Dicobalt, bis(μ2-carbonyl)-bis(η5-pentamethylcyclopentadienyl)-
- Formula: C22H30Co2O2
- Molecular weight: 444.3388
- CAS Registry Number: 69657-52-9
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 5.95 | PE | Dudeney, Green, et al., 1984 | LBLHLM |
| 5.95 | PE | Dudeney, Green, et al., 1983 | LBLHLM |
| 6.22 ± 0.02 | PE | Lichtenberger and Copenhaver, 1990 | Vertical value; LL |
| 6.29 | PE | Dudeney, Green, et al., 1984 | Vertical value; LBLHLM |
| 6.29 | PE | Dudeney, Green, et al., 1983 | Vertical value; LBLHLM |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Dudeney, Green, et al., 1984
Dudeney, N.; Green, J.C.; Kirchner, O.N.; Smallwood, F.S.J.,
A study of the electronic structure of the dimers [Co2(η-C5Me5)2(CO)2], [Rh2(η-C5Me5)2], [Co2(η-C5Me5)2(NO)2] and [Co2(η-C5Me5)2(CO)(NO)] by He-I and He-II photoelectron spectroscopy,
J. Chem. Soc. Dalton Trans., 1984, 1883. [all data]
Dudeney, Green, et al., 1983
Dudeney, N.; Green, J.C.; Grebenik, P.; Kirchner, O.N.,
Synthesis and structural characterization of the electron rich complexes Co(η-C5Me5)(R2PCH2CH2PR2) (R = Me, Ph) photoelectron spectroscopic studies of some pentamethylcyclopentadienylphosphinecobalt complexes,
J. Organomet. Chem., 1983, 252, 221. [all data]
Lichtenberger and Copenhaver, 1990
Lichtenberger, D.L.; Copenhaver, A.S.,
The electronic structure of nitrosyl and carbonyl supported metal-metal interactions. The photoelectron spectra of [η5-(C5H5)Fe(μ-NO)]2, [η5-(C5(CH3)5)Fe(μ-NO)]2, [η5-(C5H5)Ru(μ-NO)]2 and [η5-(C5(CH3)5)Co(μ-CO)]2,
Polyhedron, 1990, 9, 1783. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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