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Hydroxymethyl-d3 radical

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
B - John E. Bartmess

View reactions leading to CD3O+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
1.5546 ± 0.0019LPESNee, Osterwalder, et al., 2006B
1.5590 ± 0.0040LPESRamond, Davico, et al., 2000B
1.5510 ± 0.0050LPESOsborn, Leahy, et al., 1998B
1.552 ± 0.022LPESEngleking, Ellison, et al., 1978B

Ionization energy determinations

IE (eV) Method Reference Comment
7.53 ± 0.02PIKuo, Zhang, et al., 1994LL
7.56 ± 0.01PEDyke, 1987LBLHLM


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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Nee, Osterwalder, et al., 2006
Nee, M.J.; Osterwalder, A.; Zhou, J.; Neumark, D.M., Slow electron velocity-map imaging photoelectron spectra of the methoxide anion, J. Chem. Phys., 2006, 125, 1, 014306, https://doi.org/10.1063/1.2212411 . [all data]

Ramond, Davico, et al., 2000
Ramond, T.M.; Davico, G.E.; Schwartz, R.L.; Lineberger, W.C., Vibronic structure of alkoxy radicals via photoelectron spectroscopy, J. Chem. Phys., 2000, 112, 3, 1158-1169, https://doi.org/10.1063/1.480767 . [all data]

Osborn, Leahy, et al., 1998
Osborn, D.L.; Leahy, D.J.; Kim, E.H.; deBeer, E.; Neumark, D.M., Photoelectron spectroscopy of CH3O- and CD3O-, Chem. Phys. Lett., 1998, 292, 4-6, 651-655, https://doi.org/10.1016/S0009-2614(98)00717-9 . [all data]

Engleking, Ellison, et al., 1978
Engleking, P.C.; Ellison, G.B.; Lineberger, W.C., Laser photodetachment electron spectrometry of methoxide, deuteromethoxide, and thiomethoxide: Electron affinities and vibrational structure of CH3O, and CH3S, J. Chem. Phys., 1978, 69, 1826. [all data]

Kuo, Zhang, et al., 1994
Kuo, S.-C.; Zhang, Z.; Klemm, R.B.; Liebman, J.F.; Stief, L.J.; Nesbitt, F.L., Photoionization of hydroxymethyl (CD2OH and CD3O) radicals: Photoion efficiency spectra, ionization energies and thermochemistry, J. Phys. Chem., 1994, 98, 4026. [all data]

Dyke, 1987
Dyke, J.M., Properties of gas-phase ions, J. Chem. Soc. Faraday Trans., 1987, 83, 69. [all data]


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