Refutation of alleged differences in the energy contents of optical isomers, Can. J. Biochem., 1969, 47, 79-83. [all data]

Parks and Manchester, 1952
Parks, G.S.; Manchester, K.E., The heats of solution of erythritol, mannitol and dulcitol; combustion values for liquid polyhydroxy alcohols, J. Am. Chem. Soc., 1952, 74, 3435-34. [all data]

Parks, Kelley, et al., 1929
Parks, G.S.; Kelley, K.K.; Huffman, H.M., Thermal data on organic compounds. V. A revision of the entropies and free energies of nineteen organic compounds, J. Am. Chem. Soc., 1929, 51, 1969-1973. [all data]

Parks and Anderson, 1926
Parks, G.S.; Anderson, C.T., Thermal data on organic compounds. III. The heat capacities, entropies and free energies of tertiary butyl alcohol, mannitol, erythritol and normal butyric acid, J. Am. Chem. Soc., 1926, 48, 1506-1512. [all data]

Lian, Chen, et al., 1982
Lian, Y.N.; Chen, A.T.; Suurkuusk, J.; Wadsoe, I., Polyol-water interactions as reflected by aqueous heat capacity values, Acta Chem. Scand., 1982, A36(9), 735-739. [all data]

Spaght, Thomas, et al., 1932
Spaght, M.E.; Thomas, S.B.; Parks, G.S., Some heat capacity data on organic compounds obtained with a radiation calorimeter, J. Phys. Chem., 1932, 36, 882-888. [all data]


Notes

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