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1,2-Hexanediol

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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas-490.1 ± 7.1kJ/molCcbKnauth and Sabbah, 1990 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafliquid-577.1 ± 7.1kJ/molCcbKnauth and Sabbah, 1990 
Quantity Value Units Method Reference Comment
Deltacliquid-3784.8 ± 7.1kJ/molCcbKnauth and Sabbah, 1990Corresponding «DELTA»fliquid = -577.1 kJ/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Tboil496.7KN/AAldrich Chemical Company Inc., 1990BS
Tboil496.65KN/AWalti, 1934Uncertainty assigned by TRC = 4. K; TRC
Quantity Value Units Method Reference Comment
Deltavap78.7 ± 0.3kJ/molGSVerevkin, 2004Based on data from 294. - 348. K.; AC
Deltavap87.0 ± 0.3kJ/molCKnauth and Sabbah, 1990ALS
Deltavap87.0kJ/molN/AKnauth and Sabbah, 1990DRB

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
NIST MS number 2042

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Gas Chromatography

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillarySE-541145.Woolley, Markides, et al., 198620. m/0.05 mm/0.25 «mu»m, He, 40. C @ 2. min, 4. K/min; Tend: 180. C
CapillarySE-541146.Woolley, Markides, et al., 198620. m/0.05 mm/0.25 «mu»m, He, 40. C @ 2. min, 4. K/min; Tend: 180. C
CapillarySE-541146.Woolley, Markides, et al., 198620. m/0.05 mm/0.25 «mu»m, He, 40. C @ 2. min, 4. K/min; Tend: 180. C
CapillarySE-541147.Woolley, Markides, et al., 198620. m/0.05 mm/0.25 «mu»m, He, 40. C @ 2. min, 4. K/min; Tend: 180. C
CapillarySE-541147.Woolley, Markides, et al., 198620. m/0.05 mm/0.25 «mu»m, He, 40. C @ 2. min, 4. K/min; Tend: 180. C
CapillarySE-541147.Woolley, Markides, et al., 198620. m/0.05 mm/0.25 «mu»m, He, 40. C @ 2. min, 4. K/min; Tend: 180. C
CapillarySE-541148.Woolley, Markides, et al., 198620. m/0.05 mm/0.25 «mu»m, He, 40. C @ 2. min, 4. K/min; Tend: 180. C
CapillarySE-541149.Woolley, Markides, et al., 198620. m/0.05 mm/0.25 «mu»m, He, 40. C @ 2. min, 4. K/min; Tend: 180. C
CapillarySE-541150.Woolley, Markides, et al., 198620. m/0.05 mm/0.25 «mu»m, He, 40. C @ 2. min, 4. K/min; Tend: 180. C
CapillarySE-541153.Woolley, Markides, et al., 198620. m/0.05 mm/0.25 «mu»m, He, 40. C @ 2. min, 4. K/min; Tend: 180. C
CapillarySE-541162.Woolley, Markides, et al., 198620. m/0.05 mm/0.25 «mu»m, He, 40. C @ 2. min, 4. K/min; Tend: 180. C

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Knauth and Sabbah, 1990
Knauth, P.; Sabbah, R., Energetics of inter- and intramolecular bonds in alkanediols. IV. The thermochemical study of 1,2-alkanediols at 298.15 K, Thermochim. Acta, 1990, 164, 145-152. [all data]

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Walti, 1934
Walti, A., J. Am. Chem. Soc., 1934, 56, 2723. [all data]

Verevkin, 2004
Verevkin, Sergey P., Determination of vapor pressures and enthalpies of vaporization of 1,2-alkanediols, Fluid Phase Equilibria, 2004, 224, 1, 23-29, https://doi.org/10.1016/j.fluid.2004.05.010 . [all data]

Woolley, Markides, et al., 1986
Woolley, C.L.; Markides, K.E.; Lee, M.L.; Bartle, K.D., Deactivation of small diameter fused silica capillary columns with organosilicon hydrides, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1986, 9, 9, 506-514, https://doi.org/10.1002/jhrc.1240090904 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Gas Chromatography, References