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1-Hexyne

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Kovats' RI, non-polar column, isothermal

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type PackedPackedPackedCapillaryCapillary
Active phase C78, Branched paraffinC78, Branched paraffinApolaneSqualaneSqualane
Column length (m) 3.33.33.7107.100.
Carrier gas He  H2N2
Substrate  Chromosorb G HP   
Column diameter (mm)    0.250.25
Phase thickness (mum)    0.40 
Temperature (C) 130.130.130.80.100.
I 587.3588.2590.583.584.
ReferenceDallos, Sisak, et al., 2000Reddy, Dutoit, et al., 1992Dutoit, 1991Soják, Farkas, et al., 1991Rang, Kuningas, et al., 1976
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SqualaneSqualaneSqualaneSqualaneSqualane
Column length (m) 100.100.100.100.100.
Carrier gas N2N2N2N2N2
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (mum)      
Temperature (C) 110.120.130.86.90.
I 584.584.584.587.584.
ReferenceRang, Kuningas, et al., 1976Rang, Kuningas, et al., 1976Rang, Kuningas, et al., 1976Rang, Kuningas, et al., 1976Rang, Kuningas, et al., 1976
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type PackedCapillaryPackedPackedPacked
Active phase ApolaneSqualaneSqualaneSqualaneSqualane
Column length (m) 2.480.15.15.15.
Carrier gas He HeHeHe
Substrate Chromosorb Chromosorb PChromosorb PChromosorb P
Column diameter (mm)  0.250.250.250.25
Phase thickness (mum)      
Temperature (C) 70.60.27.49.67.
I 587.3588.586.586.587.
ReferenceRiedo, Fritz, et al., 1976Orav and Eisen, 1972Hively and Hinton, 1968Hively and Hinton, 1968Hively and Hinton, 1968
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type Packed
Active phase Squalane
Column length (m) 15.
Carrier gas He
Substrate Chromosorb P
Column diameter (mm) 0.25
Phase thickness (mum)  
Temperature (C) 86.
I 587.
ReferenceHively and Hinton, 1968
Comment MSDC-RI

References

Go To: Top, Kovats' RI, non-polar column, isothermal, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dallos, Sisak, et al., 2000
Dallos, A.; Sisak, A.; Kulcsár, Z.; Kováts, E., Pair-wise interactions by gas chromatography VII. Interaction free enthalpies of solutes with secondary alcohol groups, J. Chromatogr. A, 2000, 904, 2, 211-242, https://doi.org/10.1016/S0021-9673(00)00908-0 . [all data]

Reddy, Dutoit, et al., 1992
Reddy, K.S.; Dutoit, J.-Cl.; Kovats, E. sz., Pair-wise interactions by gas chromatography. I. Interaction free enthalpies of solutes with non-associated primary alcohol groups, J. Chromatogr., 1992, 609, 1-2, 229-259, https://doi.org/10.1016/0021-9673(92)80167-S . [all data]

Dutoit, 1991
Dutoit, J., Gas chromatographic retention behaviour of some solutes on structurally similar polar and non-polar stationary phases, J. Chromatogr., 1991, 555, 1-2, 191-204, https://doi.org/10.1016/S0021-9673(01)87179-X . [all data]

Soják, Farkas, et al., 1991
Soják, L.; Farkas, P.; Ostrovský, I.; Janák, J.; Chrétien, J.R., Capillary gas chromatography of C5 - C13 branched alkynes on squalane and liquid crystal stationary phases, J. Chromatogr., 1991, 557, 241-253, https://doi.org/10.1016/S0021-9673(01)87136-3 . [all data]

Rang, Kuningas, et al., 1976
Rang, S.; Kuningas, K.; Orav, A.; Eisen, O., Capillary gas chromatography of n-alkynes. I. Retention indices, J. Chromatogr., 1976, 119, 451-460, https://doi.org/10.1016/S0021-9673(00)86807-7 . [all data]

Riedo, Fritz, et al., 1976
Riedo, F.; Fritz, D.; Tarján, G.; Kováts, E.Sz., A tailor-made C87 hydrocarbon as a possible non-polar standard stationary phase for gas chromatography, J. Chromatogr., 1976, 126, 63-83, https://doi.org/10.1016/S0021-9673(01)84063-2 . [all data]

Orav and Eisen, 1972
Orav, A.; Eisen, O., The retention indexes for alkenes, alkynes and cyclenes on capillary columns, Izv. Akad. Nauk Est. SSR, Khim. Geol., 1972, 21, 1, 39-47. [all data]

Hively and Hinton, 1968
Hively, R.A.; Hinton, R.E., Variation of the retention index with temperature on squalane substrates, J. Gas Chromatogr., 1968, 6, 4, 203-217, https://doi.org/10.1093/chromsci/6.4.203 . [all data]


Notes

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