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Boron hydride sulfide cation


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
gas,1 bar225.34J/mol*KReviewChase, 1998Data last reviewed in December, 1975

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 38000 ± 1000 gas Fehlner and Turner, 1973
Kroto, Suffolk, et al., 1973


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigma+ 1 BH stretch 2190 ± 100 gas PE Fehlner and Turner, 1973
Kroto, Suffolk, et al., 1973

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 19827 gas A-X 479 635 McDonald and Innes, 1969
King, Klapstein, et al., 1985


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigma+ 1 BH stretch 2214.8 ± 0.4 gas EF King, Klapstein, et al., 1985
3 BS stretch 1050.9 ± 0.4 gas EF King, Klapstein, et al., 1985

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigma+ 1 BH stretch 2746.8 ± 0.4 gas EF King, Klapstein, et al., 1985
Pi 2 Bend 659 ± 1 gas EF King, Klapstein, et al., 1985
Sigma+ 3 BS stretch 984.1 ± 0.4 gas EF King, Klapstein, et al., 1985

Additional references: Jacox, 1994, page 31; Jacox, 1998, page 141; King, Kuhn, et al., 1986; Chau, Tang, et al., 1994

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Gas phase thermochemistry data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Fehlner and Turner, 1973
Fehlner, T.P.; Turner, D.W., Photoelectron spectrum of HBS, J. Am. Chem. Soc., 1973, 95, 7175. [all data]

Kroto, Suffolk, et al., 1973
Kroto, H.W.; Suffolk, R.J.; Westwood, N.P.C., The photoelectron spectrum of thioborine, HBS, Chem. Phys. Lett., 1973, 22, 495. [all data]

McDonald and Innes, 1969
McDonald, J.K.; Innes, K.K., 2«DELTA»i-A2«PI»i and two 2«SIGMA»+-2«PI»i band systems of the boron monosulfide molecule, J. Mol. Spectrosc., 1969, 29, 1-3, 251, https://doi.org/10.1016/0022-2852(69)90106-4 . [all data]

King, Klapstein, et al., 1985
King, M.A.; Klapstein, D.; Kuhn, R.; Maier, J.P.; Kroto, H.W., Mol. Phys., 1985, 56, 4, 871, https://doi.org/10.1080/00268978500102771 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

King, Kuhn, et al., 1986
King, M.A.; Kuhn, R.; Maier, J.P., ~A2.SIGMA.+ .fwdarw. ~X2.PI.i emission spectra of fluoro- and chlorothioboron cations, FBS+ and ClBS+, J. Phys. Chem., 1986, 90, 24, 6460, https://doi.org/10.1021/j100282a011 . [all data]

Chau, Tang, et al., 1994
Chau, F.T.; Tang, Y.W.; Song, X., Geometries of thioborine and chlorothioboron cations, J. Electron Spectrosc. Relat. Phenom., 1994, 70, 1, 39, https://doi.org/10.1016/0368-2048(94)02209-I . [all data]


Notes

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