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Tripropyl borate

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Phase change data

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Reference Comment
52.3355.Thomas, Smith, et al., 2007Based on data from 340. - 453. K.
47.6452.Christopher and Shilman, 1967Based on data from 358. - 452. K.

Gas phase ion energetics data

Go To: Top, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
10.02EILappert, Litzow, et al., 1970RDSH
10.62 ± 0.15EIFallon, Kelly, et al., 1968RDSH

Mass spectrum (electron ionization)

Go To: Top, Phase change data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin P.J.FALLON UNIV. OF NEWCASTLE UPON TYNE, UK
NIST MS number 8102

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References

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Thomas, Smith, et al., 2007
Thomas, Leo H.; Smith, Harry; Davies, Gwyn H., Vapour pressures, molar entropies of vaporisation and liquid-state conformation of alkoxides, J. Chem. Technol. Biotechnol., 2007, 30, 1, 476-480, https://doi.org/10.1002/jctb.503300160 . [all data]

Christopher and Shilman, 1967
Christopher, Phoebus M.; Shilman, Avner, Vapor pressures of trialkyl borates, J. Chem. Eng. Data, 1967, 12, 3, 333-335, https://doi.org/10.1021/je60034a012 . [all data]

Lappert, Litzow, et al., 1970
Lappert, M.F.; Litzow, M.R.; Pedley, J.B.; Riley, P.N.K.; Spalding, T.R.; Tweedale, A., Bonding studies of compounds of boron and the group IV elements. Part III.First ionisation potentials of some simple boron compounds by electron impact and by a new empirical molecular orbital method, J. Chem. Soc. A, 1970, 2320. [all data]

Fallon, Kelly, et al., 1968
Fallon, P.J.; Kelly, P.; Lockhart, J.C., Fragmentation of some alkyl borates under electron impact, Intern. J. Mass Spectrom. Ion Phys., 1968, 1, 133. [all data]


Notes

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References